5 Structure and Reactivity of Transition Metal Chalcogenides toward the Molecular Oxygen Reduction Reaction

2011 ◽  
pp. 255-300 ◽  
Author(s):  
Nicolás Alonso-Vante
Keyword(s):  
Transition Metal ◽  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Molecular Oxygen ◽  
Reduction Reaction ◽  
Metal Chalcogenides ◽  
Transition Metal Chalcogenides

scholarly journals The Catalytic Centre of Transition Metal Chalcogenides vis-à-vis the Oxygen Reduction Reaction : An In Situ Electrochemical EXAFS Study

1997 ◽  
Vol 7 (C2) ◽  
pp. C2-887-C2-889 ◽  
Author(s):  
N. Alonso-Vante ◽  
M. Fieber-Erdmann ◽  
H. Rossner ◽  
E. Holub-Krappe ◽  
Ch. Giorgetti ◽  
...  
Keyword(s):  
Transition Metal ◽  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Reduction Reaction ◽  
Metal Chalcogenides ◽  
Transition Metal Chalcogenides ◽  
Exafs Study

Enhanced activity of selenocyanate-containing transition metal chalcogenides supported by nitrogen-doped carbon materials for the oxygen reduction reaction

2019 ◽  
Vol 9 (13) ◽  
pp. 3426-3434 ◽  
Author(s):  
Huan-Ping Jhong ◽  
Sun-Tang Chang ◽  
Hsin-Chih Huang ◽  
Kai-Chin Wang ◽  
Jyh-Fu Lee ◽  
...  
Keyword(s):  
Transition Metal ◽  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Carbon Materials ◽  
Reduction Reaction ◽  
Metal Chalcogenides ◽  
Nitrogen Doped ◽  
Transition Metal Chalcogenides ◽  
Orr Activity ◽  
Nitrogen Doped Carbon

The SeCN− containing transition metal chalcogenides supported by nitrogen-doped carbon catalyzes the ORR activity.

Phase Control of Ultrafine FeSe Nanocrystals in N-doped Carbon Matrix for Highly Efficient and Stable Oxygen Reduction Reaction

2021 ◽  
Author(s):  
Yangfei Cao ◽  
Senchuan Huang ◽  
Zhangquan Peng ◽  
Fen Yao ◽  
Xiaohui Li ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Energy Efficient ◽  
Carbon Matrix ◽  
Cost Effective ◽  
Phase Control ◽  
Reduction Reaction ◽  
Metal Chalcogenides ◽  
Transition Metal Chalcogenides ◽  
Stable Oxygen

Transition metal chalcogenides have been known as cost-effective and energy-efficient electrocatalysts for oxygen reduction reaction (ORR). Crystal phase control is vital for tailoring their ORR performances. Herein, hexagonal (h-FeSe) and...

scholarly journals Probing the activity of transition metal M and heteroatom N4 co-doped in vacancy fullerene (M–N4–C64, M = Fe, Co, and Ni) towards the oxygen reduction reaction by density functional theory

RSC Advances ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 3174-3182
Author(s):  
Siwei Yang ◽  
Chaoyu Zhao ◽  
Ruxin Qu ◽  
Yaxuan Cheng ◽  
Huiling Liu ◽  
...  
Keyword(s):  
Density Functional Theory ◽  
Transition Metal ◽  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Density Functional ◽  
Reduction Reaction ◽  
Functional Theory ◽  
Co Doped

In this study, a novel type oxygen reduction reaction (ORR) electrocatalyst is explored using density functional theory (DFT); the catalyst consists of transition metal M and heteroatom N4 co-doped in vacancy fullerene (M–N4–C64, M = Fe, Co, and Ni).

scholarly journals Transition Metal (Fe, Co, Ni) Nanoparticles on Selective Amino-N-Doped Carbon as High-Performance Oxygen Reduction Reaction Electrocatalyst

Nanomaterials ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 742 ◽  
Author(s):  
Seonghee Kim ◽  
Shuhei Kato ◽  
Takahiro Ishizaki ◽  
Oi Lun Li ◽  
Jun Kang
Keyword(s):  
Transition Metal ◽  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
High Performance ◽  
Reduction Reaction ◽  
Metal Nanoparticle ◽  
Superior Performance ◽  
Pt Catalyst ◽  
Hydrogen Electrode ◽  
Electrochemical Testing

Metal-air batteries are attracting increasing attention as a superior renewable energy conversion device due to their high performance and strong potential. However, the high cost and low stability of the current Pt catalyst is the main obstacle preventing wide industrial application. In this work, we applied a plasma process to fabricate aniline and a transition metals electrode (Fe, Co, Ni) as the carbon-nitrogen and the metal nanoparticle (NP) precursors, respectively, for selective metal/amino-N-doped carbon catalysts. All three as-synthesized catalysts exhibited dominant amino-N as the major C–N bonding state. In electrochemical testing, Co/amino-N-doped carbon showed positive E1/2 potential (0.83 V vs. Reversible Hydrogen Electrode (RHE)). In addition, the calculated electron transfer number (n) of Co/amino-N-doped carbon at 0.5 V vs. RHE was 3.81, which was only slightly less than that of commercial Pt/C (3.97). This superior performance of transition metal/amino-N-doped carbon promotes it as an economical oxygen reduction reaction (ORR) electrocatalyst to replace expensive Pt/C in metal-air batteries.

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