Magnetic field assisted electrocatalytic oxygen evolution reaction of nickel-based materials

The dominant role of the magnetoresistance effect caused by spin electron scattering in the oxygen evolution reaction is unveiled through an in situ tunable magnetic field-electrochemical testing system.

Designing a Graphene Coating-Based Supercapacitor with Lithium Ion Electrolyte: An Experimental and Computational Study via Multiscale Modeling

Graphene electrodes are investigated for electrochemical double layer capacitors (EDLCs) with lithium ion electrolyte, the focus being the effect of the pore size distribution (PSD) of electrode with respect to the solvated and desolvated electrolyte ions. Two graphene electrode coatings are examined: a low specific surface area (SSA) xGNP-750 coating and a high SSA coating based on a-MWGO (activated microwave expanded graphene oxide). The study comprises an experimental and a computer modeling part. The experimental part includes fabrication, material characterization and electrochemical testing of an EDLC with xGNP-750 coating electrodes and electrolyte 1M LiPF6 in EC:DMC. The computational part includes simulations of the galvanostatic charge-discharge of each EDLC type, based on a continuum ion transport model taking into account the PSD of electrodes, as well as molecular modeling to determine the parameters of the solvated and desolvated electrolyte ions and their adsorption energies with each type of electrode pore surface material. Predictions, in agreement with the experimental data, yield a specific electrode capacitance of 110 F g−1 for xGNP-750 coating electrodes in electrolyte 1M LiPF6 in EC:DMC, which is three times higher than that of the high SSA a-MWGO coating electrodes in the same lithium ion electrolyte.

Carrageenan as an Ecological Alternative of Polyvinylidene Difluoride Binder for Li-S Batteries

Lithium-sulfur batteries are one of the most promising battery systems nowadays. However, this system is still not suitable for practical application because of the number of shortcomings that limit its cycle life. One of the main problems related to this system is the volumetric change during cycling. This deficiency can be compensated by using the appropriate binder. In this article, we present the influence of a water-soluble binder carrageenan on the electrochemical properties of the Li-S battery. The electrode with a carrageenan binder provides good stability during cycling and at high C-rates. Electrochemical testing was also carried out with a small prototype pouch cell with a capacity of 16 mAh. This prototype pouch cell with the water-based carrageenan binder showed lower self-discharge and low capacity drop. Capacity decreased by 7% after 70 cycles.

Preparation of Zinc Oxide and Zinc Ferrite from Zinc Hypoxide by Wet Process and Electrochemistry

With the increase of zinc resource consumption, the recovery and utilization of zinc resources in zinc suboxide has become one of the current research hotspots. In this study, the electrochemical method was used to remove the impurities in the zinc leaching night and enrich the zinc ferrite in the ammonia leaching residue for the solution and ammonia leaching slag after the ammonia leaching of zinc hypoxide, in order to realize the comprehensive utilization of the essence of zinc immersion night and new resources. The results showed that the reduction potentials of copper, lead, cadmium, and zinc in the ammonia leaching solution were analyzed by electrochemical testing methods to be −0.76 V, −0.82 V, −0.94 V, and −1.3 V, respectively. Through constant potential electrodeposition, the removal rate of copper, lead, cadmium. The removal rate of cadmium is 98.73%, and the removal rate of lead and copper is more than 99%. The purified ammonia leaching solution is evaporated at 90 °C for 25 min to obtain basic zinc carbonate. The purity of ZnO obtained after calcination at 500 °C for 120 min is 96.31%. The ammonia leaching residue was pickled with 3 mol·L−1 acetic acid for 30 min to effectively remove PbCO3, and then magnetic separation was carried out with a current intensity of 1.4 A. The final zinc ferrite content was 83.83%.

Nanoelectrode Ensembles Consisting of Carbon Nanotubes

Incorporating the nanoscale properties of carbon nanotubes (CNTs) and their assemblies into macroscopic materials is at the forefront of scientific innovation. The electrical conductivity, chemical inertness, and large aspect ratios of these cylindrical structures make them ideal electrode materials for electrochemical studies. The ability to assemble CNTs into nano-, micro-, and macroscale materials broadens their field of applications. Here, we report the fabrication of random arrays of CNT cross-sections and their performance as nanoelectrode ensembles (NEEs). Single ribbons of drawable CNTs were employed to create the CNT-NEEs that allows easier fabrication of nanoscale electrodes for general electrochemical applications. Surface analysis of the prepared NEEs using scanning electron microscopy showed a random distribution of CNTs within the encapsulating polymer. Electrochemical testing via cyclic voltammetry and scanning electrochemical cell microscopy revealed voltametric differences from the typical macroelectrode response with the steady-state nature of NEEs. Finally, when the NEE was employed for Pb2+ detection using square-wave anodic stripping voltammetry, a limit of detection of 0.57 ppb with a linear range of 10–35 ppb was achieved.

Study of Electrochemical Properties of NiCo2O4/ Reduced Graphene Oxide / PEDOT:PSS Ternary Nanocomposite for High Performance Supercapacitor Electrode

A two-step procedure is used to create a novel ternary composite NiCo2O4 hexagonalnanoplatesarray/ reducedgrapheneoxide/poly(3,4ethylenedioxythiophene): poly (styrene-sulfonate) (NiCo2O4-rGO/PEDOT:PSS). It was tested to see if it might be used in super capacitor electrode materials. According to electrochemical testing, the NiCo2O4-rGO-PEDOT. PSS materials has a great exact capacitance of 1115 Fg.1 on a current compactness of 2 Ag-1, decent rate ability, and excellent cycle stability, with capacitance retention of 88 percent after 10000 cycles. As a consequence, this ternary composite may find use in a variety of energy storage electrodes.

Wave amplitude of embedded ultrasonic transducer-based damage monitoring of concrete due to steel bar corrosion

In this research, four embedded ultrasonic piezoelectric transducers were combined to form cross pair and opposite pair monitoring schemes for continuously monitoring the damage to different strength grades of concrete caused by the corrosion of reinforcements under accelerated corrosion conditions. The damage process was analyzed by combining the electrochemical effects of steel corrosion, that is, half-cell potential and galvanic current tests. Results show that the embedded ultrasonic transducer method can detect damage of concrete during steel corrosion and that each stage of damage can be determined from the plots of ultrasonic transducer data versus corrosion rate. The results further indicate that a combination of cross pair and opposite pair testing methods can more comprehensively reflect the damage to concrete caused by the expansion of corrosion of steel bars, than a single testing method. Since electrochemical testing can only depict the corrosion state of steel rebars, it is beneficial to use embedded ultrasonic measurements to monitor the damage process of concrete. The differences in damage between different strength grades of concrete, that is, the resistance to corrosion of steel bars and brittle failure, can be obtained from the plots of ultrasonic transducer data.