Einstein’s Light-Quantum Hypothesis, or Why Didn’t Einstein Propose a Quantum Gas a Decade-and-a-Half Earlier?

Author(s):  
John Stachel
2012 ◽  
Vol 554-556 ◽  
pp. 374-378 ◽  
Author(s):  
Li Wei Wang

Based on the Planck's quantum hypothesis and the Einstein's light quantum hypothesis , the Zhongjizi (a new elementary particles) hypothesis is proposed. It revealed the quantum nature of light. Light quantum (which is photon) was essentially a collection of Zhongjizi, light was constituted of Zhongjizi, the essence of light was the nature of particle, and the quantum nature of light was essentially the Zhongjizi nature of light. The quantum nature of light revealed out: atomic spectra was produced by the light of different frequencies that emitted and absorbed by the extranuclear electrons of different motion states (different rotation frequencies) under certain conditions. The rotation frequency of extranuclear electrons was equal to the frequencies of light that emitted and absorbed by the electrons. By using this law, and according to the atomic spectra, we can know the state of the electron structure of atoms and the movement of electrons ,according to the frequency (the cycle )that rotate round the nuclear of the extranuclear electron in a state of motion , and the relationship of the distance between the electrons and the atomic nucleus .


Author(s):  
Anthony Duncan ◽  
Michel Janssen

We provide an overview, as non‐technical as possible, of the contents of Vol. 1 of the book. Reflecting the structure of the volume, this overview consists of two parts. In the first part, we summarize the most important early contributions to quantum theory (covered in detail in Chs. 2–4). This part starts with Planck’s work on black‐body radiation culminating in the introduction of Planck’s constant in 1900. It then moves on to Einstein’s 1905 light‐quantum hypothesis, his theory of specific heats, and his formulas for energy and momentum fluctuations in black‐body radiation. After summarizing Bohr’s path to his quantum model of the atom, it concludes with Einstein’s 1916–17 radiation theory combining elements of Bohr’s model with his own light‐quantum hypothesis. In the second part we summarize our analysis of the old quantum theory (given in detail in Chs. 5–7). After a brief overview of the career of Sommerfeld, who together with Bohr took the lead in developing the old quantum theory, we review the three principles we have identified as the cornerstones of the theory (the quantization conditions, the adiabatic principle, and the correspondence principle). We then discuss three of the theory’s most notable successes (fine structure, Stark effect, X‐ray spectra) and, finally, three of its most notorious failures (multiplets, Zeeman effect, helium).


Author(s):  
Anthony Duncan ◽  
Michel Janssen

After three papers on statistical mechanics, mostly duplicating work by Boltzmann and Gibbs, Einstein relied heavily on arguments from statistical mechanics in the most revolutionary of his famous 1905 papers, the one introducing the light‐quantum hypothesis. He showed that the equipartition theorem inescapably leads to the classical Rayleigh‐Jeans law for black‐body radiation and the ultraviolet catastrophe (as Ehrenfest later called it). Einstein and Ehrenfest were the first to point this out but the physics community only accepted it after the venerable H.A. Lorentz, came to the same conclusion in 1908. The central argument for light quanta in Einstein’s 1905 paper involves a comparison between fluctuations in black‐body radiation in the Wien regime and fluctuations in an ideal gas. From this comparison Einstein inferred that black‐body radiation in the Wien regime behaves as a collection of discrete, independent, and localized particles. We show that the same argument works for non‐localized quantized wave modes. Although nobody noticed this flaw in Einstein’s reasoning at the time, his fluctuation argument, and several others like it, failed to convince anybody of the reality of light quanta. Even Millikan’s verification of Einstein formula for the photoelectric effect only led to the acceptance of the formula, not of the theory behind it. Einstein’s quantization of matter was better received, especially his simple model of a solid consisting of quantized oscillators. This model could explain why the specific heats of solids fall off sharply as the temperature is lowered instead of remaining constant as it should according to the well‐known Dulong‐Petit law, which is a direct consequence of the equipartition theorem. The confirmation of Einstein’s theory of specific heats by Nernst and his associates was an important milestone in the development of quantum theory and a central topic at the first Solvay conference of 1911, which brought the fledgling theory to the attention of a larger segment of the physics community. Returning to the quantum theory after spending a few years on the development of general relativity, Einstein combined his light‐quantum hypothesis with elements of Bohr’s model of the atom in a new quantum radiation theory.


Einstein’s statistical-thermodynamic calculations of the random variations of the radiation density constitute the ground upon which the light quantum hypothesis was originally based. According to these calculations such a variation of the radiation energy prevails—superposed above the fluctuations caused by the interferences calculated according to the classical theory—as if the radiation consisted of mutually independently mobile quanta hv of energy. According to Einstein, Maxwell’s theory correctly renders mean time values, which alone have been directly observable, as proved by the complete agreement between theory and experiment in optics; but Maxwell’s theory leads to laws respecting the thermic properties of radiation which are incompatible with the entropy-probability relation. After the wave-mechanical theory of de Broglie and Schrödinger had been generally accepted, the idea concerning the statistical character of the wave-field—already presented by Einstein in 1905—has, of course, been taken up again by Born in a more general way. As is well known, Bohr and Heisenberg have tried to conquer the difficulties to which the radiation theory has led by a radical change in our conception of energy.


Author(s):  
Evgeniy Krasnopevtsev

Correlation of particles number in an equilibrium thermal state of quantum gas is caused mutual «interference repulsion» and antibunching at fermions and «interference attraction» and bunching at bosons.


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