Exploring Particle Size Transport Variability of Suspended Sediments in Two Alpine Catchments Over the Lesser Himalayan Region, India

Author(s):  
Omvir Singh
2021 ◽  
Author(s):  
Dhruv Sehgal ◽  
Núria Martínez-Carreras ◽  
Christophe Hissler ◽  
Victor Bense ◽  
AJF (Ton) Hoitink

<p>Manual and unattended sampling in the field and laboratory analysis are common practices to measure suspended sediment (SS) carbon content and particle size. However, one of the major drawbacks of these ex-situ methods is that they make high frequency measurements challenging. This includes restricted data collection due to limited access to the sampling locations during turbulent conditions or high flows, when the largest amount of sediments is transported downstream, introducing uncertainty in quantification of SS properties (particle size and carbon content) and sediment loads. Knowledge on SS carbon content and particle size is also important to better understand the multi-component form of suspended sediments (i.e. flocs) that directly affect sediment transport and other sediment properties (e.g. settling velocity and density). Moreover, SS carbon content and particle size exert an impact on the optical sensor readings that are traditionally used to measure turbidity. In that respect, high frequency measurements of SS carbon content and particle size could eventually help us to move from ‘local’ calibrations towards ‘global’ dependencies based on in-situ SS characterization.</p><p>In this study, we propose to use a submerged UV-VIS spectrometer to infer SS carbon content and particle size. The sensor measures the entire light absorption spectrum of water between 200 nm and 750 nm at sampling intervals as short as 2-minutes. To this end, we first test our approach under controlled conditions with an experimental laboratory setup consisting of a cylindrical tank (40-L) with an open top. An UV-VIS spectrometer and a LISST-200X sensor (to measure particle size distribution) are installed horizontally. A stirrer facilitates the homogeneous mixing of SS and prevents the settling of heavy particles at the bottom. We use the sediments sampled from 6 sites in Luxembourg with contrasting composition and representing different land use types and geological settings. The sampled sediments were wet sieved into 3 size classes to clearly recognize the effect of particle size on absorption. In our investigation, we use specific wavelengths, chemometric techniques and carbon content specific absorbance indices to infer SS composition and particle size from the absorption spectrum. Results are then validated using in-situ field data from two instrumented field sites in Luxembourg. Amid the challenge of associating laboratory and field results, the preliminary results indicate that the absorption spectrum measured with a submerged UV-VIS spectrometer can be used to estimate SS particle size and carbon content.</p>


2015 ◽  
Vol 54 (20) ◽  
pp. 6367 ◽  
Author(s):  
Yuanzhi Zhang ◽  
Zhaojun Huang ◽  
Chuqun Chen ◽  
Yijun He ◽  
Tingchen Jiang

1991 ◽  
Vol 23 (1-3) ◽  
pp. 447-454 ◽  
Author(s):  
H. M. Liljestrand ◽  
Y. D. Lee

The results of controlled batch experimental studies of the adsorption and desorption kinetics of dichlorobenzene to 1) size fractionated, washed sediments, 2) aggregate, washed sediment, 3) dissolved/colloidal sediment materials, and 4) bulk sediments,are used to determine the effect of inhomogeneous mixtures on the overall sorption rates. The size-segregated sediments are modeled as spherical particles with a porous outer shell of organic matter for sorption and an inert, inorganic core. The characteristic times of intraparticle diffusive transport are found to vary with particle size by about two orders of magnitude. The distribution of natural organic matter content with particle size results in sorption rates which differ greatly from that predicted by the monodisperse, homogeneous particle model. Coupled, reversible reactions between the solute and each solid size fraction are presented as a conceptual model for the interpretation of the empirical results of batch experiments.


Author(s):  
C. J. Chan ◽  
K. R. Venkatachari ◽  
W. M. Kriven ◽  
J. F. Young

Dicalcium silicate (Ca2SiO4) is a major component of Portland cement. It has also been investigated as a potential transformation toughener alternative to zirconia. It has five polymorphs: α, α'H, α'L, β and γ. Of interest is the β-to-γ transformation on cooling at about 490°C. This transformation, accompanied by a 12% volume increase and a 4.6° unit cell shape change, is analogous to the tetragonal-to-monoclinic transformation in zirconia. Due to the processing methods used, previous studies into the particle size effect were limited by a wide range of particle size distribution. In an attempt to obtain a more uniform size, a fast quench rate involving a laser-melting/roller-quenching technique was investigated.The laser-melting/roller-quenching experiment used precompacted bars of stoichiometric γ-Ca2SiO4 powder, which were synthesized from AR grade CaCO3 and SiO2xH2O. The raw materials were mixed by conventional ceramic processing techniques, and sintered at 1450°C. The dusted γ-Ca2SiO4 powder was uniaxially pressed into 0.4 cm x 0.4 cm x 4 cm bars under 34 MPa and cold isostatically pressed under 172 MPa. The γ-Ca2SiO4 bars were melted by a 10 KW-CO2 laser.


Author(s):  
Sooho Kim ◽  
M. J. D’Aniello

Automotive catalysts generally lose-agtivity during vehicle operation due to several well-known deactivation mechanisms. To gain a more fundamental understanding of catalyst deactivation, the microscopic details of fresh and vehicle-aged commercial pelleted automotive exhaust catalysts containing Pt, Pd and Rh were studied by employing Analytical Electron Microscopy (AEM). Two different vehicle-aged samples containing similar poison levels but having different catalytic activities (denoted better and poorer) were selected for this study.The general microstructure of the supports and the noble metal particles of the two catalysts looks similar; the noble metal particles were generally found to be spherical and often faceted. However, the average noble metal particle size on the poorer catalyst (21 nm) was larger than that on the better catalyst (16 nm). These sizes represent a significant increase over that found on the fresh catalyst (8 nm). The activity of these catalysts decreases as the observed particle size increases.


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