Carbonate Phase in the Formation of Binding Substance in Dolomite Cement

Author(s):  
Nikolay Shelikhov ◽  
Ruslan Sagdiev
2019 ◽  
Vol 89 (10) ◽  
pp. 1055-1073 ◽  
Author(s):  
Nicolaas Molenaar ◽  
Marita Felder

ABSTRACT Dolomite is a common and volumetrically important mineral in many siliciclastic sandstones, including Permian Rotliegend sandstones (the Slochteren Formation). These sandstones form extensive gas reservoirs in the Southern Permian Basin in the Netherlands, Germany, Poland, and the UK. The reservoir quality of these sandstones is negatively influenced by the content and distribution of dolomite. The origin and the stratigraphic distribution of the dolomite is not yet fully understood. The aim of this study is to identify the origin of carbonate. The main methods used to achieve those aims are a combination of thin-section petrography, scanning electron microscopy (SEM and EDX), and XRD analyses. The present study shows that the typical dispersed occurrence of the dolomite is a consequence of dispersed detrital carbonate grains that served both as nuclei and source for authigenic dolomite cement. The dolomite cement formed syntaxial outgrowths and overgrowths around detrital carbonate grains. The study also shows that dolomite cement, often in combination with ankerite and siderite, precipitated during burial after mechanical compaction. Most of the carbonate grains consisted of dolomite before deposition. The carbonate grains were affected by compaction and pressure dissolution, and commonly have no well-defined outlines anymore. The distribution of dolomite cement in the Rotliegend sandstones was controlled by the presence of stable carbonate grains. Due to the restricted and variable content of carbonate grains and their dispersed occurrence, the cement is also dispersed and the degree of cementation heterogeneous. Our findings have important implications on diagenesis modeling. The presence of detrital carbonate excludes the need for external supply by any large-scale advective flow of diagenetic fluids. By knowing that the carbonate source is local and related to detrital grains instead of being externally derived from an unknown source, the presence of carbonate cement can be linked to a paleogeographic and sedimentological model.


1965 ◽  
Vol 49 (1) ◽  
pp. 131-149 ◽  
Author(s):  
F. Norman Briggs ◽  
Martin Fleishman

A high molecular weight fraction of a soluble Marsh muscle-relaxing preparation has been shown to contain a calcium-complexing substance. By examining the nature of the competition between this fraction and chelex-100 for calcium at various total calcium concentrations it has been possible to calculate the concentration and calcium stability constant of this calcium-complexing substance. Taking into account dilutions which occur during the preparation of fractions containing this substance its concentration may be estimated at about 2·10-4 in muscle and its calcium stability constant was found to be about 1.5·105 M-1. Preliminary evidence suggests that the calcium-binding substance is a protein.


2019 ◽  
Vol 16 (32) ◽  
pp. 930-944
Author(s):  
G. BABAEE KHOU ◽  
M. H. ADABI ◽  
D. JAHANI ◽  
S. H. VAZIRI

To understand microfacies, depositional environment and geochemistry of Upper Permian rocks in Alborz region, the type sections of Ruteh Formation were studied. During the Permian, the Alborz region was a part of the east-west trending Paleotethys sea. Stratigraphic studies indicate that the Ruteh Formation in Ruteh section is composed of thin to massive limestone, argillaceous limestone interbedded with shale, is overlain by distinct laterite horizon of the Elika Formation and is underlain by the disconformity by the Dorud Formation. Facies analysis and petrographic studies led to the recognition of 11 microfacies in Ruteh section. These facies were deposited in 4 facies belts such as tidal flat, lagoon, shoal and open marine sub-environment. The Permian calcareous algae in the Ruteh Formation are widespread and well documented to determine the environment and microfacies of Permian deposits. Cementation and dolomitization are the main diagenetic processes in Ruteh Formation. Based on petrographic (size and fabric) studies, 4 dolomite types such as dolomicrite, dolomicrospar, dolospar, and dolomite cement were recognized. Seawater was the main source of Mg for early diagenetic dolomite (type 1), while Mg for late diagenetic dolomite (types 2,3,4) probably were sourced by shale pressing processes and pressure solution. Major and minor element studies led to there cognition of aragonite mineralogy. The geochemical study illustrates that these carbonates were affected mostly by meteoric diagenesis, which is occurred in a semi-close to open diagenetic system.


1973 ◽  
Vol 13 (3) ◽  
pp. 901-911
Author(s):  
KOZO UTSUMI ◽  
TAKUZO ODA

Ruthenium red induces the agglutination of ascites hepatoma cells. The agglutination was inhibited by acidic polysaccharides but not by haptenic inhibitors of some plant agglutinins. The agglutination was also abolished by treatment of the cells with a low concentration of papain. Papain digestion causes a decrease in the number of microvilli on the cell surface and the release of carbohydrate-containing red-binding substance. One of them is a heparan sulphate-like mucopolysaccharide and the other is a glycoprotein which contains sialic acid. The ruthenium red-binding fractions inhibit the cell agglutination induced by ruthenium red.


Author(s):  
Jiangtao Xu ◽  
Duyou Lu ◽  
Shaohua Zhang ◽  
Zhongzi Xu ◽  
RD Hooton

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