Characterization of Siliceous Nodules in Western Kefalonia Ιsland Greece: An Initial Approach to Their Formation and Diagenetic Characteristics

In this study, siliceous nodules from the world-famous Myrtos beach, as well as from Avithos beach, in the western flanks of Kefalonia Island in Greece are examined by means of petrographical, mineralogical, geochemical and micropaleontological methods. The objectives of this study are to characterize the textural and compositional features of the nodules, with the aim to provide an initial interpretation of their origin and their diagenetic evolution. The studied siliceous nodules are hosted within Lower Cretaceous thin-bedded limestones at Myrtos and Upper Eocene limestones at Avithos. Nodules from both areas display a characteristic concentric texture at a macroscopic and microscopic scale. They both have a dense fine-grained siliceous sedimentary fabric, composed mainly of microcrystalline or cryptocrystalline quartz and moganite with common residual calcite in the case of Avithos. These results, and in particular the shape of the nodules, along the textural and compositional characteristics, indicate different conditions of formation in the two localities, both during the early epigenetic stages, as well as later during the diagenetic processes. Myrtos nodules originated from Si-precursors deposited in a pelagic environment, going through intense Si-replacement. Avithos nodules were deposited in a more proximal environment, being influenced by a less intense silicification. Nevertheless, the higher degree of recrystallization of Avithos samples indicates a syn- or post-diagenetic tectonic activity that resulted in the circulation of geothermal fluids. The conclusions drawn from this work demonstrate the usefulness of thorough studies of siliceous nodules in order to get a more comprehensive understanding of the initial depositional conditions, as well as diagenetic pathways and processes.

Stable Isotopes Carbon C13 and Oxygen O18 as Indicators of Triassic Limestone Sedimentation Environment and Diagenesis

The results of researches of the stable isotopes, carbon 13C and oxygen 18O, measured in Triassic limestones of Opole Silesia in Poland were presented in this article. The study was carried out to obtain data for interpretation of the environment of these rocks formation. Moreover, it was possible to form the theory about diagenetic processes which influenced on the mineral composition of limestone and some of their carbonte phases. The results of study show a general differentiation of δ13C and δ18O contents in carbonate minerals. All δ18O values are less than 0 ‰. It indicates that the origin oxygen isotope composition could be probably reset by diagenesis. The crystallization temperatures of low-Mg calcite and high-Mg, calculated on the basis of δ18O values are greater than 25 oC. They are higher than typical for sea basin and are also not be related to the presence of hydrothermal solutions. The increased temperatures of calcites crystallization are related to diagenetic processes that took place after the deposition and burial of carbonate material. The preservation of high-Mg calcite, an ustable carbonate phase, which is usually trasformed into low-Mg calcite during diagenesis, is probably connected with the increased salinity of the sea basin in which studied limestones were formed.

Diagenetic stages of oil-saturated sandstones of the pashyisky horizon at the Romashkinskoye oil field

It was identified three stages of reservoir rock formation of the Pashyisky horizon of the Frasnian stage of the Upper Devonian at the Romashkinskoye field, based on optical microscopic studies. The first stage, associated with clastic deposits sedimentation and marked by clastic grains dense structural packing formation, close to cubic. The second diagenetic stage of quartz sandstones is associated with the subsidence stage of sediments into the burial zone. During this period were actively proceeding the processes of grains mechanical deformation, blastesis of quartz clasts, the formation of siderite fragments, and fibrous chalcedony, partially metasomatic replacing clay layers in sandstones. The third diagenetic stage in quartz sandstones is associated with the migration of underground gas-water solutions. Analysis of the transformation degree of the Pashyisky horizon quartz sandstones at different areas of the Romashkinskoye field revealed the relationship between the intensity of secondary diagenetic processes and the degree of rocks oil saturation. Keywords: pashyisky horizon; oil; sandstone; reservoir; diagenesis.

Integrated Porosity Classification and Quantification Scheme for Enhanced Carbonate Reservoir Quality: Implications from the Miocene Malaysian Carbonates

The pore system in carbonates is complicated because of the associated biological and chemical activity. Secondary porosity, on the other hand, is the result of chemical reactions that occur during diagenetic processes. A thorough understanding of the carbonate pore system is essential to hydrocarbon prospecting. Porosity classification schemes are currently limited to accurately forecast the petrophysical parameters of different reservoirs with various origins and depositional environments. Although rock classification offers a way to describe lithofacies, it has no impact on the application of the poro-perm correlation. An outstanding example of pore complexity (both in terms of type and origin) may be found in the Central Luconia carbonate system (Malaysia), which has been altered by diagenetic processes. Using transmitted light microscopy, 32 high-resolution pictures were collected of each thin segment for quantitative examination. An FESEM picture and a petrographic study of thin sections were used to quantify the grains, matrix, cement, and macroporosity (pore types). Microporosity was determined by subtracting macroporosity from total porosity using a point-counting technique. Moldic porosity (macroporosity) was shown to be the predominant type of porosity in thin sections, whereas microporosity seems to account for 40 to 50% of the overall porosity. Carbonates from the Miocene have been shown to possess a substantial quantity of microporosity, making hydrocarbon estimate and production much more difficult. It might lead to a higher level of uncertainty in the estimation of hydrocarbon reserves if ignored. Existing porosity classifications cannot be used to better understand the poro-perm correlation because of the wide range of geological characteristics. However, by considering pore types and pore structures, which may be separated into macro- and microporosity, the classification can be enhanced. Microporosity identification and classification investigations have become a key problem in limestone reservoirs across the globe.

The impact of diagenesis on the reservoir quality of the early Cretaceous Lower Goru sandstones in the Lower Indus Basin, Pakistan

The sandstone units of the Early Cretaceous Lower Goru Formation are significant reservoir for gas, oil, and condensates in the Lower Indus Basin of Pakistan. Even though these sandstones are significant reservoir rocks for hydrocarbon exploration, the diagenetic controls on the reservoir properties of the sandstones are poorly documented. For effective exploration, production, and appraisal of a promising reservoir, the diagenesis and reservoir properties must be comprehensively analyzed first. For this study, core samples from depths of more than 3100 m from the KD-01 well within the central division of the basin have been studied. These sandstones were analyzed using petrographic, X-ray diffraction, and scanning electron microscopic analyses to unravel diagenetic impacts on reservoir properties of the sandstone. Medium to coarse-grained and well-sorted sandstone have been identified during petrographic study. The sandstone are categorized as arkose and lithic arkose. Principal diagenetic events which have resulted in changing the primary characters of the sandstones are compaction, cementation, dissolution, and mineral replacement. The observed diagenetic processes can be grouped into early, burial, and late diagenesis. Chlorite is the dominant diagenetic constituent that occurs as rims, coatings, and replacing grains. The early phase of coating of authigenic chlorite has preserved the primary porosity. The recrystallization of chlorite into chamosite has massively reduced the original pore space because of its bridging structure. The current study reveals that diagenetic processes have altered the original rock properties and reservoir characteristics of the Lower Goru sandstone. These preliminary outcomes of this study have great potential to improve the understanding of diagenetic process and their impact on reservoir properties of the Lower Goru sandstone in the Lower Indus Basin and adjoining areas.

Petrofacies investigations of the Cretaceous Pab Formation Rakhi Gorge Eastern Sulaiman Range Pakistan - Implication for reservoir potential

Petrologic investigations of the sixty representative thin sections from the Pab Formation within Rakhi Gorge section Eastern Sulaiman Range Pakistan have been used to characterize different diagenetic patterns, identification of primary composition and reservoir characters. Sublithic, lithic and quartzose sandstones have been the principal constituents of the formation. The processes responsible for the late-stage alteration and diagenetic processes identified during the petrographic study include compaction of lithic fragments and mud clasts, formation of quartz overgrowth structures, feldspar replacement and alteration, cementation, and replacement of grains by clay minerals other ferrous elements and diagenetic minerals. The study shows that the initial porosity has been primary intergranular, but the secondary porosity has been originated in the rocks as a result of the alteration of the primary and secondary constituents, as well as fracturing. These facies characters replicate the reservoir quality including, good, medium, low-quality, and non-reservoir. Samples displaying average total porosity greater than 10 % have been declared as good quality. While rocks samples having 7 % or greater porosity are grouped as a medium reservoir. Those samples consisting of porosity values between 1 and 4% are considered as a low quality reservoir while those samples having porosity ranges low than 1% have been called non-reservoir. Based on the investigated parameters the studied samples from the Pab Formation displayed the characters of a medium reservoir that may hold significant hydrocarbon. This different quality including good and low quality zonation can be attributed to the facies and diagenetic change in the formation.

Anthropogenic Inputs of Terrestrial Organic Matter Influence Carbon Loading and Methanogenesis in Coastal Baltic Sea Sediments

Coastal regions globally have experienced widespread anthropogenic eutrophication in recent decades. Loading of autochthonous carbon to coastal sediments enhances the demand for electron acceptors for microbial remineralization, often leading to rearrangement of the sediment diagenetic zonation and potentially enhancing fluxes of methane and hydrogen sulfide from the seafloor. However, the role of anthropogenic inputs of terrestrial organic matter (OMterr.) in modulating diagenesis in coastal sediments is often overlooked, despite being of potential importance in regions of land-use and industrial change. Here we present a dated 4-m sediment and porewater geochemistry record from a eutrophic coastal location in the northern Baltic Sea, to investigate sources of recent carbon loading and their impact on modern diagenetic processes. Based on an end-member mixing model of sediment N/C ratios, we observe that a significant fraction of the late-20th century carbon loading at this location was contributed by OMterr.. Furthermore, analysis of lignin in this material shows depleted ratios of syringyl/vanillyl (S/V) and cinnamyl/vanillyl (C/V) phenols, indicative of enhanced inputs of woody gymnosperm tissue likely from forest industries. The rapid loading of organic matter from combined terrestrial and autochthonous sources during the late 20th century has stimulated methanogenesis in the sediment column, and shoaled the sulfate-methane transition zone (SMTZ) to a depth of 5–20 cm. Optical parameters of colored dissolved organic matter confirm that OMterr. is actively degrading in the methanogenic layer, implying a role for this material in diagenetic processes. Porewater CH4, SO42− δ13C-DIC, and ∑S2− data suggest that the modern SMTZ is a broad zone in which organoclastic sulfate reduction, methanogenesis and anaerobic oxidation of methane (AOM) co-occur. However, fluxes of CH4 and SO42− show that rates of these processes are similar to other marine locations with a comparably shallow SMTZ. We suggest that the shallow depth of the modern SMTZ is the principal reason for high observed diffusive and ebullitive methane fluxes from sediments in this area. Our results highlight that anthropogenic activities lead to multiple pathways of carbon loading to coastal sediments, and that forest industry impacts on sedimentation in the northern Baltic Sea may be more widespread than previously acknowledged.

Joint Application of Diagenetic, Petrophysical and Geomechanical Data for Selecting Hydraulic Fracturing Candidate Zone

The more comprehensive information on the reservoir properties will help to better plan drilling and design production. Herein, diagenetic processes and geomechanical properties are notable parameters that determine reservoir quality. Recognizing the geomechanical properties of the reservoir as well as building a mechanical earth model play a strong role in the hydrocarbon reservoir life cycle and are key factors in analyzing wellbore instability, drilling operation optimization, and hydraulic fracturing designing operation. Therefore, the present study focuses on selecting the candidate zone for hydraulic fracturing through a novel approach that simultaneously considers the diagenetic, petrophysical, and geomechanical properties. The diagenetic processes were analyzed to determine the porosity types in the reservoir. After that, based on the laboratory test results for estimating reservoir petrophysical parameters, the zones with suitable reservoir properties were selected. Moreover, based on the reservoir geomechanical parameters and the constructed mechanical earth model, the best zones were selected for hydraulic fracturing operation in one of the Iranian fractured carbonate reservoirs. Finally, a new empirical equation for estimating pore pressure in nine zones of the studied well was developed. This equation provides a more precise estimation of stress profiles and thus leads to more accurate decision-making for candidate zone selection. Based on the results, vuggy porosity was the best porosity type, and zones C2, E2 and G2, having suitable values of porosity, permeability, and water saturation, showed good reservoir properties. Therefore, zone E2 and G2 were chosen as the candidate for hydraulic fracturing simulation based on their E (Young’s modulus) and ν (Poisson’s ratio) values. Based on the mechanical earth model and changes in the acoustic data versus depth, a new equation is introduced for calculating the pore pressure in the studied reservoir. According to the new equation, the dominant stress regime in the whole well, especially in the candidate zones, is SigHmax>SigV>Sighmin, while according to the pore pressure equation presented in the literature, the dominant stress regime in the studied well turns out to be SigHmax>Sighmin>SigV.

Prediction and Early Detection of Karsts—An Overview of Methods and Technologies for Safer Drilling in Carbonates

The nature of carbonate deposition as well as diagenetic processes can cause the development of unique geological features such as cavities, vugs and fractures. These are called karsts. Encountering karsts while drilling can lead to serious consequences such as severe mud losses, drops of bottom hole assembly and gas kicks. To improve drilling safety in intervals of karstification, it is important to detect karsts as early as possible, preferably in advance. In this paper, we review methods and technologies that can be used for the prediction and early detection of karsts. In particular, we consider acoustic, resistivity, seismic and drilling-data methods. In addition to the inventions and technologies developed and published over the past 40 years, this paper identifies the advantages, limitations and gaps of these existing technologies and discusses the most promising methods for karst detection and prediction.