A Reactor System for Mineral Leaching Investigations

Author(s):  
T. Babij ◽  
R. B. Doble ◽  
B. J. Ralph
Author(s):  
T. Babij ◽  
R. B. Doble ◽  
B. J. Ralph

Author(s):  
Lorn Messner ◽  
Marieke H. Antink ◽  
Tongwei Guo ◽  
Michael Maas ◽  
Sascha Beutel

2010 ◽  
Vol 22 (2) ◽  
pp. 230-236 ◽  
Author(s):  
Rohan Jain ◽  
Ashish Pathak ◽  
T.R. Sreekrishnan ◽  
M.G. Dastidar

2009 ◽  
Vol 71-73 ◽  
pp. 437-440
Author(s):  
Lasse Ahonen ◽  
Pauliina Nurmi ◽  
Olli H. Tuovinen

Geochemical modeling program PHREEQC was used to simulate generic bioleaching processes. Carbonate minerals (e.g., calcite) dissolve in acid solution, increasing the solution pH and Ca concentration while the concentration of CO2 may be controlled by the equilibrium with the atmospheric CO2. Non-oxidative dissolution of Fe-monosulphides was demonstrated to release H2S and increase the pH. In the absence of ferric iron precipitation (goethite), the oxidation of pyrite decreased the solution pH from 2 to ~1.4, while the oxidation of Fe-monosulphide and chalcopyrite increased the solution pH to ~3.2-3.4. Assuming equilibrium precipitation of goethite, oxidative leaching decreased the solution pH for all three minerals from pH ~2 to ~0.9-1.2. Adjustment of the solution pH to 1.8 or 2.0 with KOH with concurrent equilibrium precipitation of K-jarosite resulted in low dissolved iron concentrations.


Sign in / Sign up

Export Citation Format

Share Document