Effect of gas flow rate and discharge volume on CO2 methanation with plasma catalysis

CO2 methanation can be a key technology for realizing a sustainable society. CH4 is used as an energy carrier and raw material for chemical products, thereby contributing to the reduction of CO2 emissions. Methanation with plasma catalysis lower the process temperature, which can improve the throughput and stability. In this study, we investigated the effect of the gas flow rate and the discharge volume on CO2 methanation, using a low- pressure CCP reactor. Higher gas flow rates can increase the rate of CO2 throughput, but the CH4 selectivity decreases owing to the reduced transportation rate of the reactants to the catalyst surface. Increasing the discharge volume is effective in improving the transportation rate. This study suggested that the structure of the reactor significantly affect the CH4 generation rate.

Treatment of C.I Reactive Blue 160 by ozonation system

This study was carried out to assess the treatment ability of color, dye, and COD in the dyeing wastewater containing C.I Reactive Blue 160 by ozonation system. Both batch and continuous operating modes with concurrent and counter-current flows were investigated. The effects of the ozone gas flow rate, pH, temperature, Na2CO3 concentration, and initial dye concentration were evaluated. The decolorization, dye removal efficiencies, and mineralization ability of COD by ozonation were determined. The results indicated that ozonation had high efficiency in the treatment of dyeing wastewater containing C.I Reactive Blue 160. The treatment performance was affected by the ozone gas flow rate, pH, temperature, Na2CO3 concentration, and initial dye concentration. The removal efficiency of color, dye, and COD were 98.04%, 99.84%, and 87.31% for the treatment of 200 mg/L initial dye concentration in batch mode with 30 min ozonation time, respectively. In the continuous operation and counter-current flow, the color, dye, and COD removal efficiencies reached 97.24%, 99.76%, and 86.38% after 30 min HRT, respectively, and higher than concurrent flow. The reaction of ozone and C. I Reactive Blue 160 was the first-order reaction in both batch and continuous operation. The complete mineralization required 90 min ozonation time.

Process Parameters Optimization for GMA Welding of AISI 1008 Steel Joints for Optimal Tensile Strength

Parameters optimization has become a gateway to achieving quality welds with improved properties desirable for construction and industrial applications. The complex interaction of welding input parameters requires process optimization to achieve optimal responses (s). This study reports the optimization of input parameters for Gas Metal Arc Welding (GMAW) for optimal ultimate tensile strength in AISI 1008 steel joints. Three levels of arc voltage, welding current, and gas flow rate were selected as input parameters, while the targeted output response is the ultimate tensile strength. Taguchi’s method with an L-9 orthogonal matrix was adopted for the process optimization. The MINITAB 17 software was used to analyze the response through analysis of variance and signal-to-noise ratio. The result revealed that the parameter settings for optimal tensile strength for the GMA welding of 6 mm thick AISI 1008 steel joint are arc voltage set at 30 V, current at 180 A, and gas flow rate set at 17 L/mm. The analysis of variance showed that the arc voltage had the most significant influence on the ultimate tensile strength with a 39.76% contribution, followed by the gas flow rate with 31.15%, while the welding current had 6.28% contributions. The surface plots show that a lower-level voltage, higher-level welding current, and higher-level gas flow rate favoured maximum ultimate tensile strength.

FEATURES FORMATION ZONE OF WAVES AND BURSTS ON THE SURFACE LADLE BATH

The results studies influence physicochemical properties and thickness cover slag, formed during ladle desulfurization pig iron by blowing a mixture of lime and magnesium, features formation a breaker on the surface bath and the level of metal losses with emissions outside ladle from this zone are presented. The necessity creating conditions for ensuring height breaker, which would not exceed thickness slag layer on the surface bath, has been substantiated. Using results of the high-temperature simulation blowing the cast iron melt with a neutral gas supplied through the nozzles tips stationary and rotating submersible lances, features development of counter waves and metal splashes in the absence and during formation slag cover with thickness of 30—80 mm on the surface bath are determined. The features change in the height and area breakers are determined depending on the gas flow rate for blowing bath and thickness slag. Based on the analysis results low-temperature modeling bath blowing, scientific ideas about the combined effect of the bath blowing intensity, speed of rotation submerged lance and thickness slag layer on the diameter bubbling zone, gas saturation of the bath and features wave formation on its surface in the slag-free zone were further developed (so-called «eye»). The nature relationship between length of the gas jet from lance nozzle, diameter «eye», and geometric parameters breaker has been established. It is shown that dependence profile breaker on speed of rotation lance and thickness slag layer is nonlinear. So, blowing bath through tip of a rotating lance with one nozzle at 240 rpm. with a gas flow rate of 2.2 l/min. creates conditions for raising top breaker to a height that is 33 % higher than the current thickness slag layer and contributes to the intensification formation of waves and bursts on the surface bath. With a decrease in the gas flow rate to 1.0 l/min., Under other unchanged conditions, height breaker is already 2/3 of the height slag layer, and as thickness slag decreases proportionally decreases. The smallest, recorded in the experiments, relative height breaker was 33.3% of the slag thickness at a lance rotation speed in the range of 90—120 rpm. Mathematical models are proposed that are suitable for calculating height breakers depending on the thickness slag layer, speed of rotation lance and intensity of gas injection into the bath. Taking into account established mutually opposite effect thickness of the cover slag layer and speed of rotation submerged lance on the «eye» area and height of the breaker, it is advisable to continue search for ways to improve design tip submerged lance and slag mode of ladle desulfurization.

End Plate Effects on the Performance of PEMFCs During Cold Start Process

The efficient, fast, and reliable cold start of polymer electrolyte membrane fuel cells is one of the major challenges for their commercialization. In this paper a segmented single cell is used to simulate the end plate effects of the stack and to investigate how the effects work. The results demonstrate that the end cells in the stack have the lowest performance, the reasons for which include the lowest temperature of the cells themselves, and probably also ice blocking in part an area inside the MEA, or in the channels, or in both together. In order to mitigate or even eliminate the influence of ice formation in the end cells, the temperature of the end plates should be increased to -10℃ or above when liquid water is generated. A high inlet gas flow rate facilitates the discharge of supercooled water and is conducive to successful cold start.

Numerical Simulation of Gas Phase Reaction for Epitaxial Chemical Vapor Deposition of Silicon Carbide by Methyltrichlorosilane in Horizontal Hot-Wall Reactor

Methyltrichlorosilane (CH3SiCl3, MTS) has good performance in stoichiometric silicon carbide (SiC) deposition and can be facilitated at relatively lower temperature. Simulations of the chemical vapor deposition in the two-dimensional horizontal hot-wall reactor for epitaxial processes of SiC, which were prepared from MTS-H2 gaseous system, were performed in this work by using the finite element method. The chemistry kinetic model of gas-phase reactions employed in this work was proposed by other researchers. The total gas flow rate, temperature, and ratio of MTS/H2 were the main process parameters in this work, and their effects on consumption rate of MTS, molar fraction of intermediate species and C/Si ratio inside the hot reaction chamber were analyzed in detail. The phenomena of our simulations are interesting. Both low total gas flow rate and high substrate temperature have obvious effectiveness on increasing the consumption rate of MTS. For all cases, the highest three C contained intermediates are CH4, C2H4 and C2H2, respectively, while the highest three Si/Cl contained intermediates are SiCl2, SiCl4 and HCl, respectively. Furthermore, low total gas flow results in a uniform C/Si ratio at different temperatures, and reducing the ratio of MTS/H2 is an interesting way to raise the C/Si ratio in the reactor.

Plasma degradation of trichloroethylene: Process optimization and reaction mechanism analysis

In this study, a multi-pin-to-plate negative glow discharge reactor was employed to degrade the hazardous compound, trichloroethylene (TCE). The response surface methodology (RSM) was applied to examine the influences of various process factors (relative humidity (RH), gas flow rate, and discharge power) on the TCE decomposition process, with regard to the TCE removal efficiency, CO2 and CO selectivities. The variance analysis was used to estimate the significance of the single process factors and their interactions. It has been proved that the discharge power had the utmost influential impact on the TCE removal efficiency, CO2 and CO selectivities, subsequently the gas flow rate, and finally RH. Under the optimal conditions with 20.83% RH, 2 W discharge power and 0.5 L·min–1 gas flow rate, the optimal TCE removal efficiency (86.05%), CO2 selectivity (8.62%), and CO selectivity (15.14%) were achieved. In addition, a possible TCE decomposition pathway was proposed based on the investigation of byproducts identified in the exhaust gas of the NTP reactor. This work paves a way for the control of chlorinated volatile organic compounds.

Effect of Mold Width on the Flow Field in a Slab Continuous-Casting Mold with High-Temperature Velocity Measurement and Numerical Simulation

In this paper, the effects of the width of the mold on the surface velocity, flow field pattern, turbulent kinetic energy distribution, and surface-level fluctuation in the mold were studied with measurement of the flow velocity near the surface of the mold at high temperature with the rod deflection method and numerical calculation with the standard k-ε model coupled with the discrete-phase model (DPM) model for automobile exposed panel production. Under the conditions of low fixed steel throughput of 2.2 ton/min, a nozzle immersion depth of 140 mm, and an argon gas flow rate of 4 L/min, as the width of the mold increases from 880 mm to 1050 mm and 1300 mm, the flow velocity near the surface of the mold decreases. The flow direction changes from the positive velocity with the mold widths of 880 mm and 1050 mm to the unstable velocity with the mold width of 1300 mm. The calculated results are in good agreement with the measured results. The turbulent kinetic energy near the submerged entry nozzle (SEN) gradually increases, and the risk of slag entrainment increases. Under the conditions of high fixed steel throughput of 3.5 ton/min, the SEN immersion depth of 160 mm, and the argon gas flow rate of 10 L/min, as the width of the mold increases from 1600 mm to 1800 mm and 2000 mm, the velocity near the mold surface decreases. The flow velocity at 1/4 of the surface of the mold is positive with the mold width of 1600 mm, while the velocities are negative with the widths of 1800 mm and 2000 mm. The calculated results are basically consistent with the measured results. The high turbulent kinetic energy area near the nozzle expands to a narrow wall, and the risk of slag entrainment is significantly increased. In both cases of low and high fixed steel throughput, the change rules of the flow field in the mold with the width are basically the same. The argon gas flow rate and the immersion depth of SEN should be adjusted reasonably to optimize the flow field in the mold with different widths under the same fixed steel throughput in the practical production.

Effects of Different Carbonization Conditions on the Color Change of Biochar

The aim of this research was to determine the effects of different carbonization temperature, gas flow rate and heating rates on biochar's color change. Three different carbonization temperatures (400°C, 500°C, and 600°C), two different gas flow rates (0.2 l min-1 and 0.5 l min-1) and two different heating temperature rates (30°C min-1 and 60°C min-1) were used in the experiments. The color changes of biochar were examined utilizing the international approved L*, a*, b* system. Atriplex nitens Schkuhr was used as a biomass source in the experiments. High carbonization temperature and high gas flow rate caused a decrease in the “L” value of biochar. It is an indication that the color is getting darker, when the L value approaches zero. In the study, only the effect of gas flow rate on the "a" value was found to be statistically significant (P≤0.05). The increase in gas flow rate caused the biochar to become darker by increasing the deep red tone. Heating rate and gas flow speed significantly influenced the "b" values of biochar. The slow heating rate and high gas flow rates made the biochar color darker. At end of the research, it can be said that the biochar produced at high carbonization temperature, low heating rate and high gas flow rates will have darker tones.