Disproportionation Equilibrium in Iron-Bearing Systems at Pressures above 100 Kbar with Applications to Chemistry of the Earth’s Mantle

Author(s):  
H. K. Mao ◽  
P. M. Bell
2016 ◽  
Vol 2 (7) ◽  
pp. e1600427 ◽  
Author(s):  
Leyla Ismailova ◽  
Elena Bykova ◽  
Maxim Bykov ◽  
Valerio Cerantola ◽  
Catherine McCammon ◽  
...  

The physical and chemical properties of Earth’s mantle, as well as its dynamics and evolution, heavily depend on the phase composition of the region. On the basis of experiments in laser-heated diamond anvil cells, we demonstrate that Fe,Al-bearing bridgmanite (magnesium silicate perovskite) is stable to pressures over 120 GPa and temperatures above 3000 K. Ferric iron stabilizes Fe-rich bridgmanite such that we were able to synthesize pure iron bridgmanite at pressures between ~45 and 110 GPa. The compressibility of ferric iron–bearing bridgmanite is significantly different from any known bridgmanite, which has direct implications for the interpretation of seismic tomography data.


Nature ◽  
2020 ◽  
Vol 586 (7830) ◽  
pp. 506-507
Author(s):  
Laura Cobden
Keyword(s):  

2007 ◽  
Vol 14 (2) ◽  
pp. 13-19 ◽  
Author(s):  
Man-sheng Chu ◽  
Xian-zhen Guo ◽  
Feng-man Shen ◽  
Jun-ichiro Yagi ◽  
Hiroshi Nogami

A phase change may hinder or enhance convection, depending on its characteristics. Univariant transformations such as may occur in the mantle constitute a barrier to convection unless the motion starts at some distance above or below the transition level; an initial temperature gradient in excess of the adiabatic value is also required. Multivariant transformations only require, in the transformation zone, an initial gradient slightly greater than the adiabatic value for a homogeneous layer. The effect on convection of transformation rates is not likely to be serious.


1968 ◽  
Vol 1 (3) ◽  
pp. 198-199
Author(s):  
D.W. Collinson
Keyword(s):  

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