Metal Speciation: Survey of Environmental Methods of Analysis

Author(s):  
Martin H. Mach ◽  
Babu Nott ◽  
Judith W. Scott ◽  
Raymond F. Maddalone ◽  
Nina T. Whiddon
1996 ◽  
Vol 90 (1-2) ◽  
pp. 269-279 ◽  
Author(s):  
Martin H. Mach ◽  
Babu Nott ◽  
Judith W. Scott ◽  
Raymond F. Maddalone ◽  
Nina T. Whiddon

Author(s):  
O. A. Lipatnikova

The study of heavy metal speciation in bottom sediments of the Vyshnevolotsky water reservoir is presented in this paper. Sequential selective procedure was used to determine the heavy metal speciation in bottom sediments and thermodynamic calculation — to determine ones in interstitial water. It has been shown that Mn are mainly presented in exchangeable and carbonate forms; for Fe, Zn, Pb и Co the forms are related to iron and manganese hydroxides is played an important role; and Cu and Ni are mainly associated with organic matter. In interstitial waters the main forms of heavy metal speciation are free ions for Zn, Ni, Co and Cd, carbonate complexes for Pb, fulvate complexes for Cu. Effects of particle size and organic matter content in sediments on distribution of mobile and potentially mobile forms of toxic elements have been revealed.


2018 ◽  
Vol 40 (1) ◽  
pp. 25-53 ◽  
Author(s):  
David MacInnes

The nature of social organization during the Orcadian Neolithic has been the subject of discussion for several decades with much of the debate focused on answering an insightful question posed by Colin Renfrew in 1979. He asked, how was society organised to construct the larger, innovative monuments of the Orcadian Late Neolithic that were centralised in the western Mainland? There are many possible answers to the question but little evidence pointing to a probable solution, so the discussion has continued for many years. This paper takes a new approach by asking a different question: what can be learned about Orcadian Neolithic social organization from the quantitative and qualitative evidence accumulating from excavated domestic structures and settlements?In an attempt to answer this question, quantitative and qualitative data about domestic structures and about settlements was collected from published reports on 15 Orcadian Neolithic excavated sites. The published data is less extensive than hoped but is sufficient to support a provisional answer: a social hierarchy probably did not develop in the Early Neolithic but almost certainly did in the Late Neolithic, for which the data is more comprehensive.While this is only one approach of several possible ways to consider the question, it is by exploring different methods of analysis and comparing them that an understanding of the Orcadian Neolithic can move forward.


2020 ◽  
Vol 23 (8) ◽  
pp. 922-939
Author(s):  
N.V. Malinovskaya ◽  
M.D. Malinovskii

Subject. This article deals with the issues relating to improving integrated reporting in terms of dovetailing strategic objectives with capital changes. Objectives. The article aims to develop a system of indicators for disclosure of capital types in integrated reporting of electricity generating companies, as well as recommendations aimed at implementing the fundamental concepts and guiding principles of integrated reporting. Methods. For the study, we used the methods of analysis and synthesis, comparison, generalization, and abstraction. As a case study, we conduct a comparative analysis of the disclosure of six types of capital by the largest electricity generating companies, namely PAO Inter RAO, AO Rosenergoatom and PAO RusHydro. Results. The article formulates proposals for disclosure of capital information to address such a lack of accountability as a contradiction to the principle of coherence. It proposes a system of indicators (core and additional) for disclosure of six types of capital by electricity generating companies. Conclusions. A significant reporting problem is the lack of correlation between key strategic objectives and capital changes. The formulated recommendations for disclosure of capital information can help solve this problem, and increase the attractiveness of the integrated report for capital providers.


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