Influence of Pore Distribution Characteristics on Relative Hydraulic Conductivity in Soil Covers—A Pore-Scale Numerical Investigation

Author(s):  
Guangyao Li ◽  
Liangtong Zhan ◽  
Sheng Dai
2020 ◽  
Author(s):  
Kirill Gerke ◽  
Marina Karsanina

<p>Classic soil physics relies heavily on the concept of representative elementary volume (REV), which is necessary to perform upscaling from the studied soil samples and parameterize continuum scale hydrological models (e.g., based on Richards equation). In this paper we explore the boundaries of the classic REV concept and conventional representativity studies that claim REV for a given physical property if its values converge to a steady value with increasing sample’s volume. We chose two conventional undisturbed soil samples from Ah and B horizons and performed pore-scale flow simulations based on their X-ray microtomography scans. The volumes of the simulation domains were 729 million of voxels with a physical volume within the order of magnitude of the whole soil core. Based on 3D pore geometry images and resulting flow velocity and pressure fields we performed REV analysis for saturated hydraulic conductivity and porosity. To further facilitate the REV analysis, we also evaluated the stationarity of pore structures by computing directional correlation functions for studied images. We concluded that neither of the studied samples can be considered to be representative due to its structural non-stationarity, which reflects on the behavior of Ksat values within the subcubes of different volume within the samples. In this contribution we extensively discuss the implications of such results. While it was possible to show that studied soil samples are not REVs for saturated hydraulic conductivity, we were unable to establish any relevant domain length scale. The latter may require tensorial flow property analysis with correct boundary conditions (Gerke et al., 2019), multi-scale soil structure imaging (Gerke et al., 2015; Karsanina et al., 2018; Karsanina and Gerke, 2018) and pore-scale simulations on fused multi-scale images (Miao et al., 2017; Gerke et al., 2018).</p><p>This work was supported by Russian Foundation for Basic Research grant 20-54-12030 ННИО_а and 18-34-20131 мол_а_вед.</p><p>References:</p><p>Karsanina, M. V., Gerke, K. M., Skvortsova, E. B., Ivanov, A. L., & Mallants, D. (2018). Enhancing image resolution of soils by stochastic multiscale image fusion. Geoderma, 314, 138-145.</p><p>Gerke, K. M., Karsanina, M. V., & Mallants, D. (2015). Universal stochastic multiscale image fusion: an example application for shale rock. Scientific reports, 5, 15880.</p><p>Gerke, K. M., Vasilyev, R. V., Khirevich, S., Collins, D., Karsanina, M. V., Sizonenko, T. O., Korost D.V., Lamontagne S., & Mallants, D. (2018). Finite-difference method Stokes solver (FDMSS) for 3D pore geometries: Software development, validation and case studies. Computers & Geosciences, 114, 41-58</p><p>Karsanina, M. V., & Gerke, K. M. (2018). Hierarchical Optimization: Fast and Robust Multiscale Stochastic Reconstructions with Rescaled Correlation Functions. Physical Review Letters, 121(26), 265501.</p><p>Miao, X., Gerke, K. M., & Sizonenko, T. O. (2017). A new way to parameterize hydraulic conductances of pore elements: A step towards creating pore-networks without pore shape simplifications. Advances in Water Resources, 105, 162-172.</p><p>Gerke, K. M., Karsanina, M. V., & Katsman, R. (2019). Calculation of tensorial flow properties on pore level: Exploring the influence of boundary conditions on the permeability of three-dimensional stochastic reconstructions. Physical Review E, 100(5), 053312.</p>


Author(s):  
Zhongping Huang ◽  
Weiming Zhang ◽  
Sonja M. Tang ◽  
Jianping Yu ◽  
Stephen J. Lai-Fook ◽  
...  

The non-uniformity of pore size and pore distribution of the current hemodialysis membrane results in low efficiency of uremic solute removal as well as the loss of albumin. By using nano technology, an anodic alumina membrane (ceramic membrane) with self-organized nano-pore structure was produced. The objective of this study was to investigate the correlation between various anodization conditions and the pore characteristics of the ceramic membrane as a potential use in artificial kidney / hemodialysis. An aluminum thin film was oxidized in two electrolytes consisting of 3% and 5% sulfuric acid and 2.7% oxalic acid. The applied voltages were 12.5, 15, 17.5 and 20 (V) for sulfuric acid and 20, 30, 40 and 50 (V) for oxalic acid. Pore size and porosity were determined by analyzing scanning electron microscopy (SEM) images and hydraulic conductivity was measured. Pore size increased linearly with voltage. Acid concentration affected pore formation but not pore size and pore distribution. Hydraulic conductivity of the ceramic membrane was higher than that of polymer dialysis membrane. The optimal formation conditions for self-organized nano-pore structure of ceramic membrane were 12.5–17.5V in 3–5% sulfuric acid at 0 °C. These conditions produced ceramic membranes with pores of ~ 10 nm diameter. Conclusion: Anodic alumina technology reliably produced in quantity structures with pore sizes in the 10–50 nm diameter range. Because of more uniform pore size, high porosity, high hydraulic conductivity and resistance to high temperature, the ceramic membrane has potential for future application as a hemodialysis membrane.


Sign in / Sign up

Export Citation Format

Share Document