Nucleation of Precipitates on Multiple Habit Planes in an Artificially Aged AA2618 Alloy

Author(s):  
Rajdeep Sarkar ◽  
A. K. Mukhopadhyay ◽  
Partha Ghosal ◽  
Vipin S. Ramteke ◽  
Deepak Kumar
Keyword(s):  
Author(s):  
C. J. D. Hetherington

Most high resolution images are not directly interpretable but must be compared with simulations based on model atomic structures and appropriate imaging conditions. Typically, the only parameters that are adjusted, in addition to the structure models, are crystal thickness and microscope defocus. Small tilts of the crystal away from the exact zone axis have only rarely been considered. It is shown here that, in the analysis of an image of a silicon twin intersection, the crystal tilt could be accurately estimated and satisfactorily included in the simulations.The micrograph shown in figure 1 was taken as part of an HREM study of indentation-induced hexagonal silicon. In this instance, the intersection of two twins on different habit planes has driven the silicon into hexagonal stacking. However, in order to confirm this observation, and in order to investigate other defects in the region, it has been necessary to simulate the image taking into account the very apparent crystal tilt. The inability to orientate the specimen at the exact [110] zone was influenced by i) the buckling of the specimen caused by strains at twin intersections, ii) the absence of Kikuchi lines or a clearly visible Laue circle in the diffraction pattern of the thin specimen and iii) the avoidance of radiation damage (which had marked effects on images taken a few minutes later following attempts to realign the crystal.) The direction of the crystal tilt was estimated by observing which of the {111} planes remained close to edge-on to the beam and hence strongly imaged. Further refinement of the direction and magnitude of the tilt was done by comparing simulated images to experimental images in a through-focal series. The presence of three different orientations of the silicon lattice aided the unambiguous determination of the tilt. The final estimate of a 0.8° tilt in the 200Å thick specimen gives atomic columns a projected width of about 3Å.


Author(s):  
Theresa M. Simon

AbstractWe analyze generic sequences for which the geometrically linear energy $$\begin{aligned} E_\eta (u,\chi )\,{:}{=} \,\eta ^{-\frac{2}{3}}\int _{B_{1}\left( 0\right) } \left| e(u)- \sum _{i=1}^3 \chi _ie_i\right| ^2 \, \mathrm {d}x+\eta ^\frac{1}{3} \sum _{i=1}^3 |D\chi _i|({B_{1}\left( 0\right) }) \end{aligned}$$ E η ( u , χ ) : = η - 2 3 ∫ B 1 0 e ( u ) - ∑ i = 1 3 χ i e i 2 d x + η 1 3 ∑ i = 1 3 | D χ i | ( B 1 0 ) remains bounded in the limit $$\eta \rightarrow 0$$ η → 0 . Here $$ e(u) \,{:}{=}\,1/2(Du + Du^T)$$ e ( u ) : = 1 / 2 ( D u + D u T ) is the (linearized) strain of the displacement u, the strains $$e_i$$ e i correspond to the martensite strains of a shape memory alloy undergoing cubic-to-tetragonal transformations and the partition into phases is given by $$\chi _i:{B_{1}\left( 0\right) } \rightarrow \{0,1\}$$ χ i : B 1 0 → { 0 , 1 } . In this regime it is known that in addition to simple laminates, branched structures are also possible, which if austenite was present would enable the alloy to form habit planes. In an ansatz-free manner we prove that the alignment of macroscopic interfaces between martensite twins is as predicted by well-known rank-one conditions. Our proof proceeds via the non-convex, non-discrete-valued differential inclusion $$\begin{aligned} e(u) \in \bigcup _{1\le i\ne j\le 3} {\text {conv}} \{e_i,e_j\}, \end{aligned}$$ e ( u ) ∈ ⋃ 1 ≤ i ≠ j ≤ 3 conv { e i , e j } , satisfied by the weak limits of bounded energy sequences and of which we classify all solutions. In particular, there exist no convex integration solutions of the inclusion with complicated geometric structures.


2016 ◽  
Vol 49 (4) ◽  
pp. 1223-1230 ◽  
Author(s):  
Xueli Wang ◽  
Huilan Huang ◽  
Xinfu Gu ◽  
Yanjun Li ◽  
Zhihong Jia ◽  
...  

The orientation relationships (ORs) between the Al matrix and Si2Hf precipitates with an orthorhombic structure in an Al–Si–Mg–Hf alloy after heat treatment at 833 K for 20 h were investigated by transmission electron microscopy and electron diffraction. Four ORs are identified as (100)Al||(010)p, (0\overline {1}1)Al||(101)pand [011]Al||[\overline {1}01]p; (11\overline {1})Al||(010)pand [011]Al||[\overline {1}01]p; (12\overline {1})Al||(010)p, (101)Al||(100)pand [1\overline {11}]Al||[001]p; (\overline {11}1)Al||(010)pand [112]Al||[\overline {1}01]p. The habit planes of these four ORs are rationalized by the fraction of good atomic matching sites at the interface. In addition, the formation of Si2Hf precipitates with a nanobelt-like morphology is interpreted on the basis of the near-coincident site lattice distribution.


1996 ◽  
Vol 442 ◽  
Author(s):  
X. Duan ◽  
J. Palm ◽  
B. Zheng ◽  
M. Morse ◽  
J. Michel ◽  
...  

AbstractA systematic study of defects in the Er/O implanted silicon was conducted using TEM, HRTEM and SIMS. Defect-free material was obtained after the annealing of 400 keV Er+ implanted (100)Si. In sharp contrast, several forms of secondary defects consisting of dislocations, dislocation loops and precipitates were induced upon annealing at different temperatures in the 4.5 MeV implanted (100)Si sample. The isothermal evolution of the defects and reactions between dopants and defects were studied. Oxygen tends to segregate into the dislocation loop zones, where platelet precipitates with habit planes of {111} were found. Following dissociation of oxygen and erbium, plate-like Er precipitates were generated, which are most likely ErSi2 with a habit plane of {111}


RSC Advances ◽  
2015 ◽  
Vol 5 (74) ◽  
pp. 59921-59925 ◽  
Author(s):  
Xiaokun Yuan ◽  
Li Cui ◽  
Yuan Ji ◽  
Xuehong Zhang ◽  
Jie Zhu

In the joint of a 5A90 Al–Li alloy prepared by the Nd:YAG laser welding, the habit planes are textured at different locations, which suggests a potential perspective to understand the crystallographic orientation dependent performances of the joint.


Meteoritics ◽  
1977 ◽  
Vol 12 (4) ◽  
pp. 437-442 ◽  
Author(s):  
Erik Randich ◽  
K.H. Eckelmeyer
Keyword(s):  

1999 ◽  
Vol 14 (2) ◽  
pp. 460-464 ◽  
Author(s):  
K. Fukuda

Crystals of (Ca1.95□0.05) (Si0.9P0.1)O4, where □ denotes a vacancy, composed of both the α′L and β phases, were prepared and examined by the precession method. The β phase was exclusively twinned on (100)β, and the relative volumes of the twin-related variants were almost identical with each other. On the basis of the lattice correspondence between the two phases and their cell parameters, the phenomenological crystallographic theory was applied to determine the habit planes and the shape deformations upon α′L-to-β martensitic transformation. The habit planes, which define the coherent interphase boundaries between α′L and β, were nearly parallel to either (100)α′L or (010)α′L·. The alternate shape deformations that produce the former habit planes resulted in the actual (100) twin structure of the β phase. The total displacement was along [100]α′L with the magnitude of 0.008. Because the transformation involved a very small volumetric shrinkage of 0.6%, the strain accommodation would be almost completed. The coherency at the interface boundaries between the two phases and the effective strain accommodation probably caused the thermoelasticity of the Ca2SiO4 solid solutions.


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