habit planes
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2022 ◽  
Vol 1213 (1) ◽  
pp. 012006
Author(s):  
M P Kashchenko ◽  
N M Kashchenko ◽  
V G Chashchina

Abstract The dynamic theory of martensitic transformations (MT) considers the formation of habit planes of martensite crystals as a consequence of the propagation of a controlling wave process (CWP). The general ideology makes it possible, by comparing the observed habits with calculations of the elastic fields of defects (as a rule, dislocations), to identify nucleation centers. In a number of cases (In-Tl alloys, Ni50Mn50 alloys, Heusler alloys …) under MT in the shape memory alloys, {110} habits are observed (in the basis of the initial cubic phase), which often have a fine twin structure with twin boundaries of the same type. This highly symmetric structure is described by the CWP containing longitudinal waves (both relatively long-wavelength ℓ and short-wavelength s) propagating along the 4-order symmetry axes. In this paper, it is shown that such habits are associated with rectilinear segments of dislocation loops with directions Λ along <001> and Burgers vectors along <010> (or <110>) orthogonal to Λ, both for sliding and for prismatic loops. The tetragonality, the relative volume change during the MT, and the dependence of the start temperature M s on changes in the concentration of alloy components are also briefly discussed.


Author(s):  
A. Leineweber ◽  
A. Walnsch ◽  
P. Fischer ◽  
H. Schumann

AbstractThe microstructure of the martensite formed in Fe–Mn–Al–Ni alloys of varying composition, consisting of A2 austenite and A1-like martensite, was investigated by means of electron backscatter diffraction (EBSD). While sufficiently structured EBSD patterns clearly revealed a tetragonal distortion of the (twinned) martensite, robust indexing using Hough-transform-based methods were successful only by assuming a cubic symmetry of the martensite. It was shown that predictions made based on the Phenomenological Theory of Martensite Crystallography (PTMC) were well compatible with the experimental data, irrespective of the alloy composition. This includes a (near-)Pitsch orientation relationship and habit planes close to {110}A2.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Yuri Shinohara ◽  
Satomu Akabane ◽  
Tomonari Inamura

AbstractHerein, variant-pairing tendencies of lenticular martensite in an Fe–30Ni–0.3C (wt%) alloy are analyzed based on rank-1 connection at martensite/martensite junction planes (JPs) to facilitate the understanding of martensite microstructure. The degree of incompatibility (θ) at the JPs successfully explained their observed frequency; in the actual microstructure, variant pairs with a small θ form preferentially. The experimentally obtained JPs were consistent with theoretical ones. To the best of our knowledge, this is the first study to confirm the validity of variant-pair crystallography in steel based on rank-1 connection, both theoretically and experimentally. Diamond, composite-spear, and composite-kink clusters are considered. The cumulative θ at the JPs can suppress diamond cluster formation because it exceeds the θ of a single variant pair, and the diamond cluster is not observed experimentally. However, θ at the JPs cancel out in composite-spear (CS) and composite-kink (CK) clusters, but CK clusters are rarely observed experimentally, while a few CS clusters are observed. This demonstrates the analytical limitations of 2D approaches used to evaluate the frequency of variant pairs and clusters. These two variant clusters have a narrow window of 2D observation because the orientation relationships between JPs and intersection lines between two habit planes affect the areas of JPs.


Author(s):  
Theresa M. Simon

AbstractWe analyze generic sequences for which the geometrically linear energy $$\begin{aligned} E_\eta (u,\chi )\,{:}{=} \,\eta ^{-\frac{2}{3}}\int _{B_{1}\left( 0\right) } \left| e(u)- \sum _{i=1}^3 \chi _ie_i\right| ^2 \, \mathrm {d}x+\eta ^\frac{1}{3} \sum _{i=1}^3 |D\chi _i|({B_{1}\left( 0\right) }) \end{aligned}$$ E η ( u , χ ) : = η - 2 3 ∫ B 1 0 e ( u ) - ∑ i = 1 3 χ i e i 2 d x + η 1 3 ∑ i = 1 3 | D χ i | ( B 1 0 ) remains bounded in the limit $$\eta \rightarrow 0$$ η → 0 . Here $$ e(u) \,{:}{=}\,1/2(Du + Du^T)$$ e ( u ) : = 1 / 2 ( D u + D u T ) is the (linearized) strain of the displacement u, the strains $$e_i$$ e i correspond to the martensite strains of a shape memory alloy undergoing cubic-to-tetragonal transformations and the partition into phases is given by $$\chi _i:{B_{1}\left( 0\right) } \rightarrow \{0,1\}$$ χ i : B 1 0 → { 0 , 1 } . In this regime it is known that in addition to simple laminates, branched structures are also possible, which if austenite was present would enable the alloy to form habit planes. In an ansatz-free manner we prove that the alignment of macroscopic interfaces between martensite twins is as predicted by well-known rank-one conditions. Our proof proceeds via the non-convex, non-discrete-valued differential inclusion $$\begin{aligned} e(u) \in \bigcup _{1\le i\ne j\le 3} {\text {conv}} \{e_i,e_j\}, \end{aligned}$$ e ( u ) ∈ ⋃ 1 ≤ i ≠ j ≤ 3 conv { e i , e j } , satisfied by the weak limits of bounded energy sequences and of which we classify all solutions. In particular, there exist no convex integration solutions of the inclusion with complicated geometric structures.


Author(s):  
Rajdeep Sarkar ◽  
A. K. Mukhopadhyay ◽  
Partha Ghosal ◽  
Vipin S. Ramteke ◽  
Deepak Kumar
Keyword(s):  

2020 ◽  
Vol 53 (4) ◽  
pp. 865-879
Author(s):  
Helge Schumann ◽  
Gunther Richter ◽  
Andreas Leineweber

Gaseous nitriding of steel and iron can significantly improve their properties, for example corrosion resistance, fatigue endurance and tribological properties. In order to obtain a better understanding of the early stages of formation of the initial cubic primitive γ′-Fe4N, the mechanism and crystallography of the α–γ′ phase transformation was investigated under simplified conditions. Single-crystal α-Fe whiskers were nitrided at 823 K and a nitriding potential of 0.7 atm−1/2 for 20 min. The resulting microstructure and phases, as well as the crystallographic orientation of crystallites belonging to a particular phase, were characterized by scanning electron microscopy coupled with electron backscatter diffraction. The habit planes were investigated by single- and two-surface trace analysis. The α-Fe whiskers partly transform into γ′-Fe4N, where γ′ grows mainly in a plate-like morphology. An orientation relationship close to the rational Pitsch orientation relationship and {0.078 0.432 0.898}α and {0.391 0.367 0.844}γ′ as habit planes were predicted by the phenomenological theory of martensite crystallography (PTMC), adopting a {101}α〈101〉α shear system for lattice invariant strain, which corresponds to a {1 1 1}γ′〈1 12〉γ′ shear system in γ′. The encountered orientation relationship and the habit planes exhibit excellent agreement with predictions from the PTMC, although the transformation definitely requires diffusion. The γ′ plates mainly exhibit one single internally untwinned variant. The formation of additional variants due to strain accommodation, as well as the formation of a complex microstructure, was suppressed to a considerable extent by the fewer mechanical constraints imposed on the transforming regions within the iron whiskers as compared to the situation at the surface of bulk samples.


2020 ◽  
Vol 321 ◽  
pp. 12026
Author(s):  
Juba HAMMA ◽  
Benoît APPOLAIRE ◽  
Yann LE BOUAR ◽  
Alphonse FINEL

A multi-phase field model describing the anisotropic growth of the {332}<113> twinning system in β-metastable titanium alloys is hereby presented considering the geometrically linear and non-linear frameworks. Phase fields are associated with each twin variant of the {332}<113> system. The lattice transformation describing the twinning systems is incorporated in the model via relevant eigenstrain tensors. We illustrate the capability of our model by investigating the formation of twins networks, within both geometrically linear and non linear frameworks. In particular, it is shown that the predicted microstructures exhibit strong differences, resulting from a difference in the selection of the variant habit planes.


2020 ◽  
Vol 321 ◽  
pp. 12024
Author(s):  
Morgan Goetz ◽  
Moukrane Dehmas ◽  
Benoît Appolaire ◽  
Elisabeth Aeby-Gautier ◽  
Sandra Andrieu ◽  
...  

The present contribution focuses on the nature of the β → α transformation in Ti-5333 alloy at intermediate temperatures. It is indeed still unclear whether this transformation is only controlled by bulk diffusion or whether interfacial kinetics may play a role. To address this issue, we have combined SEM and STEM-EDX to measure the concentrations of Al, Cr, Mo, V and Fe in α intragranular precipitates as well as in the abutting β matrix, paying a particular attention to the concentrations at flat interfaces corresponding to the precipitates habit planes. The comparison with Calphad calculations suggests that interfaces are not at equilibrium during the thickening of the plates.


CrystEngComm ◽  
2020 ◽  
Vol 22 (20) ◽  
pp. 3489-3496 ◽  
Author(s):  
Taka Narumi ◽  
Didier Chaussende ◽  
Takeshi Yoshikawa

We investigated the stable habit planes of 3C–, 4H– and 6H–SiC in Si and Si–Cr-based solvents using Ostwald ripening of SiC particles, and found that particle-growth behaviour varied significantly with both SiC polytypes and solvent compositions.


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