Electrochemical determination of the oxidation potentials and the thermodynamic stability of the valence states of the transuranium elements in aqueous alkaline media

1982 ◽  
Vol 31 (4) ◽  
pp. 726-730
Author(s):  
V. F. Peretrukhin ◽  
V. I. Spitsyn
Keyword(s):  
Thermodynamic Stability ◽  
Electrochemical Determination ◽  
Alkaline Media ◽  
Transuranium Elements ◽  
Oxidation Potentials ◽  
Valence States

scholarly journals Simultaneous electrochemical determination of acetaminophen and metoclopramide at electrochemically pre-treated disposable graphite pencil electrode

2016 ◽  
Vol 6 (3) ◽  
pp. 265 ◽  
Author(s):  
Shreekant M Patil ◽  
Vijay P Pattar ◽  
Sharanappa T Nandibewoor
Keyword(s):  
Simultaneous Determination ◽  
Differential Pulse ◽  
Electrochemical Determination ◽  
Experimental Conditions ◽  
Positive Direction ◽  
Oxidation Potentials ◽  
Voltammetric Behavior ◽  
Pulse Voltammetry ◽  
Apparent Shift

<p class="PaperAbstract"><span lang="EN-US">A sensitive and economic voltammetric method was developed for the simultaneous determination of acetaminophen (AMP) and metoclopramide (MCP) using pre-treated graphite pencil electrode (PTGPE). Compared to a graphite pencil electrode, the pre-treated electrode showed an apparent shift of the oxidation potentials in the positive direction and a notable enhancement in the current responses for both AMP and MCP. Cyclic voltammetry (CV) was used to study the voltammetric behavior of the drugs, while differential pulse voltammetry (DPV) was used to determine AMP and MCP simulta­neously. The dependence of the current on scan rate, pH and concentration was investi­gated to boost the experimental conditions for simultaneous determination. The calibra­tion curves were obtained over the range of 0.1</span><span lang="EN-US">×</span><span lang="EN-US">10<sup>-7</sup> to 1.1</span><span lang="EN-US">×</span><span lang="EN-US">10<sup>-7</sup> M, the concentration of each of both the drugs was varied by keeping the other constant, and achieved lower detection limit of 3.25 nM for AMP and 1.16 nM for MCP. The developed method was found to be selective and rapid for the simultaneous determination of AMP and MCP. The proposed method was applied simultaneously in real samples and pharmaceutical samples, with satisfactory results.</span></p>

scholarly journals Electrochemical Determination of Dopamine on a Glassy Carbon Electrode Modified by Using Nanostructure Ruthenium Oxide Hexacyanoferrate/Ruthenium Hexacyanoferrate Thin Film

2011 ◽  
Vol 2011 ◽  
pp. 1-11 ◽  
Author(s):  
Reza Karimi Shervedani ◽  
Hossein Ali Alinajafi-Najafabadi
Keyword(s):  
Ascorbic Acid ◽  
Detection Limit ◽  
Glassy Carbon Electrode ◽  
Glassy Carbon ◽  
Ruthenium Oxide ◽  
Electrochemical Determination ◽  
Human Blood Plasma ◽  
Carbon Electrode ◽  
Oxidation Potentials

Application of mixed ruthenium oxide hexacyanoferrate/ruthenium hexacyanoferrate glassy carbon electrode for electrochemical determination of dopamine (DA) is described for the first time. The overlapped voltammetric oxidation potentials of ascorbic acid (AA) and DA are separated and shifted to more facile direction, +170 and +320 mV versus Ag/AgCl, respectively. Voltammetric response of the electrode toward the DA showed a dynamic calibration curve with two linear parts, from 0.50 to 10.00 μM and 25.00 to 550.00 μM DA, and a detection limit of 0.195 μM. The sensitivity (0.2917 μA/μM) and detection limit (0.195×10−7 μMDA) of this electrode are 21 times higher and 11.5 times lower than those found in our previous paper. The sensor response of 9.95 μMDA was not affected by 5.0 mM of glucose, 4.5 mM of fructose, 0.58 mM of sucrose, 0.28 mM of cystine, 0.25 mM of ascorbic acid, 79.60 μM of cysteine, and 49.70 μM of uric acid and urea. The fabricated sensor was successfully tested for determination of DA in injection medicine and human blood plasma samples.

scholarly journals Simultaneous electrochemical determination of acetaminophen and metoclopramide at electrochemically pre-treated disposable graphite pencil electrode

2016 ◽  
Vol 6 (3) ◽  
pp. 265
Author(s):  
Shreekant M Patil ◽  
Vijay P Pattar ◽  
Sharanappa T Nandibewoor
Keyword(s):  
Simultaneous Determination ◽  
Differential Pulse ◽  
Electrochemical Determination ◽  
Experimental Conditions ◽  
Positive Direction ◽  
Oxidation Potentials ◽  
Voltammetric Behavior ◽  
Pulse Voltammetry ◽  
Apparent Shift

<p class="PaperAbstract"><span lang="EN-US">A sensitive and economic voltammetric method was developed for the simultaneous determination of acetaminophen (AMP) and metoclopramide (MCP) using pre-treated graphite pencil electrode (PTGPE). Compared to a graphite pencil electrode, the pre-treated electrode showed an apparent shift of the oxidation potentials in the positive direction and a notable enhancement in the current responses for both AMP and MCP. Cyclic voltammetry (CV) was used to study the voltammetric behavior of the drugs, while differential pulse voltammetry (DPV) was used to determine AMP and MCP simulta­neously. The dependence of the current on scan rate, pH and concentration was investi­gated to boost the experimental conditions for simultaneous determination. The calibra­tion curves were obtained over the range of 0.1</span><span lang="EN-US">×</span><span lang="EN-US">10<sup>-7</sup> to 1.1</span><span lang="EN-US">×</span><span lang="EN-US">10<sup>-7</sup> M, the concentration of each of both the drugs was varied by keeping the other constant, and achieved lower detection limit of 3.25 nM for AMP and 1.16 nM for MCP. The developed method was found to be selective, and rapid for the simultaneous determination of AMP and MCP. The proposed method was applied simultaneously in real samples and pharmaceutical samples, with satisfactory results.</span></p>

Electrochemical determination of sulphide at nickel electrodes in alkaline media: a new electrochemical sensor

2003 ◽  
Vol 88 (3) ◽  
pp. 320-328 ◽  
Author(s):  
Debora Giovanelli ◽  
Nathan S. Lawrence ◽  
Li Jiang ◽  
Timothy G.J. Jones ◽  
Richard G. Compton
Keyword(s):  
Electrochemical Sensor ◽  
Electrochemical Determination ◽  
Alkaline Media ◽  
Nickel Electrodes

Spectrophotometric study of the acid-base and optical properties of the 5-bromo and 5-chloro derivatives of 2-(2-pyridylazo)-5-(diethylamino)phenol (BrPADAP, ClPADAP) and their complexation equilibria with zinc(II) ions

1982 ◽  
Vol 47 (10) ◽  
pp. 2676-2691 ◽  
Author(s):  
Miroslav Macka ◽  
Vlastimil Kubáň
Keyword(s):  
Equilibrium Constants ◽  
Spectrophotometric Study ◽  
Graphical Analysis ◽  
Alkaline Media ◽  
Acid Base ◽  
Ethanol Medium ◽  
Triton X ◽  
Mixed Water ◽  
Derivatives Of

The optical and acid-base characteristics of BrPADAP and ClPADAP were studied in mixed water-ethanol and water-DMF media and in 10% ethanol medium in the presence of cationic, anionic and nonionic tensides. The composition, optical characteristics, molar absorption coefficients and equilibrium constants of the ML and ML2 complexes with zinc(II) ions were found by graphical analysis and numerical interpretation of the absorbance curves by the modified SQUAD-G program. Optimal conditions were found for the spectrophotometric determination of Zn(II) in the presence of 0.1% Triton X-100 or 1% Brij 35 in alkaline media with pH = 6.5-10. BrPADAP and ClPADAP are the most sensitive reagents (ε = 1.3-1.6 . 105 mmol-1 cm2 at 557 and 560 nm, respectively) for the determination of zinc with high colour contrast of the reaction (Δλ = 104 nm) and selectivity similar to that for the other N-heterocyclic azodyes (PAN, PAR, etc.).

scholarly journals Electrochemical determination of sertraline in pharmaceutical formulation and serum using a gold electrode in a pH 8.4 bicarbonate solution

2021 ◽  
Vol 152 (2) ◽  
pp. 185-192
Author(s):  
Jelena Lović ◽  
Jelena Lađarević ◽  
Nemanja Trišović ◽  
Filip Andrić ◽  
Aleksandar Mladenović ◽  
...  
Keyword(s):  
Gold Electrode ◽  
Electrochemical Determination ◽  
Pharmaceutical Formulation
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