An approximate treatment of the transient state in the corrosion of binary alloys forming the most-stable oxide. Part I: Solid-solution alloys

F. Gesmundo; P. Castello; F. Viani; J. Philibert

doi:10.1007/bf01682373

An approximate treatment of the transient state in the corrosion of binary alloys forming the most-stable oxide. Part I: Solid-solution alloys

Oxidation of Metals ◽

10.1007/bf01682373 ◽

1997 ◽

Vol 47 (1-2) ◽

pp. 91-115 ◽

Cited By ~ 10

Author(s):

F. Gesmundo ◽

P. Castello ◽

F. Viani ◽

J. Philibert

Keyword(s):

Solid Solution ◽

Binary Alloys ◽

Transient State ◽

Stable Oxide ◽

Approximate Treatment

An approximate treatment of the transient state in the oxidation of binary alloys forming the most-stable oxide. Part II: Single-phase alloys in systems with a solubility gap

Oxidation of Metals ◽

10.1007/bf02134790 ◽

1997 ◽

Vol 47 (5-6) ◽

pp. 525-550 ◽

Cited By ~ 2

Author(s):

F. Gesmundo ◽

P. Castello ◽

F. Viani ◽

J. Philibert

Keyword(s):

Single Phase ◽

Binary Alloys ◽

Transient State ◽

Stable Oxide ◽

Approximate Treatment

The transient state in the oxidation of binary alloys forming the most-stable oxide: A numerical solution

Oxidation of Metals ◽

10.1007/bf02134789 ◽

1997 ◽

Vol 47 (5-6) ◽

pp. 507-524 ◽

Cited By ~ 7

Author(s):

F. Gesmundo ◽

M. Pereira

Keyword(s):

Numerical Solution ◽

Binary Alloys ◽

Transient State ◽

Stable Oxide

Extension of Solid Solution in Rapidly Solidified Binary Alloys

Key Engineering Materials ◽

10.4028/www.scientific.net/kem.38-39.83 ◽

1991 ◽

Vol 38-39 ◽

pp. 83-98

Author(s):

Kamanio Chattopadhyay ◽

K. Raviprasad

Keyword(s):

Solid Solution ◽

Binary Alloys ◽

Rapidly Solidified

The corrosion of solid solution Mg-Sn binary alloys in NaCl solutions

Electrochimica Acta ◽

10.1016/j.electacta.2018.11.118 ◽

2019 ◽

Vol 297 ◽

pp. 564-575 ◽

Cited By ~ 17

Author(s):

T.W. Cain ◽

C.F. Glover ◽

J.R. Scully

Keyword(s):

Solid Solution ◽

Binary Alloys

The steady-State corrosion kinetics of two-phase binary alloys forming the most-stable oxide

Oxidation of Metals ◽

10.1007/bf01048637 ◽

1996 ◽

Vol 46 (5-6) ◽

pp. 383-398 ◽

Cited By ~ 14

Author(s):

F. Gesmundo ◽

P. Castello ◽

F. Viani

Keyword(s):

Steady State ◽

Binary Alloys ◽

Two Phase ◽

Stable Oxide ◽

Corrosion Kinetics ◽

Kinetics Of

Oxide Scale Evolution on Binary Alloys: Transient State Kinetics from First Principles

ECS Meeting Abstracts ◽

10.1149/ma2020-0291176mtgabs ◽

2020 ◽

Vol MA2020-02 (9) ◽

pp. 1176-1176

Author(s):

Penghao Xiao ◽

Brandon C. Wood

Keyword(s):

Oxide Scale ◽

First Principles ◽

Binary Alloys ◽

Transient State ◽

Scale Evolution

X-ray Diffraction Study on Lattice Constant of Supersaturated Solid Solution for Al Based Binary Alloys and Selected Al-Zn-Mg-Cu Alloys

ICAA13: 13th International Conference on Aluminum Alloys ◽

10.1002/9781118495292.ch199 ◽

2012 ◽

pp. 1295-1300

Author(s):

Zhihui Li ◽

Baiqing Xiong ◽

Yongan Zhang ◽

Xiwu Li ◽

Baohong Zhu ◽

...

Keyword(s):

Solid Solution ◽

Diffraction Study ◽

Lattice Constant ◽

Supersaturated Solid Solution ◽

Binary Alloys ◽

X Ray Diffraction ◽

X Ray ◽

Cu Alloys

Solid solution strengthening in polycrystals of Mg–Sn binary alloys

Journal of Alloys and Compounds ◽

10.1016/j.jallcom.2010.12.065 ◽

2011 ◽

Vol 509 (7) ◽

pp. 3357-3362 ◽

Cited By ~ 41

Author(s):

B.Q. Shi ◽

R.S. Chen ◽

W. Ke

Keyword(s):

Solid Solution ◽

Binary Alloys ◽

Solid Solution Strengthening ◽

Solution Strengthening

Bounds to Hardening by Solid Solution, Precipitation and Short Range Order in Mg Binary Alloys

Magnesium Technology 2013 ◽

10.1002/9781118663004.ch37 ◽

2013 ◽

pp. 225-230 ◽

Cited By ~ 2

Author(s):

C.H. Cáceres ◽

Saeideh Abaspour

Keyword(s):

Solid Solution ◽

Short Range ◽

Short Range Order ◽

Binary Alloys ◽

Range Order

The diffusion-controlled growth of solid solution scales on binary alloys

Proceedings of the Royal Society of London Series A - Mathematical and Physical Sciences ◽

10.1098/rspa.1977.0128 ◽

1977 ◽

Vol 356 (1685) ◽

pp. 177-214 ◽

Cited By ~ 16

Keyword(s):

Solid Solution ◽

Cation Distribution ◽

Binary Alloys ◽

Analytical Description ◽

Parabolic Rate Constant ◽

Detailed Examination ◽

Second Phase ◽

Scale Growth ◽

Cation Diffusion ◽

The Individual

A detailed examination is made of the equations originally developed by Wagner (1969), and subsequently modified by other workers, which describe the growth of solid solution scales by cation diffusion on binary alloys. By reference to finite difference solutions of the relevant differential equations, it is demonstrated that an accurate limiting solution can be obtained for k , the parabolic rate constant for scale growth. Upon combining this with existing equations describing both diffusion in the alloy and mass-balances at the scale boundaries, a set of interdependent relations is extracted which provide a complete analytical description of scale growth. As a result, k can be calculated for conditions relevant to the formation of compact, solid solution scales on single phase, binary alloys, from pertinent diffusion and thermodynamic data. Representative values for the relative diffusion rates of the participating metal atoms in the alloy and ions in the scale, the individual rates of cation diffusion in the scale, the degree of selective oxidation of the appropriate alloy component and the activity of the oxidizing atmosphere are each examined quantitatively for their influence both on k and on the cation distribution in the scale. General patterns of behaviour are established and the relation between the cation distribution and the precipitation of a second phase is discussed. A quantitative assessment of the reliability of the analysis is restricted by the limited availability of the requisite data for real systems and is confined to the calculation of k for Co-Ni, Co-Fe, Fe-Mn and dilute Ni-Cr alloys. Satisfactory agreement with experimental data is obtained in each case. Further support for the analysis is obtained from a consideration of distributions of cations in scales on the same alloys.