Equilibrium vapor pressure of butylated hydroxyanisole and butylated hydroxytolune in high temperature oil solution

1975 ◽  
Vol 52 (3) ◽  
pp. 103-105 ◽  
Author(s):  
I. J. Kopelman ◽  
S. Mizrahi ◽  
R. Schab
Author(s):  
V. R. Matricardi ◽  
G. G. Hausner ◽  
D. F. Parsons

In order to observe room temperature hydrated specimens in an electron microscope, the following conditions should be satisfied: The specimen should be surrounded by water vapor as close as possible to the equilibrium vapor pressure corresponding to the temperature of the specimen.The specimen grid should be inserted, focused and photo graphed in the shortest possible time in order to minimize dehydration.The full area of the specimen grid should be visible in order to minimize the number of changes of specimen required.There should be no pressure gradient across the grid so that specimens can be straddled across holes.Leakage of water vapor to the column should be minimized.


1966 ◽  
Vol 31 (2) ◽  
pp. 196-201 ◽  
Author(s):  
DAVID F. DYER ◽  
DEWEY K. CARPENTER ◽  
J. EDWARD SUNDERLAND

1961 ◽  
Vol 39 (11) ◽  
pp. 2290-2294 ◽  
Author(s):  
K. Grjotheim ◽  
O. Herstad ◽  
J. M. Toguri

The equilibrium vapor pressure of magnesium over the reaction between the calcined dolomite and aluminum was measured by means of the transportation method. In the temperature range 886–1035 °C, the reaction was found to proceed according to the equilibrium[Formula: see text]and the measured equilibrium pressure of magnesium can be expressed by the equation[Formula: see text]


Author(s):  
Seungbae Park ◽  
Haojun Zhang ◽  
Changsoo Jang

The pop-corning failure is known to result from high vapor pressure generation inside cavities at defective interfaces of the electronic package. In order to study the phenomenon, vapor pressure inside a void at high temperature is measured using a specific specimen configuration developed for this purpose. The specimen incorporates a volume-controllable cavity at a polymer-metal interface. A pressure sensor is used to monitor pressure evolution inside the void at high temperature. An underfill material used in the configuration is characterized in terms of hygroscopic properties. The phenomenon is also simulated on a finite element model based on these properties and specimen geometry. The prediction by the numerical model well matches the measurement by pressure sensor. This corroborates the validity of the hypothesis of high vapor pressure employed in numerous existing studies that simulated the pop-corning failure.


2008 ◽  
Vol 595-598 ◽  
pp. 763-768
Author(s):  
Martah Homa ◽  
Zbigniew Żurek

The high temperature corrosion behavior of Fe20Cr6Al-Y,Hf steel was studied in the range of temperature 800-1000oC in H2/H2S atmospheres at pS2=10-2 ,10-3 and 10-4 Pa sulphur vapor pressures. Kinetics depend on the temperature and sulphur vapor pressure. After 24 hours the whole specimen was practically consumed because the samples were 0,06 cm thick. Morphology of the scales have been performed by SEM techniques. Phase and chemical composition have been studied by EDX and XRD techniques. It was found that scale formed on Fe20Cr6Al-Y,Hf alloy was built with porosity sulphides layer. EDX analysis of the scale surface show that the any aluminum, hafnium and yttrium sulfides were found in the formed scale layer, however small amounts of Al2S3 was detected in scale/steel interface. Also internal sulphidation was observed. A phase analysis of the formed scale revealed that it is composed mainly of an FeS, Fe7S8 phases and CrS, Cr5S6. Result were compared with data obtained on the pure Fe and Cr samples.


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