Thermal analysis and kinetics of the oxidative roasting process of a copper smelter dust

2017 ◽  
Vol 94 (5-8) ◽  
pp. 2393-2400 ◽  
Author(s):  
D. O. Okanigbe ◽  
A. P. I. Popoola ◽  
A. A. Adeleke
2005 ◽  
Vol 82 (2) ◽  
pp. 383-388 ◽  
Author(s):  
D. Minić ◽  
Nada Štrbac ◽  
I. Mihajlović ◽  
Ž. Živković

2020 ◽  
Vol 7 ◽  
pp. 100125 ◽  
Author(s):  
Daniel O Okanigbe ◽  
Michael K Ayomoh ◽  
Olawale M Popoola ◽  
Patricia A Popoola ◽  
Victor S Aigbodion

2018 ◽  
Author(s):  
Asel Sartbaeva ◽  
Paul R. Raithby ◽  
Remi Castaing ◽  
Antony Nearchou

Through a combination of thermogravimetry, mass spectrometry and differential thermal analysis, we demonstrate for the first time that all four zeolites show experimental differences in their host-guest interactions with 18C6. In addition, we have estimated the kinetics of 18C6 decomposition, which is a technique that has not been applied to zeolites previously. Using these findings as a toolkit, a more rational use of OSDAs can be utilised to prepare designer zeolites. Furthermore, the new methodologies presented herein can be applied to current zeolites, such as MFI-type zeolites used in the petrochemical industry.


1983 ◽  
Vol 48 (12) ◽  
pp. 3340-3355 ◽  
Author(s):  
Pavel Fott ◽  
Pavel Šebesta

The kinetic parameters of reactivation of a carbonized hydrodesulphurization (HDS) catalyst by air were evaluated from combined thermogravimetric (TG) and differential thermal analysis (DTA) data. In addition, the gaseous products leaving a temperature-programmed reactor with a thin layer of catalyst were analyzed chromatographically. Two exothermic processes were found to take part in the reactivation, and their kinetics were described by 1st order equations. In the first process (180-400 °C), sulphur in Co and Mo sulphides is oxidized to sulphur dioxide; in the second process (300-540 °C), in which the essential portion of heat is produced, the deposited carbon is oxidized to give predominantly carbon dioxide. If the reaction heat is not removed efficiently enough, ignition of the catalyst takes place, which is associated with a transition to the diffusion region. The application of the obtained kinetic parameters to modelling a temperature-programmed reactivation is illustrated on the case of a single particle.


2021 ◽  
Vol 413 ◽  
pp. 125365
Author(s):  
Jianrong Xue ◽  
Dongping Long ◽  
Hong Zhong ◽  
Shuai Wang ◽  
Lihua Liu

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