A study of the microstructure, thermal properties and wetting kinetics of Sn–3Ag–xZn lead-free solders

2016 ◽  
Vol 122 (6) ◽  
Author(s):  
Yulong Li ◽  
Xiao Yu ◽  
Dusan P. Sekulic ◽  
Xiaowu Hu ◽  
Ming Yan ◽  
...  
2008 ◽  
Vol 38 (2) ◽  
pp. 284-291 ◽  
Author(s):  
Hui Zhao ◽  
Dinesh Reddy Nalagatla ◽  
Dusan P. Sekulic

Author(s):  
Mohammad Faizan ◽  
Guo-X. Wang

Soldering has become an indispensable joining process in the electronic packaging industry. The industry is aiming for the use of environment friendly lead-free solders. All the lead-free solders are high tin-containing alloys. During the soldering process, an intense interaction of metallization on PCB and tin from the solder occurs at the metallization/solder interface. Intermetallic compound (IMC) is formed at the interface and subsequently PCB bond-metal (substrate) is dissolved into the molten solder. In the present study the terms bond-metal and substrate will be used interchangeably and the term 'substrate' refers to the top layer of the PCB which comes in contact with the molten solder during soldering reaction. Thickness of the intermetallic phase formed at the joint interface and amount of substrate lost is critical in achieving reliable solder joints. During the wet phase of soldering process, the IMC does not grow as layered structure; rather it takes the shape of scallops. The growth of scalloped IMC during the solder/substrate interaction entails complicated physics. Understanding of the actual kinetics involved in the formation of IMC phase is important in controlling the process to achieve desired results. This paper presents theoretical analysis of the kinetics involved in the formation of the scalloped intermetallic phase. The intermetallic phase growth is experimentally investigated to support the underlying kinetics of the process. Numerical model has been suggested to translate the physics of the process. The model is based on the basic mass diffusion equations and can predict the substrate dissolution and IMC thickness as a function of soldering time.


Author(s):  
M. Faizan ◽  
G.-X. Wang

Soldering is the default joining process in the electronic packaging industry. Solder joints are obtained by interaction of the substrate with the molten solder. Soldering reaction and the resulting dissolution of substrate material is a complicated process. Reliability and strength of solder joints during service have always been the critical issues in electronic packaging industry. Mechanical strength of solder joints can significantly be increased by employing composite solders. These composite solders are sometimes obtained by incorporation of micro- and nano-size metal particles in the solder paste before the soldering process. Better understanding of substrate-solder interaction is important for the proper selection of the reinforcing particle size and composition. In the present research the relative importance of interface reaction and diffusion has been studied. Dissolution kinetics of a planar substrate and spherical particles has been investigated. Our results show that the dissolution is governed both by interface kinetics and long-range diffusion. Non-equilibrium behavior has been observed in the early stage of the process. It has been observed that at the early stage the dissolution process is governed by interface kinetics, while diffusion became the rate controlling mechanism at the later phase. A mathematically rigorous model has been proposed for simulating the dissolution of the substrate in the liquid lead-free solders. The study is extended to investigate the dissolution of spherical particles in molten solders. The results show that the initial particle dimension plays a critical role in the end particle size after the reflow process.


2009 ◽  
Vol 38 (9) ◽  
pp. 1846-1854 ◽  
Author(s):  
H. Zhao ◽  
H. Q. Wang ◽  
D. P. Sekulic ◽  
Y. Y. Qian

2006 ◽  
Vol 35 (11) ◽  
pp. 1948-1954 ◽  
Author(s):  
C. W. Chang ◽  
C. E. Ho ◽  
S. C. Yang ◽  
C. R. Kao

2009 ◽  
Vol 113 (22) ◽  
pp. 9546-9552 ◽  
Author(s):  
Fan Gao ◽  
Subhadeep Mukherjee ◽  
Qingzhou Cui ◽  
Zhiyong Gu

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