Effect of surface area of carbon nanotubes on membrane performance for effective water desalination

2018 ◽  
Vol 124 (11) ◽  
Author(s):  
Javad Eslami ◽  
Yaser Abdi ◽  
Anousha Khamsavi ◽  
Zahra EbrahimNataj ◽  
Asieh S. Kazemi
Author(s):  
Dengsong Zhang ◽  
Liyi Shil ◽  
Jianhui Fang ◽  
Kai Dai

Modified multiwall carbon nanotubes (MWCNTs) were used as the electrodes of flow–through capacitor for the desalination, which were cost–cutting, energy–saving, and enviromnent–friendly and could be expected to be an altemative technology for reverse osmosis membrane for sea water desalination. Investigated by transmission electron microscope (TEM) and nitrogen adsorption/desorption for modified MWCNTs, it was confirmed that after modification treatment by immersion in diluted HNO3 solution with ultrasonic and then milling by ball at a high velocity, the metal catalyst particles at the tip of MWCNTs disappeared, the MWCNT length became short, the cap at the tip of nanotube was opened, the internal surface area could be effectively used, leading to the increase of the specific surface area and pore volume, and thus MWCNTs modified by that method had the best desalination performance. This modification technique is simple and the efficiency is high.


2014 ◽  
Vol 625 ◽  
pp. 148-151 ◽  
Author(s):  
Rahmam Syuhaidah ◽  
Muti Mohamed Norani ◽  
Suriati Sufian

Carbon Nanotubes (CNT) have emerged and gained great interest for research in many applications because of their unique specific characteristics such as having high porosity, high surface area and the existence of a wide spectrum of surface functional groups through chemical modification. Multiwalled carbon nanotubes (MWCNT) is a type of CNT that comprises of multiple layers of concentric cylinders. The overall study of this research work is to modify MWCNT to become a good adsorbent that can adsorb CO2 at its optimum capacity. In order to make MWCNT as an efficient adsorbent, surface treatment on pristine MWCNT is necessary to overcome the hydrophobicity issue by the introduction of carboxyl group. Upon the surface treatment, functionalization of MWCNT with 3-Aminopropyl triethoxysilane (APTS) was conducted to obtain the attachment of amine group that will assist MWCNT in adsorbing CO2. The surface treatment and functionalization process undergone by MWCNT changed the physical properties of MWCNT such as the surface area, pore volume, and pore size distribution. These properties can be determined using surface area and pore analyzer (SAP). Sample that treated with the mixture of nitric and sulfuric acid (HNO3/H2SO4) and functionalized with APTS gives the lowest surface area (22.07 m2/g) and pore volume (0.06 cm3/g). The pore size distribution also decreases due to the most presence of functional group onto the surface of modified MWCNT. This research paper is focusing on the effect of surface area, pore volume, and pore size distribution on the modified MWCNT.


ACS Omega ◽  
2019 ◽  
Vol 4 (4) ◽  
pp. 6826-6847 ◽  
Author(s):  
Asieh Sadat Kazemi ◽  
Ali Akbar Noroozi ◽  
Anousha Khamsavi ◽  
Ali Mazaheri ◽  
Seiyed Mossa Hosseini ◽  
...  

2021 ◽  
Author(s):  
Yaxiong Zhang ◽  
Erqing Xie

Carbon nanotubes (CNTs) have been widely studied as supercapacitor electrodes because of their excellent conductivity, high aspect ratio, excellent mechanical properties, chemical stability, and large specific surface area. However, the...


2021 ◽  
Vol 1036 ◽  
pp. 130-136
Author(s):  
Ting Qun Tan ◽  
Lei Geng ◽  
Yan Lin ◽  
Yan He

In order to prepare carbon nanotubes with high specific surface area, small diameter, low resistivity, high purity and high catalytic activity, the Fe-Mo/Al2O3 catalyst was prepared based on the microreactor. The influence of different Fe/Al molar ratios on the catalyst and the carbon nanotubes prepared was studied through BET, SEM, TEM and other detection methods. Studies have shown that the pore structure of the catalyst is dominated by slit pores at a lower Fe/Al molar ratio. The catalytic activity is the highest when the Fe/Al molar ratio is 1:1, reaching 74.1%. When the Fe/Al molar ratio is 1:2, the catalyst has a higher specific surface area, the maximum pore size is 8.63 nm, and the four-probe resistivity and ash content of the corresponding carbon nanotubes are the lowest. The higher the proportion of aluminum, the higher the specific surface area of the catalyst and the carbon nanotubes, and the finer the diameter of the carbon nanotubes, which gradually tends to relax. The results show that when the Fe/Al molar ratio is 1:2, although the catalytic activity of the catalyst is not the highest, the carbon nanotubes prepared have the best performance.


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