Effects of contact angle hysteresis on ice adhesion and growth on superhydrophobic surfaces under dynamic flow conditions

2012 ◽  
Vol 291 (2) ◽  
pp. 427-435 ◽  
Author(s):  
Mohammad Amin Sarshar ◽  
Christopher Swarctz ◽  
Scott Hunter ◽  
John Simpson ◽  
Chang-Hwan Choi
Author(s):  
Mohammad Amin Sarshar ◽  
Christopher Swarctz ◽  
Scott Hunter ◽  
John Simpson ◽  
Chang-Hwan Choi

In this paper, the iceophobic properties of superhydrophobic surfaces are compared to those of uncoated aluminum and steel plate surfaces as investigated under dynamic flow conditions by using a closed loop low-temperature wind tunnel. Superhydrophobic surfaces were prepared at the Oak Ridge National Laboratory by coating aluminum and steel plates with nano-structured hydrophobic particles. The contact angle and contact angle hysteresis measured for these surfaces ranged from 165–170° and 1–8°, respectively. The superhydrophobic plates along with uncoated control ones were exposed to an air flow of 12 m/s and 20°F with micron-sized water droplets in the icing wind tunnel and the ice formation and accretion were probed by using high speed cameras for 90 seconds. Results show that the developed superhydrophobic coatings significantly delay the ice formation and accretion even with the impingement of accelerated super-cooled water droplets, but there is a time scale for this phenomenon which has a clear relation with contact angle hysteresis of the samples. Among the different superhydrophobic coating samples, the plate having the lowest contact angle hysteresis showed the most pronounced iceophobic effects, while the correlation between static contact angles and the iceophobic effects was not evident. The results suggest that the key parameter for designing iceophobic surfaces is to retain a low contact angle hysteresis, rather than to have only a low contact angle, which can result in more efficient anti-icing properties in dynamic flow conditions.


2018 ◽  
Vol 845 ◽  
pp. 560-580 ◽  
Author(s):  
James W. Gose ◽  
Kevin Golovin ◽  
Mathew Boban ◽  
Joseph M. Mabry ◽  
Anish Tuteja ◽  
...  

A significant amount of the fuel consumed by marine vehicles is expended to overcome skin-friction drag resulting from turbulent boundary layer flows. Hence, a substantial reduction in this frictional drag would notably reduce cost and environmental impact. Superhydrophobic surfaces (SHSs), which entrap a layer of air underwater, have shown promise in reducing drag in small-scale applications and/or in laminar flow conditions. Recently, the efficacy of these surfaces in reducing drag resulting from turbulent flows has been shown. In this work we examine four different, mechanically durable, large-scale SHSs. When evaluated in fully developed turbulent flow, in the height-based Reynolds number range of 10 000 to 30 000, significant drag reduction was observed on some of the surfaces, dependent on their exact morphology. We then discuss how neither the roughness of the SHSs, nor the conventional contact angle goniometry method of evaluating the non-wettability of SHSs at ambient pressure, can predict their drag reduction under turbulent flow conditions. Instead, we propose a new characterization parameter, based on the contact angle hysteresis at higher pressure, which aids in the rational design of randomly rough, friction-reducing SHSs. Overall, we find that both the contact angle hysteresis at higher pressure, and the non-dimensionalized surface roughness, must be minimized to achieve meaningful turbulent drag reduction. Further, we show that even SHSs that are considered hydrodynamically smooth can cause significant drag increase if these two parameters are not sufficiently minimized.


2008 ◽  
Vol 112 (30) ◽  
pp. 11403-11407 ◽  
Author(s):  
Yonghao Xiu ◽  
Lingbo Zhu ◽  
Dennis W. Hess ◽  
C. P. Wong

2012 ◽  
Vol 706-709 ◽  
pp. 2874-2879 ◽  
Author(s):  
R. Jafari ◽  
Masoud Farzaneh

Superhydrophobic surfaces were prepared using a very simple and low-cost method by spray coating. A high static water contact angle of about 154° was obtained by deposition of stearic acid on an aluminium alloy. However, this coating demonstrated a high contact angle hysteresis (~ 30º). On the other hand, superhydrophobic surfaces with a static contact angle of about 162º and 158º, and a low contact angle hysteresis of about 3º and 5º were respectively obtained by incorporating nanoparticles of SiO2and CaCO3in stearic acid. The excellent resulting hydrophobicity is attributed to the synergistic effects of micro/nanoroughness and low surface energy. A study of the wettability of these surfaces at temperatures ranging from 20 to-10 °C showed that the superhydrophobic surface becomes rather hydrophobic at supercooled temperatures.


Author(s):  
Mercy Dicuangco ◽  
Susmita Dash ◽  
Justin A. Weibel ◽  
Suresh V. Garimella

The ability to control the size, shape, and location of particulate deposits is important in patterning, nanowire growth, sorting biological samples, and many other industrial and scientific applications. It is therefore of interest to understand the fundamentals of particle deposition via droplet evaporation. In the present study, we experimentally probe the assembly of particles on superhydrophobic surfaces by the evaporation of sessile water droplets containing suspended latex particles. Superhydrophobic surfaces are known to result in a significant decrease in the solid-liquid contact area of a droplet placed on such a substrate, thereby increasing the droplet contact angle and reducing the contact angle hysteresis. We conduct experiments on superhydrophobic surfaces of different geometric parameters that are maintained at different surface temperatures. The transient droplet shape and wetting behavior during evaporation are analyzed as a function of substrate temperature as well as surface morphology. During the evaporation process, the droplet exhibits a constant contact radius mode, a constant contact angle mode, or a mixed mode in which the contact angle and contact radius change simultaneously. The evaporation time of a droplet can be significantly reduced with substrate heating as compared to room-temperature evaporation. To describe the spatial distribution of the particle residues left on the surfaces, qualitative and quantitative evaluations of the deposits are presented. The results show that droplet evaporation on superhydrophobic surfaces, driven by mass diffusion under isothermal conditions or by substrate heating, suppresses particle deposition at the contact line. This preempts the so-called coffee-ring and allows active control of the location of particle deposition.


Processes ◽  
2020 ◽  
Vol 8 (12) ◽  
pp. 1635
Author(s):  
Rafał Kozera ◽  
Bartłomiej Przybyszewski ◽  
Katarzyna Żołyńska ◽  
Anna Boczkowska ◽  
Bogna Sztorch ◽  
...  

Ice accumulation is a key and unsolved problem for many composite structures with polymer matrices, e.g., wind turbines and airplanes. One of the solutions to avoid icing is to use anti-icing coatings. In recent years, the influence of hydrophobicity of a surface on its icephobic properties has been studied. This solution is based on the idea that a material with poor wettability maximally reduces the contact time between a cooled drop of water and the surface, consequently prevents the formation of ice, and decreases its adhesion to the surface. In this work, a hybrid modification of a gelcoat based on unsaturated polyester resin with nanosilica and chemical modifiers from the group of triple functionalized polyhedral oligomeric silsesquioxanes (POSS) and double organofunctionalized polysiloxanes (generally called multi-functionalized organosilicon compounds (MFSC)) was applied. The work describes how the change of modifier concentration and its structural structure finally influences the ice phobic properties. The modifiers used in their structure groups lowered the free surface energy and crosslinking groups with the applied resin, lowering the phenomena of migration and removing the modifier from the surface layer of gelcoat. The main studies from the icephobicity point of view were the measurements of ice adhesion forces between modified materials and ice. The tests were based on the measurements of the shear strength between the ice layer and the modified surface and were conducted using a tensile machine. Hydrophobic properties of the obtained nanocomposites were determined by measurement of the contact angle and contact angle hysteresis. As the results of the work, it was found that the modification of gelcoat with nanosilica and multi-functionalized silicone compounds results in the improvement of icephobic properties when compared to unmodified gelcoat while no direct influence of wettability properties was found. Ice adhesion decreased by more than 30%.


2013 ◽  
Vol 29 (8) ◽  
pp. 633-636 ◽  
Author(s):  
Y F Huang ◽  
C Huang ◽  
Y L Zhong ◽  
S P Yi

Langmuir ◽  
2011 ◽  
Vol 27 (6) ◽  
pp. 2166-2169 ◽  
Author(s):  
Joseph W. Krumpfer ◽  
Pei Bian ◽  
Peiwen Zheng ◽  
Lichao Gao ◽  
Thomas J. McCarthy

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