Investigations in annealing effects on structure and properties of β-isotactic polypropylene with X-ray synchrotron experiments

2014 ◽  
Vol 292 (12) ◽  
pp. 3205-3221 ◽  
Author(s):  
Yingrui Shang ◽  
Jing Zhao ◽  
Jingqing Li ◽  
Zhonghua Wu ◽  
Shichun Jiang
Keyword(s):  
Isotactic Polypropylene ◽  
Structure And Properties ◽  
X Ray ◽  
Annealing Effects

Copper-containing nanocomposites on the basis of isotactic polypropylene and butadiene-nitrile rubber

2021 ◽  
Vol 5 ◽  
pp. 76-81
Author(s):  
N.I. Kurbanova ◽  
◽  
S. K. Ragimova ◽  
N. A. Alimirzoeva ◽  
N. Ya. Ishenko ◽  
...  
Keyword(s):  
Isotactic Polypropylene ◽  
Thermal Analyses ◽  
Nitrile Rubber ◽  
Polymer Composition ◽  
Rheological Parameters ◽  
Structure And Properties ◽  
Pressing Method ◽  
X Ray ◽  
High Pressure Polyethylene ◽  
Butadiene Nitrile Rubber

The influence of additives of nanofillers (NF) containing nanoparticles of copper oxides stabilized by a polymer matrix of high-pressure polyethylene (PE) obtained by the mechanochemical method on the structure and properties features of metal-containing nanocomposites based on isotactic polypropylene (PP) and butadiene-nitrile rubber (BNK) is studied by X-ray phase (XRD) and differential thermal analyses(DTA). The improvement of strength, deformation and rheological parameters, as well as thermal-oxidative stability of the obtained nanocomposites was revealed, which, apparently, is associated with the synergistic effect of interfacial interaction of copper-containing nanoparticles in the PE matrix with the components of the PP/BNK polymer composition. It is shown that nanocomposites based on PP/BNK/NF can be processed both by pressing method and by injection molding and extrusion methods, which expands the scope of its application.

scholarly journals COPPER-CONTAINING NANOCOMPOSITES BASED ON ISOTACTIC POLYPROPYLENE AND HIGH PRESSURE POLYETHYLENE

2021 ◽  
pp. 49-53
Author(s):  
S.K. Ragimova ◽  
Keyword(s):  
High Pressure ◽  
Isotactic Polypropylene ◽  
Copper Oxide Nanoparticles ◽  
Polymer Composition ◽  
Rheological Parameters ◽  
Structure And Properties ◽  
Mechanochemical Method ◽  
X Ray ◽  
Thermal Oxidative Stability ◽  
High Pressure Polyethylene

The effect of nanofilles additives containing copper oxide nanoparticles stabilized by a polymer matrix of high-pressure polyethylene obtained by the mechanochemical method on features of the structure and properties of metal-containing nanocomposites based on isotactic polypropylene and high-pressure polyethylene was studied using differential thermal (DTA) and X-ray phase (XRD) analyzes. The improvement of strength, deformation and rheological parameters, as well as thermal-oxidative stability of the obtained nanocomposites was revealed, that apparently, is associated with the synergistic effect of interfacial interaction of copper-containing nanoparticles in the PE matrix with the components of the PP/PE polymer composition

scholarly journals COPPER-CONTAINING NANOCOMPOSITES ON THE BASIS OF ISOTACTIC POLYPROPYLENE AND BUTADIENE-NITRILE RUBBER

2021 ◽  
pp. 38-43
Author(s):  
T.M. Gulieva ◽  
Keyword(s):  
High Pressure ◽  
Isotactic Polypropylene ◽  
Thermal Analyses ◽  
Nitrile Rubber ◽  
Rheological Parameters ◽  
Structure And Properties ◽  
Pressing Method ◽  
X Ray ◽  
High Pressure Polyethylene ◽  
Butadiene Nitrile Rubber

The influence of additives of nanofillers containing nanoparticles of copper oxides stabilized by a polymer matrix of maleinized high-pressure polyethylene obtained by the mechano-chemical method on the structure and properties features of metal-containing nanocomposites based on isotactic polypropylene and butadiene-nitrile rubber by x-ray phase and differential thermal analyses is studied. The improvement of strength, deformation and rheological parameters, as well as thermal-oxidative stability of the obtained nanocomposites was revealed, that is probably due to the synergistic effect of interaction of copper-containing nanoparticles with maleic groups of maleinated high-pressure polyethylene. It is shown that nanocomposites based on isotactic polypropylene and butadiene-nitrile rubber can be processed both by pressing method and by injection molding and extrusion methods that expands the scope of its application

Composites based on isotactic polypropylene and high-pressure polyethylene with zink-containing nanofillers

2021 ◽  
Vol 11 ◽  
pp. 47-53
Author(s):  
N. I. Kurbanova ◽  
◽  
S. K. Ragimova ◽  
N. A. Alimirzoeva ◽  
N. Ya. Ishenko ◽  
...  
Keyword(s):  
High Pressure ◽  
Isotactic Polypropylene ◽  
Polymer Composition ◽  
Rheological Parameters ◽  
Structure And Properties ◽  
Mechanochemical Method ◽  
Pressing Method ◽  
X Ray ◽  
Thermal Oxidative Stability ◽  
High Pressure Polyethylene

The effect of nanofiller (NF) additives containing zink oxide nanoparticles stabilized by a polymer matrix of high pressure polyethylene obtained by the mechanochemical method on the structure and properties of metal-containing nanocomposites based on isotactic polypropylene (PP) and high pressure polyethylene (PE) using differential thermal (DTA) and X-ray phase (XRF) analyzes. The improvement of strength, deformation and rheological parameters, as well as thermal-oxidative stability of the obtained nanocomposites was revealed, which, apparently, is associated with the synergistic effect of interfacial interaction of zink — containing nanoparticles in the PE matrix with the components of the PP/PE polymer composition. It is shown that nanocomposites based on PP/PE/NF can be processed both by pressing method and by injection molding and extrusion methods, which expands the scope of its application.

Properties of nanocomposites based on isotactic polypropylene and high-pressure polyethylene with metal-containing nanofillers

2020 ◽  
pp. 59-64
Author(s):  
N. I. Kurbanova ◽  
◽  
T. M. Gulieva ◽  
N. Ya. Ischenko ◽  
◽  
...  
Keyword(s):  
High Pressure ◽  
Synergistic Effect ◽  
Polymer Matrix ◽  
Isotactic Polypropylene ◽  
Rheological Parameters ◽  
Mechanochemical Method ◽  
X Ray ◽  
Effect Of Additives ◽  
High Pressure Polyethylene ◽  
Properties Of Composites

The effect of additives of nanofillers (NF) containing nanoparticles (NP) of copper oxide, stabilized by a polymer matrix of maleized polyethylene (MPE), obtained by the mechanochemical method, on the properties of composites based on isotactic polypropylene (PP) and high-pressure polyethylene (PE) was studied by X-ray phase (XRD) and thermogravimetric (TGA) analyzes. The enhancement of strength, deformation, and rheological parameters, as well as the thermo-oxidative stability of the obtained nanocomposites was revealed, which, apparently, is due to the synergistic effect of the interaction of copper-containing nanoparticles with anhydride groups of MPE. It is shown that nanocomposites based on PP/PE/NF can be processed both by pressing and injection molding and extrusion, which expands the scope of its application.

X-ray structure and properties of a cyclo[6]pyrrole[3]thiophene

2013 ◽  
Vol 17 (01n02) ◽  
pp. 27-35 ◽  
Author(s):  
Thanh-Tuan Bui ◽  
Aude Escande ◽  
Christian Philouze ◽  
Gianluca Cioci ◽  
Sudip Ghosh ◽  
...  
Keyword(s):  
Synchrotron Radiation ◽  
Structure And Properties ◽  
X Ray ◽  
Expanded Porphyrins ◽  
Pyrrole Derivative

A new member of the cyclo[n]pyrrole class of expanded porphyrins was prepared from the corresponding thiophene-containing terpyrrole precursor through use of a mild electrochemical oxidative procedure. The isolated macrocycle, featuring nine heterocyclic subunits directly connected through their α,α′-positions, is the largest cyclo[n]pyrrole derivative reported to date. The structure obtained via synchrotron radiation-based studies revealed a dimeric arrangement involving individual macrocyclic subunits.

Sensitivity of Macro- and Micro-Residual Stress States of Steel Surfaces to Thermal Influences Caused by Grinding Burn and Laser Treatments

2013 ◽  
Vol 768-769 ◽  
pp. 412-419
Author(s):  
Bernd Eigenmann ◽  
Antje Zösch ◽  
Martin Seidel
Keyword(s):  
Residual Stress ◽  
Threshold Values ◽  
Materials Properties ◽  
X Ray ◽  
Grinding Burn ◽  
Laser Treatments ◽  
Annealing Effects ◽  
Calibration Samples ◽  
Steel Surfaces ◽  
Stress States

Thermal influences, introduced intentionally or unintentionally do have significant effects on surfaces of steel components. Materials properties are reduced by annealing effects or even re-hardening zones can occur. Grinding, one of the most important technological processes for preci-sion manufacturing of hardened steel components, is an important source of thermal influences to steel surfaces. In pronounced cases, these influences are referred to as grinding burn. They are known as possible reasons for gray stains as well as development of cracks and pittings on heavy-duty gears and on roller bearings. The basic effect of thermal influences on the material is a change of the macro- and micro-residual stress states. Therefore, the knowledge of these residual stress states is of fundamental importance. The paper treats the mechanisms of grinding which can lead to thermal influences. Some characteristic appearances of grinding burn are shown and characterized by X-ray macro- and micro residual stress determinations. It is shown that defined laser treatments can be used to create reproducible thermal influences similar to grinding burn. Their effects are also characterized by X-ray residual stress measurements. The sensitivities of X-ray and metallographical investigations are compared. Defined laser traces are proposed as calibration samples for magnetic and eddy current measurements which allow to determine threshold values for the actual apparatus and measuring problem.

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