UV-activated coating polymer particle containing quaternary ammonium for antimicrobial fabrics

2022 ◽  
Author(s):  
Latdamanee Phutthatham ◽  
Piyalak Ngernchuklin ◽  
Dolnapa Kaewpa ◽  
Preeyaporn Chaiyasat ◽  
Amorn Chaiyasat
Keyword(s):  
Quaternary Ammonium ◽  
Polymer Particle

Catalyst- and oxidant-free electrochemical para-selective hydroxylation of N-arylamides in batch and continuous-flow

2020 ◽  
Vol 22 (19) ◽  
pp. 6437-6443
Author(s):  
Cheng-Kou Liu ◽  
Meng-Yi Chen ◽  
Xin-Xin Lin ◽  
Zheng Fang ◽  
Kai Guo
Keyword(s):  
Ammonium Salt ◽  
Quaternary Ammonium ◽  
Continuous Flow ◽  
Quaternary Ammonium Salt ◽  
Selective Hydroxylation

A catalyst-, oxidant-, acidic solvent- and quaternary ammonium salt-free electrochemical para-selective hydroxylation of N-arylamides at rt in batch and continuous-flow was developed.

A Study on Polymer Particle Flow in a Disk Zone of a Screw-Disk Extruder

2014 ◽  
Vol 35 (1) ◽  
pp. 121-135 ◽  
Author(s):  
Tomasz Rydzkowski ◽  
Iwona Michalska-Pożoga
Keyword(s):  
Mechanical Properties ◽  
Computer Simulations ◽  
Particle Motion ◽  
Polymer Melt ◽  
Experimental Tests ◽  
Polymer Particle ◽  
Particle Flow ◽  
Material Particle ◽  
Motion Trajectories ◽  
Stretching Effect

Abstract The paper presents the summary of research on polymer melt particle motion trajectories in a disc zone of a screw-disk extruder. We analysed two models of its structure, different in levels of taken simplifications. The analysis includes computer simulations of material particle flow and results of experimental tests to determine the properties of the resultant extrudate. Analysis of the results shows that the motion of melt in the disk zone of a screw-disk extruder is a superposition of pressure and dragged streams. The observed trajectories of polymer particles and relations of mechanical properties and elongation of the molecular chain proved the presence of a stretching effect on polymer molecular chains.

Determination of quaternary ammonium compounds in food products by the method of ultra-performance liquid chromatography/high resolution mass-spectrometry

2020 ◽  
Vol 86 (8) ◽  
pp. 23-31
Author(s):  
V. G. Amelin ◽  
D. S. Bolshakov
Keyword(s):  
Mass Spectrometry ◽  
High Resolution ◽  
Quaternary Ammonium ◽  
High Resolution Mass Spectrometry ◽  
Food Products ◽  
Quaternary Ammonium Compounds ◽  
High Resolution Mass ◽  
Ammonium Compounds ◽  
Resolution Mass

The goal of the study is developing a methodology for determination of the residual amounts of quaternary ammonium compounds (QAC) in food products by UHPLC/high-resolution mass spectrometry after water-acetonitrile extraction of the determined components from the analyzed samples. The identification and determination of QAC was carried out on an «UltiMate 3000» ultra-high-performance liquid chromatograph (Thermo Scientific, USA) equipped with a «maXis 4G» high-resolution quadrupole-time-of-flight mass spectrometric detector and an ion spray «ionBooster» source (Bruker Daltonics, Germany). Samples of milk, cheese (upper cortical layer), dumplings, pork, chicken skin and ground beef were used as working samples. Optimal conditions are specified for chromatographic separation of the mixture of five QAC, two of them being a mixture of homologues with a linear structure (including isomeric forms). The identification of QAC is carried out by the retention time, exact mass of the ions, and coincidence of the mSigma isotopic distribution. The limits for QAC detection are 0.1 – 0.5 ng/ml, the determination limits are 1 ng/ml for aqueous standard solutions. The determinable content of QAC in food products ranges within 1 – 100 ng/g. The results of analysis revealed the residual amount of QAC present in all samples, which confirms data of numerous sources of information about active use of QAC-based disinfectants in the meat and dairy industry. The correctness of the obtained results is verified by introduction of the additives in food products at a level of 10 ng/g for each QAC. The relative standard deviation of the analysis results does not exceed 0.18. The duration of the analysis is 30 – 40 min.

Synthesis and Performance of Polyoxy-ethylene Ester Quaternary Ammonium Salt

2013 ◽  
Vol 50 (1) ◽  
pp. 9-13 ◽  
Author(s):  
Yong-Qiang Sun ◽  
Wen-Jing Li ◽  
Wan-Xu Wang ◽  
Qiu-Xiao Li ◽  
Wieslaw Hreczuch ◽  
...  
Keyword(s):  
Ammonium Salt ◽  
Quaternary Ammonium ◽  
Quaternary Ammonium Salt ◽  
And Performance

Instability of Solutions of Quaternary Ammonium Permanganates in Dichloromethane

1997 ◽  
Vol 62 (6) ◽  
pp. 849-854 ◽  
Author(s):  
Vladislav Holba ◽  
Renata Košická
Keyword(s):  
Ammonium Salt ◽  
Rate Constants ◽  
Quaternary Ammonium ◽  
Quaternary Ammonium Salt ◽  
Activation Parameters ◽  
The Stability

The paper deals with instability of solutions of quaternary ammonium permanganates, QMnO4 (Q = tetraethyl-, tetra-1-propyl-, tetra-1-butyl-, tetra-1-pentyl-, tetra-1-octyl-, and cetyltrimethylammonium), in dichloromethane and presents the rate constants and activation parameters of the reduction of permanganate. Attention was paid to the properties of colloidal Mn(IV) intermediate. The stability of the solutions depends markedly on the quaternary ammonium salt used.

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