Chemical and Strontium Isotopic Compositions of the Hanjiang Basin Rivers in China: Anthropogenic Impacts and Chemical Weathering

2011 ◽  
Vol 17 (3) ◽  
pp. 243-264 ◽  
Author(s):  
Zhifang Xu ◽  
Chao Shi ◽  
Yang Tang ◽  
Hongyin Han
Keyword(s):  
Chemical Weathering ◽  
Anthropogenic Impacts ◽  
Isotopic Compositions

scholarly journals Sr isotopic characteristics in two small watersheds draining silicate and carbonate rocks: implication for studies on seawater Sr isotopic evolution

2014 ◽  
Vol 18 (2) ◽  
pp. 559-573
Author(s):  
W. H. Wu ◽  
H. B. Zheng ◽  
J. H. Cao ◽  
J. D. Yang
Keyword(s):  
River Water ◽  
Carbonate Rocks ◽  
Chemical Weathering ◽  
Silicate Weathering ◽  
86Sr Ratio ◽  
Weathering Rates ◽  
Isotopic Compositions ◽  
Small Watersheds ◽  
Isotopic Evolution ◽  
The Pearl River

Abstract. We systematically investigated the Sr isotopic characteristics of a small silicate watershed, the Xishui River a tributary of the Yangtze River, and a small carbonate watershed, the Guijiang River a tributary of the Pearl River. The results show that the two rivers have uncommon Sr isotopic characteristics compared with most small watersheds. Specifically, the silicate watershed (Xishui River) has relatively high Sr concentrations (0.468 to 1.70 μmol L−1 in summer and 1.30 to 3.17 μmol L−1 in winter, respectively) and low 87Sr/86Sr ratios (0.708686 to 0.709148 in summer and 0.708515 to 0.709305 in winter). The carbonate watershed (Guijiang River) has low Sr concentrations (0.124 to 1.098 μmol L−1) and high 87Sr/86Sr ratios (0.710558 to 0.724605). As the 87Sr/86Sr ratios in the Xishui River are lower than those in seawater, the 87Sr/86Sr ratio of seawater will decrease after the river water is transported to the oceans. Previous studies have also shown that some basaltic watersheds with extremely high chemical weathering rates reduced the seawater Sr isotope ratios. In other words, river catchments with high silicate weathering rates do not certainly transport highly radiogenic Sr into oceans. Therefore, the use of the variations in the seawater 87Sr/86Sr ratio to indicate the continental silicate weathering intensity may be questionable. In the Guijiang River catchment, the 87Sr/86Sr ratios of carbonate rocks and other sources (rainwater, domestic and industrial waste water, and agricultural fertilizer) are lower than 0.71. In comparison, some non-carbonate components, such as sand rocks, mud rocks, and shales, have relatively high Sr isotopic compositions. Moreover, granites accounted for only 5% of the drainage area have extremely high 87Sr/86Sr ratios with an average of greater than 0.8. Therefore, a few silicate components in carbonate rocks obviously increase the Sr isotopic compositions of the river water.

Geochemistry of the dissolved load of the Changjiang Basin rivers: Anthropogenic impacts and chemical weathering

2008 ◽  
Vol 72 (17) ◽  
pp. 4254-4277 ◽  
Author(s):  
B. Chetelat ◽  
C.-Q. Liu ◽  
Z.Q. Zhao ◽  
Q.L. Wang ◽  
S.L. Li ◽  
...  
Keyword(s):  
Chemical Weathering ◽  
Anthropogenic Impacts ◽  
Dissolved Load

Geochemical and Nd isotopic compositions of the Palaeoproterozoic metasedimentary rocks in the Kongling complex, nucleus of Yangtze craton, South China block: implications for provenance and tectonic evolution

2017 ◽  
Vol 155 (6) ◽  
pp. 1263-1276 ◽  
Author(s):  
XIAO-FEI QIU ◽  
XIAO-MING ZHAO ◽  
HONG-MEI YANG ◽  
SHAN-SONG LU ◽  
NIAN-WEN WU ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
South China ◽  
Chemical Weathering ◽  
Tectonic Setting ◽  
South China Block ◽  
Yangtze Craton ◽  
Metasedimentary Rocks ◽  
Isotopic Compositions ◽  
High Pressure Granulite

AbstractPalaeoproterozic metasedimentary rocks, also referred to as khondalites, characterized by Al-rich minerals, are extensively exposed in the nucleus of the Yangtze craton, South China block. Samples of garnet–sillimanite gneiss in the khondalite suite were collected from the Kongling complex for Nd isotopic and elemental geochemical study. These rocks are characterized by variable SiO2 contents ranging from 35.71 to 58.07 wt%, and have low CaO (0.45–0.84 wt%) but high Al2O3 (18.56–29.04 wt%), Cr (174–334 ppm) and Ni (42.5–153 ppm) contents. They have high CIW (Chemical Index of Weathering) values (90.4–94.7), indicating intense chemical weathering of the source material. The samples display light rare earth elements (LREE) enrichment with negative Eu anomalies (Eu/Eu*=0.40–0.68), and have flat heavy rare earth elements (HREE) patterns. The high contents of transition elements (e.g. Cr, Ni, Sc, V) and moderately radiogenic Nd isotopic compositions suggest that the paragneisses might be those of first-cycle erosion products of predominantly mafic rocks mixing with small amounts of felsic moderately evolved Archaean crustal source. Geochemical and Nd isotopic compositions reveal that at least some of the protoliths of Kongling khondalite were sourced from local pre-existing mafic igneous rocks in a continental arc tectonic setting. Combined with documented zircon U–Pb geochronological data, we propose that the Palaeoproterozoic high-pressure granulite-facies metamorphism, rapid weathering, erosion and deposition of the khondalites in the interior of the Yangtze craton might be related to a Palaeoproterozoic collisional orogenic event during 2.1–1.9 Ga, consistent with the worldwide contemporary orogeny, implying that the Yangtze craton may have been an important component of the Palaeoprotorozoic Columbia supercontinent.

scholarly journals A Strontium and Hydro-Geochemical Perspective on Human Impacted Tributary of the Mekong River Basin: Sources Identification, Fluxes, and CO2 Consumption

Water ◽  
2021 ◽  
Vol 13 (21) ◽  
pp. 3137
Author(s):  
Shitong Zhang ◽  
Guilin Han ◽  
Jie Zeng ◽  
Xuhuan Xiao ◽  
Fairda Malem
Keyword(s):  
River Basin ◽  
Chemical Weathering ◽  
Anthropogenic Impacts ◽  
Mekong River ◽  
Silicate Weathering ◽  
Sr Isotopes ◽  
Co2 Consumption ◽  
Geological Conditions ◽  
Basin Scale ◽  
Evaporite Dissolution

As the largest and most representative tributary of the Mekong River, the Mun River Basin (MRB) provides critical understanding of regional hydro-geochemical features and rock weathering processes on a basin scale. The present study measured strontium (Sr) isotopes with hydro-geochemistry data of 56 water samples in detail in the MRB in northeast Thailand. The dissolved Sr contents and 87Sr/86Sr isotopic ratios were reported to be 8.7–344.6 μg/L (average 126.9 μg/L) and 0.7085–0.7281 (average 0.7156), respectively. The concentrations of dissolved Sr in the mainstream slightly decreased from upstream to downstream, while the variation trend of 87Sr/86Sr was on the contrary. Correlation analysis showed that Na+ strongly correlated with Cl− (0.995, p < 0.01), while Ca2+ exhibited weak relationships with SO42− (0.356, p < 0.01). Samples of the MRB exhibited lower Mg2+/Na+, Ca2+/Na+, HCO3−/Na+ and 1000Sr/Na ratios, and gathered around the end-member of evaporite dissolution, with slight shift to silicate weathering end-member, demonstrating the dominant contribution of evaporite dissolution and silicate weathering on dissolved loads. Comparing with data of major world rivers from previous research, our results remained consistency with rivers draining through similar geological conditions. The dissolved Sr flux to the adjacent Mekong River was estimated to be 20.7 tons/year. In accordance with the forward model, silicate weathering rate and CO2 consumption rate during dry season were calculated to be 0.73 tons/km2/year and 1.94 × 104 mol/km2/year, and may get underestimated due to intense water consumption by extensive agricultural activities. The superimposed effect of anthropogenic impacts on the water environment could enhance chemical weathering, and thus should be taken into account in regional ion cycles and carbon budgets. These findings highlight the coupling analysis of Sr isotopes and hydro-geochemistry in Earth surface processes and provide basic investigation for sustainable regional water treatment mechanisms in the pan basin of the Mekong River.

scholarly journals Sr isotopic characteristics in two small watersheds draining typical silicate and carbonate rocks: implication for the studies on seawater Sr isotopic evolution

2013 ◽  
Vol 10 (6) ◽  
pp. 8031-8069 ◽  
Author(s):  
W. H. Wu ◽  
H. B. Zheng ◽  
J. D. Yang
Keyword(s):  
Carbonate Rocks ◽  
Chemical Weathering ◽  
Silicate Weathering ◽  
86Sr Ratio ◽  
Sr Isotope ◽  
River Catchment ◽  
Weathering Rates ◽  
Isotopic Compositions ◽  
Isotopic Evolution ◽  
The Pearl River

Abstract. We systematically investigated Sr isotopic characteristics of small silicate watershed – the tributary Xishui River of the Yangtze River, and small carbonate watershed – the tributary Guijiang River of the Pearl River. The results show that the Xishui River has relatively high Sr concentrations (0.468–1.70 μmol L−1 in summer and 1.30–3.17 μmol L−1 in winter, respectively) and low 87Sr/86Sr ratios (0.708686–0.709148 in summer and 0.708515–0.709305 in winter), which is similar to the characteristics of carbonate weathering. The Guijiang River has low Sr concentrations (0.124–1.098 μmol L−1) and high 87Sr/86Sr ratios (0.710558–0.724605), being characterized by silicate weathering. In the Xishui River catchment, chemical weathering rates in summer are far higher than those in winter, indicating significant influence of climate regime. However, slight differences of 87Sr/86Sr ratios between summer and winter show that influence of climate on Sr isotope is uncertainty owing to very similar Sr isotope values in silicate and carbonate bedrocks. As 87Sr/86Sr ratios in the Xishui River are lower than those in seawater, they will decrease 87Sr/86Sr ratio of seawater after transported into oceans. Previous studies also showed that some basaltic watersheds with extremely high chemical weathering rates reduced the seawater Sr isotope ratios. In other words, river catchments with high silicate weathering rates do not certainly transport highly radiogenic Sr into oceans. Therefore, it may be questionable that using the variations of seawater 87Sr/86Sr ratio to indicate the continental silicate weathering intensity. In the Guijiang River catchment, 87Sr/86Sr ratios of carbonate rocks and other sources (rainwater, domestic and industrial waste water, and agricultural fertilizer) are lower than 0.71. In comparison, some non-carbonate components, such as, sand rocks, mud rocks, shales, have relatively high Sr isotopic compositions. Moreover, granites accounted for only 5% of the drainage area have extremely high 87Sr/86Sr ratios with an average of over 0.8. Therefore, a few silicate components contained in carbonate rocks obviously increases the Sr isotopic compositions of the river water, and results in a positive effect on the rise of 87Sr/86Sr ratio of seawater. Therefore, the relation between Sr isotope evolution of seawater and continental weathering rate is complex, 87Sr/86Sr ratios of underlying bedrock in catchment could be an important controlling factors.

Justification of the need to increase the fertility of reclaimed alluvial soils of JSC «Moskovskoe»

2020 ◽  
pp. 44-48
Author(s):  
Andrey ilinsky ◽  
Alexander Nefedov ◽  
Konstantin Evsenkin
Keyword(s):  
Organic Matter ◽  
Agricultural Land ◽  
Crop Yields ◽  
Anthropogenic Impacts ◽  
Fertility Restoration ◽  
Research Work ◽  
Alluvial Soils ◽  
Ecological Stability ◽  
Reclaimed Land ◽  
Adverse Weather

Global climatic changes, technogenic pollution by pollutants, violations of technologies of exploitation of reclaimed land lead to a decrease in fertility and soil degradation of agricultural land. Adverse weather conditions, resulting in a lack of adequate flood water, and economic difficulties in agriculture make it difficult to fill the deficit of organic matter and macronutrients in reclaimed alluvial soils. The monitoring of agrochemical properties of alluvial meadow medium-loamy soil of the stationary site (reclaimed lands of JSC «Moskovskoye» of Ryazan region), located in the floodplain of the Oka river, conducted by the Meshchersky branch of Vniigim, showed the presence and intensification of degradation changes in the soil. Thus, comparing the agrochemical indicators in the layer 0–20 cm, carried out in 1995, with the indicators of 2019, it should be noted a decrease in soil fertility. The decrease in soil quality was expressed in a decrease in the amount of mobile phosphorus by 37.6 %, mobile potassium by 53.3 %. Also, during this time there was a decrease in organic matter by 9.1 %, and an increase in soil acidity was 0.6 pH. As a result of such changes, soils lose ecological stability and become more vulnerable to adverse weather and negative anthropogenic impacts. In such a situation, advanced agricultural techniques should be actively used to obtain guaranteed, environmentally safe crop yields and restore the fertility of degraded reclaimed soils. In this regard, there is a need to develop innovative methods of fertility restoration of degraded alluvial soils in reclaimed lands using multi-component organic-mineral ameliorants. Meshchersky branch performs research work in addressing this issue.

Submergence, nutrient enrichment, and tropical storm impacts on Spartina alterniflora in the microtidal northern Gulf of Mexico

2020 ◽  
Vol 644 ◽  
pp. 33-45
Author(s):  
JM Hill ◽  
PS Petraitis ◽  
KL Heck
Keyword(s):  
Gulf Of Mexico ◽  
Sea Level Rise ◽  
Sea Level ◽  
Spartina Alterniflora ◽  
Anthropogenic Impacts ◽  
Interactive Effects ◽  
Relative Sea Level ◽  
Hurricane Disturbance ◽  
Submergence Stress ◽  
Relative Sea Level Rise

Salt marshes face chronic anthropogenic impacts such as relative sea level rise and eutrophication, as well as acute disturbances from tropical storms that can affect the productivity of these important communities. However, it is not well understood how marshes already subjected to eutrophication and sea level rise will respond to added effects of episodic storms such as hurricanes. We examined the interactive effects of nutrient addition, sea level rise, and a hurricane on the growth, biomass accumulation, and resilience of the saltmarsh cordgrass Spartina alterniflora in the Gulf of Mexico. In a microtidal marsh, we manipulated nutrient levels and submergence using marsh organs in which cordgrasses were planted at differing intertidal elevations and measured the impacts of Hurricane Isaac, which occurred during the experiment. Prior to the hurricane, grasses at intermediate and high elevations increased in abundance. After the hurricane, all treatments lost approximately 50% of their shoots, demonstrating that added nutrients and elevation did not provide resistance to hurricane disturbance. At the end of the experiment, only the highest elevations had been resilient to the hurricane, with increased above- and belowground growth. Added nutrients provided a modest increase in above- and belowground growth, but only at the highest elevations, suggesting that only elevation will enhance resilience to hurricane disturbance. These results empirically demonstrate that S. alterniflora in microtidal locations already subjected to submergence stress is less able to recover from storm disturbance and suggests we may be underestimating the loss of northern Gulf Coast marshes due to relative sea level rise.

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