scholarly journals Sr isotopic characteristics in two small watersheds draining silicate and carbonate rocks: implication for studies on seawater Sr isotopic evolution

2014 ◽  
Vol 18 (2) ◽  
pp. 559-573
Author(s):  
W. H. Wu ◽  
H. B. Zheng ◽  
J. H. Cao ◽  
J. D. Yang
Keyword(s):  
River Water ◽  
Carbonate Rocks ◽  
Chemical Weathering ◽  
Silicate Weathering ◽  
86Sr Ratio ◽  
Weathering Rates ◽  
Isotopic Compositions ◽  
Small Watersheds ◽  
Isotopic Evolution ◽  
The Pearl River

Abstract. We systematically investigated the Sr isotopic characteristics of a small silicate watershed, the Xishui River a tributary of the Yangtze River, and a small carbonate watershed, the Guijiang River a tributary of the Pearl River. The results show that the two rivers have uncommon Sr isotopic characteristics compared with most small watersheds. Specifically, the silicate watershed (Xishui River) has relatively high Sr concentrations (0.468 to 1.70 μmol L−1 in summer and 1.30 to 3.17 μmol L−1 in winter, respectively) and low 87Sr/86Sr ratios (0.708686 to 0.709148 in summer and 0.708515 to 0.709305 in winter). The carbonate watershed (Guijiang River) has low Sr concentrations (0.124 to 1.098 μmol L−1) and high 87Sr/86Sr ratios (0.710558 to 0.724605). As the 87Sr/86Sr ratios in the Xishui River are lower than those in seawater, the 87Sr/86Sr ratio of seawater will decrease after the river water is transported to the oceans. Previous studies have also shown that some basaltic watersheds with extremely high chemical weathering rates reduced the seawater Sr isotope ratios. In other words, river catchments with high silicate weathering rates do not certainly transport highly radiogenic Sr into oceans. Therefore, the use of the variations in the seawater 87Sr/86Sr ratio to indicate the continental silicate weathering intensity may be questionable. In the Guijiang River catchment, the 87Sr/86Sr ratios of carbonate rocks and other sources (rainwater, domestic and industrial waste water, and agricultural fertilizer) are lower than 0.71. In comparison, some non-carbonate components, such as sand rocks, mud rocks, and shales, have relatively high Sr isotopic compositions. Moreover, granites accounted for only 5% of the drainage area have extremely high 87Sr/86Sr ratios with an average of greater than 0.8. Therefore, a few silicate components in carbonate rocks obviously increase the Sr isotopic compositions of the river water.

scholarly journals Sr isotopic characteristics in two small watersheds draining typical silicate and carbonate rocks: implication for the studies on seawater Sr isotopic evolution

2013 ◽  
Vol 10 (6) ◽  
pp. 8031-8069 ◽  
Author(s):  
W. H. Wu ◽  
H. B. Zheng ◽  
J. D. Yang
Keyword(s):  
Carbonate Rocks ◽  
Chemical Weathering ◽  
Silicate Weathering ◽  
86Sr Ratio ◽  
Sr Isotope ◽  
River Catchment ◽  
Weathering Rates ◽  
Isotopic Compositions ◽  
Isotopic Evolution ◽  
The Pearl River

Abstract. We systematically investigated Sr isotopic characteristics of small silicate watershed – the tributary Xishui River of the Yangtze River, and small carbonate watershed – the tributary Guijiang River of the Pearl River. The results show that the Xishui River has relatively high Sr concentrations (0.468–1.70 μmol L−1 in summer and 1.30–3.17 μmol L−1 in winter, respectively) and low 87Sr/86Sr ratios (0.708686–0.709148 in summer and 0.708515–0.709305 in winter), which is similar to the characteristics of carbonate weathering. The Guijiang River has low Sr concentrations (0.124–1.098 μmol L−1) and high 87Sr/86Sr ratios (0.710558–0.724605), being characterized by silicate weathering. In the Xishui River catchment, chemical weathering rates in summer are far higher than those in winter, indicating significant influence of climate regime. However, slight differences of 87Sr/86Sr ratios between summer and winter show that influence of climate on Sr isotope is uncertainty owing to very similar Sr isotope values in silicate and carbonate bedrocks. As 87Sr/86Sr ratios in the Xishui River are lower than those in seawater, they will decrease 87Sr/86Sr ratio of seawater after transported into oceans. Previous studies also showed that some basaltic watersheds with extremely high chemical weathering rates reduced the seawater Sr isotope ratios. In other words, river catchments with high silicate weathering rates do not certainly transport highly radiogenic Sr into oceans. Therefore, it may be questionable that using the variations of seawater 87Sr/86Sr ratio to indicate the continental silicate weathering intensity. In the Guijiang River catchment, 87Sr/86Sr ratios of carbonate rocks and other sources (rainwater, domestic and industrial waste water, and agricultural fertilizer) are lower than 0.71. In comparison, some non-carbonate components, such as, sand rocks, mud rocks, shales, have relatively high Sr isotopic compositions. Moreover, granites accounted for only 5% of the drainage area have extremely high 87Sr/86Sr ratios with an average of over 0.8. Therefore, a few silicate components contained in carbonate rocks obviously increases the Sr isotopic compositions of the river water, and results in a positive effect on the rise of 87Sr/86Sr ratio of seawater. Therefore, the relation between Sr isotope evolution of seawater and continental weathering rate is complex, 87Sr/86Sr ratios of underlying bedrock in catchment could be an important controlling factors.

Silicate weathering rates decoupled from the 87Sr/86Sr ratio of the dissolved load during Himalayan erosion

2003 ◽  
Vol 201 (1-2) ◽  
pp. 119-139 ◽  
Author(s):  
Lee Oliver ◽  
Nigel Harris ◽  
Mike Bickle ◽  
Hazel Chapman ◽  
Nancy Dise ◽  
...  
Keyword(s):  
Silicate Weathering ◽  
86Sr Ratio ◽  
Weathering Rates ◽  
Dissolved Load

scholarly journals Direct measurement of fungal contribution to silicate weathering rates in soil

Geology ◽  
2021 ◽  
Author(s):  
Bastien Wild ◽  
Gwenaël Imfeld ◽  
Damien Daval
Keyword(s):  
Chemical Weathering ◽  
Silicate Weathering ◽  
Nutrient Fluxes ◽  
Weathering Rates ◽  
Relative Contribution ◽  
Quantitative Estimates ◽  
Fungal Hyphae ◽  
Nanoscale Topography ◽  
Natural Settings

Chemical weathering produces solutes that control groundwater chemistry and supply ecosystems with essential nutrients. Although microbial activity influences silicate weathering rates and associated nutrient fluxes, its relative contribution to silicate weathering in natural settings remains largely unknown. We provide the first quantitative estimates of in situ silicate weathering rates that account for microbially induced dissolution and identify microbial actors associated with weathering. Nanoscale topography measurements showed that fungi colonizing olivine [(Mg,Fe)2SiO4] samples in a Mg-deficient forest soil accounted for up to 16% of the weathering flux after 9 mo of incubation. A local increase in olivine weathering rate was measured and attributed to fungal hyphae of Verticillium sp. Altogether, this approach provides quantitative parameters of bioweathering (i.e., rates and actors) and opens new avenues to improve elemental budgets in natural settings.

scholarly journals Hydro-Geochemistry of the River Water in the Jiulongjiang River Basin, Southeast China: Implications of Anthropogenic Inputs and Chemical Weathering

2019 ◽  
Vol 16 (3) ◽  
pp. 440 ◽  
Author(s):  
Xiaoqiang Li ◽  
Guilin Han ◽  
Man Liu ◽  
Kunhua Yang ◽  
Jinke Liu
Keyword(s):  
River Water ◽  
River Basin ◽  
Human Activities ◽  
Chemical Weathering ◽  
Silicate Weathering ◽  
Carbonate Weathering ◽  
Southeast China ◽  
Anthropogenic Inputs ◽  
Weathering Process ◽  
Jiulongjiang River

This study focuses on the chemical weathering process under the influence of human activities in the Jiulongjiang River basin, which is the most developed and heavily polluted area in southeast China. The average total dissolved solid (TDS) of the river water is 116.6 mg/L and total cation concentration ( TZ + ) is 1.5 meq/L. Calcium and HCO 3 − followed by Na + and SO 4 2 − constitute the main species in river waters. A mass balance based on cations calculation indicated that the silicate weathering (43.3%), carbonate weathering (30.7%), atmospheric (15.6%) and anthropogenic inputs (10.4%) are four reservoirs contributing to the dissolved load. Silicates (SCW) and carbonates (CCW) chemical weathering rates are calculated to be approximately 53.2 ton/km2/a and 15.0 ton/km2/a, respectively. When sulfuric and nitric acid from rainfall affected by human activities are involved in the weathering process, the actual atmospheric CO 2 consumption rates are estimated at 3.7 × 105 mol/km2/a for silicate weathering and 2.2 × 105 mol/km2/a for carbonate weathering. An overestimated carbon sink (17.4 Gg C / a ) is about 27.0% of the CO 2 consumption flux via silicate weathering in the Jiulongjiang River basin, this result shows the strong effects of anthropogenic factors on atmospheric CO 2 level and current and future climate change of earth.

scholarly journals Temporary and net sinks of atmospheric CO<sub>2</sub> due to chemical weathering in subtropical catchment with mixing carbonate and silicate lithology

2020 ◽  
Vol 17 (14) ◽  
pp. 3875-3890
Author(s):  
Yingjie Cao ◽  
Yingxue Xuan ◽  
Changyuan Tang ◽  
Shuai Guan ◽  
Yisheng Peng
Keyword(s):  
Acid Deposition ◽  
Chemical Weathering ◽  
Dissolved Inorganic Carbon ◽  
Silicate Weathering ◽  
Carbonate Weathering ◽  
Weathering Rate ◽  
Weathering Rates ◽  
Hypsometric Integral ◽  
Co2 Sink ◽  
Chemical Weathering Rate

Abstract. The study provided the major ion chemistry, chemical weathering rates and temporary and net CO2 sinks in the Bei Jiang, which was characterized as a hyperactive region with high chemical weathering rates, carbonate and silicate mixing lithology, and abundant sulfuric acid chemical weathering agent of acid deposition and acid mining drainage (AMD) origins. The total chemical weathering rate of 85.46 t km−2 a−1 was comparable to that of other rivers in the hyperactive zones between the latitudes 0 and 30∘. A carbonate weathering rate of 61.15 t km−2 a−1 contributed to about 70 % of the total. The lithology, runoff, and geomorphology had a significant influence on the chemical weathering rate. The proportion of carbonate outcrops had a significant positive correlation with the chemical weathering rate. Due to the interaction between dilution and compensation effect, a significant positive linear relationship was detected between runoff and total carbonate and silicate weathering rates. The geomorphology factors such as catchment area, average slope, and hypsometric integral value (HI) had nonlinear correlation with chemical weathering rate and showed significant scale effect, which revealed the complexity in chemical weathering processes. Dissolved inorganic carbon (DIC) apportionment showed that CCW (carbonate weathering by CO2) was the dominant origin of DIC (35 %–87 %). SCW (carbonate weathering by H2SO4) (3 %–15 %) and CSW (silicate weathering by CO2) (7 %–59 %) were non-negligible processes. The temporary CO2 sink was 823.41×103 mol km−2 a−1. Compared with the temporary sink, the net sink of CO2 for the Bei Jiang was approximately 23.18×103 mol km−2 a−1 of CO2 and was about 2.82 % of the “temporary” CO2 sink. Human activities (sulfur acid deposition and AMD) dramatically decreased the CO2 net sink, even making chemical weathering a CO2 source to the atmosphere.

scholarly journals Temporary and net sinks of atmospheric CO<sub>2</sub> due to chemical weathering in subtropical catchment with mixing carbonate and silicate lithology

2019 ◽  
Author(s):  
Yingjie Cao ◽  
Yingxue Xuan ◽  
Changyuan Tang ◽  
Shuai Guan ◽  
Yisheng Peng
Keyword(s):  
Acid Deposition ◽  
Chemical Weathering ◽  
Silicate Weathering ◽  
Carbonate Weathering ◽  
Weathering Rate ◽  
Weathering Rates ◽  
Beijiang River ◽  
Hypsometric Integral ◽  
Co2 Sink ◽  
Chemical Weathering Rate

Abstract. The study provides the major ion chemistry, chemical weathering rates and temporary and net CO2 sinks in the Beijiang River, which was characterized as hyperactive region with high chemical weathering rates, carbonate and silicate mixing lithology and abundant sulfuric acid chemical weathering agent with acid deposition and AMD origins. The total chemical weathering rate of 85.46 t km−2 a−1 was comparable to other rivers in the hyperactive zones between the latitude 0–30°. Carbonate weathering rates of 61.15 t km−2 a−1 contributed to about 70 % of the total. The lithology, runoff and geomorphology had significant influence on the chemical weathering rate. The proportion of carbonate outcrops had significant positive correlation with the chemical weathering rate. Due to the interaction between dilution and compensation effect, significant positive linear relationship was detected between runoff and total, carbonate and silicate weathering rates. The geomorphology factors such as catchment area, average slope and hypsometric integral value (HI) had non-linear correlation on chemical weathering rate and showed significant scale effect, which revealed the complexity in chemical weathering processes. DIC-apportionment showed that CCW (Carbonate weathering by CO2) was the dominant origin of DIC (35 %–87 %) and that SCW (Carbonate weathering by H2SO4) (3 %–15 %) and CSW (Silicate weathering by CO2) (7 %–59 %) were non-negligible processes. The temporary CO2 sink was 823.41 103 mol km−2 a−1. Compared with the temporary sink, the net sink of CO2 for the Beijiang River was approximately 23.18 × 103 mol km−2 a−1 of CO2 and was about 2.82 % of the temporary CO2 sink. Human activities (sulfur acid deposition and AMD) dramatically decreased the CO2 net sink and even make chemical weathering a CO2 source to the atmosphere.

scholarly journals Global silicate weathering flux overestimated because of sediment–water cation exchange

2020 ◽  
Vol 118 (1) ◽  
pp. e2016430118
Author(s):  
Edward T. Tipper ◽  
Emily I. Stevenson ◽  
Victoria Alcock ◽  
Alasdair C. G. Knight ◽  
J. Jotautas Baronas ◽  
...  
Keyword(s):  
Cation Exchange ◽  
River Water ◽  
Chemical Weathering ◽  
Global Scale ◽  
Mineral Weathering ◽  
Climate Feedback ◽  
Silicate Weathering ◽  
Exchange Equilibrium ◽  
Silicate Mineral ◽  
River Water Chemistry

Rivers carry the dissolved and solid products of silicate mineral weathering, a process that removesCO2from the atmosphere and provides a key negative climate feedback over geological timescales. Here we show that, in some river systems, a reactive exchange pool on river suspended particulate matter, bonded weakly to mineral surfaces, increases the mobile cation flux by 50%. The chemistry of both river waters and the exchange pool demonstrates exchange equilibrium, confirmed by Sr isotopes. Global silicate weathering fluxes are calculated based on riverine dissolved sodium (Na+) from silicate minerals. The large exchange pool supplies Na+of nonsilicate origin to the dissolved load, especially in catchments with widespread marine sediments, or where rocks have equilibrated with saline basement fluids. We quantify this by comparing the riverine sediment exchange pool and river water chemistry. In some basins, cation exchange could account for the majority of sodium in the river water, significantly reducing estimates of silicate weathering. At a global scale, we demonstrate that silicate weathering fluxes are overestimated by 12 to 28%. This overestimation is greatest in regions of high erosion and high sediment loads where the negative climate feedback has a maximum sensitivity to chemical weathering reactions. In the context of other recent findings that reduce the netCO2consumption through chemical weathering, the magnitude of the continental silicate weathering fluxes and its implications for solid EarthCO2degassing fluxes need to be further investigated.

scholarly journals Supply-limited weathering regime in a tropical shields basin (Ogooué River basin, Gabon)

2020 ◽  
Author(s):  
Jean-Sébastien Moquet ◽  
Julien Bouchez ◽  
Jean-Jacques Braun ◽  
Sakaros Bogning ◽  
Auguste Mbonda ◽  
...  
Keyword(s):  
Chemical Weathering ◽  
Biogeochemical Cycles ◽  
Tectonic Activity ◽  
Silicate Weathering ◽  
Weathering Rate ◽  
Weathering Rates ◽  
Erosion Rates ◽  
The World ◽  
Weathering Intensity

&lt;p&gt;At the global scale and on geological time scales, mechanical erosion and chemical weathering budgets are linked. Together, these processes contribute to the formation and the degradation of the Earth&amp;#8217;s critical zone and to the biogeochemical cycles of elements. While the weathering of hot and humid shields areas exhibit low weathering rates because of the depth of the mature depleted soil mantle there, shields areas dominate the continents areas over intertropical regions and, therefore, represent a significant proportion of the global delivery of dissolved matter to the oceans. In addition, these environments are under supply-limited conditions (the weathering rate is limited by the low rates of the erosion) and thus particularly sensitive to long-term variability erosion rates. Despite this importance, weathering-erosion budgets and rates estimation in these environments is sparse, and generally performed at a local scale (soil profiles) or, when performed at a larger catchment scale, the intra cratonic characteristics variabilities (e. g. the diversity of mechanical erosional regimes) are usually not singled out.&lt;/p&gt;&lt;p&gt;In the present study, we explored the variability of the weathering intensity of the Ogoou&amp;#233; sub-basins (Western central Africa, Gabon) as a function of their geomorphologic, tectonic and lithological setting variability. We analyzed major and trace elements concentration and the strontium and neodymium isotopes of water, suspended matter sediments and bedload sampled in 24 Ogoou&amp;#233; tributaries (September 2017 campaign). Our results show that shield areas exhibit a high variability of chemical weathering intensity, which follows the erosional regime characteristics of the studied sub-basins, likely related to their tectonic activity. Three regions can be distinguished: The Bateke plateau (East sub-basins - PB), is composed of pure sandstones (quartz) and is inert in term of tectonic activity and therefore in term of erosion and weathering budget; the northern sub-basins (NB) are subjected to low tectonic activity and exhibit slightly higher erosion and weathering intensity than PB region and, by comparison, southern sub-basins (SB) exhibits uplift activity which is traduced by more intensive erosion and weathering processes.&lt;/p&gt;&lt;p&gt;The annual dissolved solid budget of the Ogoou&amp;#233; basin is ~2.52 t.yr&lt;sup&gt;-1&lt;/sup&gt; for a rate of 11.7 t.km&lt;sup&gt;-2&lt;/sup&gt;.yr&lt;sup&gt;-1&lt;/sup&gt;. According to the source discrimination method performed based on the geochemical analysis, the atmospheric inputs contributes to around 20% to the TDS, the silicate weathering contribution dominates the dissolved exports throughout 70% of its production while the carbonates weathering lowly contributes to the TDS production.&lt;/p&gt;&lt;p&gt;By comparison to the other large shields rivers, this basin exhibit a lower range of chemical silicate weathering rate than most of the world&amp;#8217;s large rivers, with values similar to those of the Congo River. This new dataset provides a key information to complete the World River chemistry database, which is limited for inter-tropical regions, especially in tectonically quiescent environments. Moreover, this study provides new data for tropical shields contexts allowing for the exploration of the interactions between erosion rates and climate in the control of continental weathering rates, and their relationships with long-term carbon cycle and short-term biogeochemical cycles.&lt;/p&gt;

scholarly journals Co-variation of silicate, carbonate and sulfide weathering drives CO2 release with erosion

2021 ◽  
Vol 14 (4) ◽  
pp. 211-216
Author(s):  
Aaron Bufe ◽  
Niels Hovius ◽  
Robert Emberson ◽  
Jeremy K. C. Rugenstein ◽  
Albert Galy ◽  
...  
Keyword(s):  
Erosion Rate ◽  
Global Climate ◽  
Stream Water ◽  
Sulfide Oxidation ◽  
Silicate Weathering ◽  
Emission Rates ◽  
Mountain Ranges ◽  
Weathering Rates ◽  
Southern Taiwan ◽  
Co2 Release

AbstractGlobal climate is thought to be modulated by the supply of minerals to Earth’s surface. Whereas silicate weathering removes carbon dioxide (CO2) from the atmosphere, weathering of accessory carbonate and sulfide minerals is a geologically relevant source of CO2. Although these weathering pathways commonly operate side by side, we lack quantitative constraints on their co-variation across erosion rate gradients. Here we use stream-water chemistry across an erosion rate gradient of three orders of magnitude in shales and sandstones of southern Taiwan, and find that sulfide and carbonate weathering rates rise with increasing erosion, while silicate weathering rates remain steady. As a result, on timescales shorter than marine sulfide compensation (approximately 106–107 years), weathering in rapidly eroding terrain leads to net CO2 emission rates that are at least twice as fast as CO2 sequestration rates in slow-eroding terrain. We propose that these weathering reactions are linked and that sulfuric acid generated from sulfide oxidation boosts carbonate solubility, whereas silicate weathering kinetics remain unaffected, possibly due to efficient buffering of the pH. We expect that these patterns are broadly applicable to many Cenozoic mountain ranges that expose marine metasediments.

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