In2S3 nanoparticles dispersed on g-C3N4 nanosheets: role of heterojunctions in photoinduced charge transfer and photoelectrochemical and photocatalytic performance

2017 ◽  
Vol 52 (12) ◽  
pp. 7077-7090 ◽  
Author(s):  
Sanjay B. Kokane ◽  
R. Sasikala ◽  
D. M. Phase ◽  
S. D. Sartale
2020 ◽  
Vol 49 (37) ◽  
pp. 12892-12917
Author(s):  
Xinlin Li ◽  
Sreehari Surendran Rajasree ◽  
Jierui Yu ◽  
Pravas Deria

Understanding PCT taking place within MOFs is crucial for designing porous photo/electrocatalysts and luminescent sensors. Unique features of PCT in MOFs and recent progress along with state-of-the-art characterization methods are discussed in the context of its applications.


2017 ◽  
Vol 19 (16) ◽  
pp. 10511-10517 ◽  
Author(s):  
V. V. Golovanov ◽  
B. V. Nazarchuk ◽  
V. V. Golovanova ◽  
N. V. Tkachenko ◽  
T. T. Rantala

A theoretical study of a phthalocyanine molecule anchored on CdSe quantum dots demonstrated strong orientational effects and the important role of a linker in the photoinduced charge transfer between the components.


RSC Advances ◽  
2017 ◽  
Vol 7 (1) ◽  
pp. 231-237 ◽  
Author(s):  
Di Li ◽  
Fenfen Shi ◽  
Deli Jiang ◽  
Min Chen ◽  
Weidong Shi

CdIn2S4/g-C3N4 heterojunction with excellent photocatalytic activities have been synthesized. The enhanced photocatalytic performance might be ascribed to the efficient photoinduced charge transfer derived from the heterojunction structure.


1996 ◽  
Vol 93 ◽  
pp. 1697-1713 ◽  
Author(s):  
P Changenet ◽  
P Plaza ◽  
MM Martin ◽  
YH Meyer ◽  
W Rettig

2020 ◽  
Author(s):  
Zhengqing Tong ◽  
Margaret S. Cheung ◽  
Barry D. Dunietz ◽  
Eitan Geva ◽  
Xiang Sun

The nonequilibrium Fermi’s golden rule (NE-FGR) describes the time-dependent rate coefficient for electronic transitions, when the nuclear degrees of freedom start out in a <i>nonequilibrium</i> state. In this letter, the linearized semiclassical (LSC) approximation of the NE-FGR is used to calculate the photoinduced charge transfer rates in the carotenoid-porphyrin-C<sub>60</sub> molecular triad dissolved in explicit tetrahydrofuran. The initial nonequilibrium state corresponds to impulsive photoexcitation from the equilibrated ground-state to the ππ* state, and the porphyrin-to-C<sub>60</sub> and the carotenoid-to-C<sub>60</sub> charge transfer rates are calculated. Our results show that accounting for the nonequilibrium nature of the initial state significantly enhances the transition rate of the porphyrin-to-C<sub>60</sub> CT process. We also derive the instantaneous Marcus theory (IMT) from LSC NE-FGR, which casts the CT rate coefficients in terms of a Marcus-like expression, with explicitly time-dependent reorganization energy and reaction free energy. IMT is found to reproduce the CT rates in the system under consideration remarkably well.


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