Super insulation and hydrophobic silica-based aerogels doped with TiO2 powder (8wt %) were successfully synthesized by using cost effective processing from Tetraeth oxysilane (TEOS). After aging and washing of wet gel, surface modification were modified using trimethylchlorosilane (TMCS) via one-step solvent exchange and surface modification. And the proper molar ratio of TMCS to pore water is 0.02. The microstructure and morphology of the ultralow density silica aerogels were characterized by the specific surface area, SBET, SEM, and the pore size distribution techniques. From the results, the obtained aerogel doped with TiO2 powder exhibited excellent physical properties with less than 10% volume shrinkage, extremely high specific surface area (652 m2/g) and super hydrophobicity (contact angle of~145°). It should be noted that TiO2 powders are physically embedded by SiO2 aerogel, and there is an obvious Ti–O–Ti and Si–O–Si bonding group based on structural analysis. The thermal properties of silica aerogel were determined using the Hot Disk device, composite aerogel exhibited thermal conductivities of 0.0426 W/m·K at 700°C, TiO2 powders effectively suppressed the intensified thermal radiations at high temperatures to achieve ultralow thermal conductivities. These results have important implications for designing novel structure of porous materials of high performance for silica aerogels.