Facile synthesis of silica aerogel composites via ambient-pressure drying without surface modification or solvent exchange

Vacuum ◽  
2020 ◽  
Vol 173 ◽  
pp. 109117 ◽  
Author(s):  
Dongxuan Du ◽  
Yonggang Jiang ◽  
Junzong Feng ◽  
Liangjun Li ◽  
Jian Feng
RSC Advances ◽  
2015 ◽  
Vol 5 (68) ◽  
pp. 55579-55587 ◽  
Author(s):  
Sekai Zong ◽  
Wei Wei ◽  
Zhifeng Jiang ◽  
Zaoxue Yan ◽  
Jianjun Zhu ◽  
...  

This preparation method of skeleton improvement of wet silica beads by ambient pressure drying is suitable for economic and large-scale industrial production of silica aerogel beads.


2017 ◽  
Vol 83 (1) ◽  
pp. 53-63 ◽  
Author(s):  
Shan Yun ◽  
Tan Guo ◽  
Jiadong Zhang ◽  
Lei He ◽  
Yanxing Li ◽  
...  

2013 ◽  
Vol 544 ◽  
pp. 144-147 ◽  
Author(s):  
Hui Xu ◽  
Gui Ln Fu ◽  
Yu Qiang Guo ◽  
Jing Chun Tu ◽  
Yong Chen

Silica aerogel has been prepared by ambient pressure drying technique using water glass as starting materials. Solvent exchange and surface modification were simultaneously conducted by immersing the wet hydrogel in EtOH/TMCS(Tri Methyl Chloro Silane)/hexane solution. The silica aerogel was obtained with the density of 0.110g•cm-3 and 95.2% porosity. The specific surface area of the silica aerogel was 472.5m2•g-1 with a average pore size distrubution of 27.5nm. FT-IR spectrum analysis showed that the surface of the silica aerogel was modified by Si-CH3 groups, which allowed the aerogel to be hydrophobic.


Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 3983
Author(s):  
Dongxuan Du ◽  
Fengqi Liu ◽  
Yonggang Jiang ◽  
Junzong Feng ◽  
Liangjun Li ◽  
...  

To further reduce the manufacturing cost and improve safety, silica aerogel composites (SAC) with low density and low thermal conductivity synthesized via ambient pressure drying (APD) technology have gradually become one of the most focused research areas. As a solvent, ethanol is flammable and needs to be replaced by other low surface tension solvents, which is dangerous and time-consuming. Therefore, the key steps of solvent replacement and surface modification in the APD process need to be simplified. Here, we demonstrate a facile strategy for preparing high strength mullite fiber reinforced SAC, which is synthesized by APD using water as a solvent, rather than using surface modification or solvent replacement. The effects of the fiber density on the physical properties, mechanical properties, and thermal conductivities of SAC are discussed in detail. The results show that when the fiber density of SAC is 0.24 g/cm3, the thermal conductivity at 1100 °C is 0.127 W/m·K, and the compressive strength at 10% strain is 1.348 MPa. Because of the simple synthesis process and excellent thermal-mechanical performance, the SAC is expected to be used as an efficient and economical insulation material.


Molecules ◽  
2018 ◽  
Vol 23 (12) ◽  
pp. 3192 ◽  
Author(s):  
Dong Chen ◽  
Xiaodong Wang ◽  
Wenhui Ding ◽  
Wenbing Zou ◽  
Qiong Zhu ◽  
...  

Owing to their ultra-low thermal conductivity, silica aerogels are promising thermal insulators; however, their extensive application is limited by their high production cost. Thus, scientists have started to explore low-cost and easy preparation processes of silica aerogels. In this work, a low-cost method was proposed to prepare silica aerogels with industrial silica hydrosol and a subsequent ambient pressure drying (APD) process. Various surfactants (cationic, amphoteric, or anionic) were added to avoid solvent exchange and surface modification during the APD process. The effects of various surfactants on the microstructure, thermal conductivity, and thermal stability of the silica aerogels were studied. The results showed that the silica aerogels prepared with a cationic or anionic surfactant have better thermal stability than that prepared with an amphoteric surfactant. After being heated at 600 °C, the silica aerogel prepared with a cationic surfactant showed the highest specific surface area of 131 m2∙g−1 and the lowest thermal conductivity of 0.038 W∙m−1∙K−1. The obtained low-cost silica aerogel with low thermal conductivity could be widely applied as a thermal insulator for building and industrial energy-saving applications.


2019 ◽  
Vol 11 (45) ◽  
pp. 5784-5792 ◽  
Author(s):  
Xiangping Ji ◽  
Juanjuan Feng ◽  
Chunying Li ◽  
Sen Han ◽  
Jiaqing Feng ◽  
...  

A silica aerogel with high surface area was prepared by an acid–base two-step catalytic sol–gel method under ambient pressure drying.


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