Thermolysis mechanism of chromium nitrate nonahydrate and computerized modeling of intermediate products

2013 ◽  
Vol 114 (3) ◽  
pp. 1021-1027 ◽  
Author(s):  
P. Melnikov ◽  
V. A. Nascimento ◽  
I. V. Arkhangelsky ◽  
L. Z. Zanoni Consolo ◽  
L. C. S. de Oliveira
Keyword(s):  
Chromium Nitrate ◽  
Intermediate Products ◽  
Nitrate Nonahydrate

The Use of Piezosensors for Determination of Carboxylic Acids in the Intermediate Products of Edible Ethanol Production

2020 ◽  
Vol 56 (14) ◽  
pp. 1379-1383
Author(s):  
Cao Nhat Linh ◽  
O. V. Duvanova ◽  
S. Yu. Nikitina ◽  
A. N. Zyablov
Keyword(s):  
Ethanol Production ◽  
Carboxylic Acids ◽  
Intermediate Products

Polarographic reduction of α-(4-ethylbenzoyl)-α,β-dibromopropionic acid on mercury dropping electrode

1979 ◽  
Vol 44 (4) ◽  
pp. 1318-1323
Author(s):  
Miloslava Počtová
Keyword(s):  
Electrochemical Reduction ◽  
Carbonyl Group ◽  
Polarographic Reduction ◽  
Polarographic Wave ◽  
Intermediate Products ◽  
Active Intermediate

A mechanism of the electrochemical reduction of β-(4-ethylbenzoyl)-α,β-dibromopropionic acid is suggested based on the results of classical polarography and polarography with Kalousek's switch and on the identification of the polarographically active intermediate products. The substance converts to β-4-ethylbenzoylacrylic acid on the electrochemical elimination of the bromine atoms, and the latter acid is reduced further to β-4-ethylbenzoylpropionic acid. The most negative polarographic wave corresponds to the reduction of the carbonyl group in the benzoyl part of the last acid.

Oxidation scheme of symmetrically disulphonated naphthidines with cerium(IV) sulphate

1981 ◽  
Vol 46 (3) ◽  
pp. 561-572 ◽  
Author(s):  
Karel Komers
Keyword(s):  
Sulphuric Acid ◽  
Rate Constants ◽  
Oxidation Product ◽  
Side Reaction ◽  
Reaction Scheme ◽  
Second Order ◽  
Intermediate Products ◽  
Stable Intermediate ◽  
Starting Compound ◽  
Oxidation Agent

The author derived theoretical dependences of preasymptotic slopes of the currentless E-t curves (potential of an indicator redox electrode against time) on the number of equivalents, n, of added oxidation agent, assuming a reaction scheme of two consecutive concurrent second-order reactions involving the formation of intermediate products ( a side reaction of the starting compound with the final oxidation product leading to an adduct, which undergoes consecutive bimolecular oxidations leading again to the final product). The dependences enable to determine the type of the relatively stable intermediate products and the ratios of the rate constants. The theory was applied to the oxidation of four symmetrically disulphonated naphthidines with cerium(IV) sulphate in aqueous sulphuric acid and the results were substantiated spectrophotometrically

UV/H2O2 oxidation of tri(2-chloroethyl) phosphate: Intermediate products, degradation pathway and toxicity evaluation

2020 ◽  
Vol 98 ◽  
pp. 55-61 ◽  
Author(s):  
Qiuyi Ji ◽  
Huan He ◽  
Zhanqi Gao ◽  
Xiaohan Wang ◽  
Shaogui Yang ◽  
...  
Keyword(s):  
Degradation Pathway ◽  
Toxicity Evaluation ◽  
Intermediate Products ◽  
H2o2 Oxidation

scholarly journals Modeling the Supply Process Using the Application of Selected Methods of Operational Analysis

2017 ◽  
Vol 7 (1) ◽  
pp. 50-54 ◽  
Author(s):  
Mária Chovancová ◽  
Vladimír Klapita
Keyword(s):  
Inventory Management ◽  
Economic Efficiency ◽  
Raw Materials ◽  
Service Level ◽  
Effective Management ◽  
Operational Analysis ◽  
Intermediate Products ◽  
The Subject

AbstractSupply process is one of the most important enterprise activities. All raw materials, intermediate products and products, which are moved within enterprise, are the subject of inventory management and by their effective management significant improvement of enterprise position on the market can be achieved. For that reason, the inventory needs to be managed, monitored, evaluated and affected. The paper deals with utilizing the methods of the operational analysis in the field of inventory management in terms of achieving the economic efficiency and ensuring the particular customer’s service level as well.

Synthesize Ti3SiC2 and Ti3SiC2-Diamond Composites at High Pressure and High Temperature

2012 ◽  
Vol 512-515 ◽  
pp. 671-675 ◽  
Author(s):  
Ai Guo Zhou ◽  
Liang Li ◽  
Tai Chao Su ◽  
Shang Sheng Li
Keyword(s):  
High Pressure ◽  
High Temperature ◽  
Intermediate Products ◽  
Diamond Particles ◽  
Ternary Carbide ◽  
The Matrix

Ti3SiC2, a ternary carbide, was proposed at this paper to use as the binder of polycrystalline diamonds to overcome the weaknesses of traditional metal binders and ceramic binders. Ti3SiC2was first reported to be in-situ synthesized under high pressure (4GPa) and at high temperature (1400°C) (HPHT) from the mixtures of Ti, Si and graphite powders or the mixture of Ti, SiC and graphite powders. Ti3SiC2-damond composites were also made at HPHT from the previous mixtures and diamond particles. TiCx, Ti5Si3Cxand TiSi2were main impurities and/or intermediate products of Ti3SiC2samples synthesized at HPHT. Ti3SiC2content increased as synthesized time increased from 10 min to 60 min. For as-synthesized composites, diamond particles were evenly distributed in matrix. The diamond particles are bonded well with the matrix by three types of interface.

Pyrolysis of Hailar Lignite: Experiments with a Tubular Reactor and a Continuous Screw Kiln Reactor

2014 ◽  
Vol 672-674 ◽  
pp. 665-671
Author(s):  
Hao Jie Gao ◽  
Yue Zhao Zhu ◽  
Hai Jun Chen ◽  
Chuan Hua Liao ◽  
Yang Du ◽  
...  
Keyword(s):  
Moisture Content ◽  
Significant Influence ◽  
Tubular Reactor ◽  
Product Yield ◽  
Heating Process ◽  
Intermediate Products ◽  
Temperature Programmed ◽  
Gas Dilution ◽  
Pyrolysis Processes

Pyrolysis of Hailar lignite (moisture content ~ 34.81 wt%) was investigated at temperatures ranging from 700 °C to 900 °C in two different reactors: A tubular reactor (TR) and a continuous screw kiln reactor (CSKR). Under temperature programmed-heating conditions in the TR reactor, the auto-generated steam from the lignite moisture was vaporized and swept out of the reactor by the N2flow during the long heating process, leading to a weakened effect on the subsequent reactions. However, in the CSKR tests all the volatiles was generated continuously while avoid the carrier gas dilution , significant interactions between the in situ steam and the intermediate products occurred. Upon comparing the two pyrolysis processes, it was found the CSKR process exhibits higher H2yield of 23.23 mol/kg, H2proportion of 49.82 vol % than those (16.97 mol/kg, 41.51 vol %) from the TR process. The results demonstrated that inherent moisture in Hailar lignite had a significant influence on the product yield, depending on the pyrolysis conditions. It was also shown that increase in temperature led to rising dry gas yield and H2yield.

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