Kinetics and thermodynamics analysis for ring-opening polymerization of ε-caprolactone initiated by tributyltin n-butoxide using differential scanning calorimetry

2014 ◽  
Vol 119 (1) ◽  
pp. 567-579 ◽  
Author(s):  
Wanich Limwanich ◽  
Puttinan Meepowpan ◽  
Kanarat Nalampang ◽  
Nawee Kungwan ◽  
Robert Molloy ◽  
...  
Keyword(s):  
Differential Scanning Calorimetry ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Scanning Calorimetry ◽  
Kinetics And Thermodynamics ◽  
Thermodynamics Analysis

Synthesis, characterization, and structures of zircona- and boracyclosiloxanes with ferrocenyl substituents

2002 ◽  
Vol 80 (11) ◽  
pp. 1469-1480 ◽  
Author(s):  
Karena Thieme ◽  
Sara C Bourke ◽  
Juan Zheng ◽  
Mark J MacLachlan ◽  
Fojan Zamanian ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Differential Scanning Calorimetry ◽  
Thermogravimetric Analysis ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
The Novel ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Multinuclear Nmr Spectroscopy

The novel zirconatetraferrocenylcyclotrisiloxane Cp2Zr(OSiFc2)2O (6), dizirconatetraferrocenylcyclotetrasiloxane [Cp2Zr(OSiFc2)O]2 (7), boratetraferrocenylcyclotrisiloxane (C6H5)B(OSiFc2)2O (8), and diboratetraferrocenylcyclotetrasiloxane [(C6H5)B(OSiFc2)O]2 (9) with ferrocenyl (Fc = Fe(η-C5H4)(η-C5H5)) substituents at silicon have been prepared from the reactions of Cp2Zr(NMe2)2 and PhBCl2 with diferrocenylsilanediol Fc2Si(OH)2 (3) and tetraferrocenyldisiloxanediol [Fc2SiOH]2O (5). The compounds were characterized by mass spectrometry, elemental analysis, UV–vis, IR, Raman, and multinuclear NMR spectroscopy, as well as single crystal X-ray diffraction. Thermogravimetric analysis and differential scanning calorimetry investigation of 6–9 showed that the cycles decompose before they can undergo any thermal ring-opening polymerization. In addition, no polymerization was detected in the presence of either KOSiMe3 or HOTf. The bulky ferrocenyl substituents on the Si atoms are likely to be at least partially responsible for the inability of these heterocycles to undergo ring-opening polymerization. Key words: heterocyclosiloxanes, ferrocenyl.

scholarly journals 1-n-Butyl-3-methylimidazolium-2-carboxylate: a versatile precatalyst for the ring-opening polymerization of ε-caprolactone and rac-lactide under solvent-free conditions

2013 ◽  
Vol 9 ◽  
pp. 647-654 ◽  
Author(s):  
Astrid Hoppe ◽  
Faten Sadaka ◽  
Claire-Hélène Brachais ◽  
Gilles Boni ◽  
Jean-Pierre Couvercelle ◽  
...  
Keyword(s):  
Differential Scanning Calorimetry ◽  
Ring Opening ◽  
Gel Permeation Chromatography ◽  
Ring Opening Polymerization ◽  
Solvent Free ◽  
Scanning Calorimetry ◽  
H Nmr ◽  
Solvent Free Conditions ◽  
Gel Permeation

The ring-opening polymerization of ε-caprolactone (ε-CL) and rac-lactide (rac-LA) under solvent-free conditions and using 1-n-butyl-3-methylimidazolium-2-carboxylate (BMIM-2-CO2) as precatalyst is described. Linear and star-branched polyesters were synthesized by successive use of benzyl alcohol, ethylene glycol, glycerol and pentaerythritol as initiator alcohols, and the products were fully characterized by 1H and 13C{1H} NMR spectroscopy, gel permeation chromatography (GPC), and differential scanning calorimetry (DSC). BMIM-2-CO2 acts as an N-heterocyclic carbene precursor, resulting from in situ decarboxylation, either by heating under vacuo (method A) or by addition of NaBPh4 (method B). Possible catalytic and deactivation mechanisms are proposed.

scholarly journals Efficiency of liquid tin(ii) n-alkoxide initiators in the ring-opening polymerization of l-lactide: kinetic studies by non-isothermal differential scanning calorimetry

RSC Advances ◽  
2020 ◽  
Vol 10 (71) ◽  
pp. 43566-43578
Author(s):  
Montira Sriyai ◽  
Tawan Chaiwon ◽  
Robert Molloy ◽  
Puttinan Meepowpan ◽  
Winita Punyodom
Keyword(s):  
Differential Scanning Calorimetry ◽  
Ring Opening ◽  
Kinetic Studies ◽  
Ring Opening Polymerization ◽  
Scanning Calorimetry ◽  
Homogeneous Liquid ◽  
Liquid Tin

The efficiency of homogeneous liquid tin(ii) n-alkoxide initiators in the ROP of l-lactide was reported in this work by non-isothermal DSC kinetic approaches.

Kinetics study of Ti[O(CH2)4OCHCH2]4initiated ring-opening polymerization of ε-caprolactone by differential scanning calorimetry

2008 ◽  
Vol 110 (6) ◽  
pp. 3990-3998 ◽  
Author(s):  
Peichun Li ◽  
Amar Zerroukhi ◽  
Jianding Chen ◽  
Yvan Chalamet ◽  
Thomas Jeanmaire ◽  
...  
Keyword(s):  
Differential Scanning Calorimetry ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Kinetics Study ◽  
Scanning Calorimetry

New Waterborne Polyurethane Dispersions from the Soybean-Oil-Based Polyols by Ring Opening of ESO with Glycol

2011 ◽  
Vol 197-198 ◽  
pp. 1196-1200
Author(s):  
Kun Peng Wang ◽  
Li Ting Yang
Keyword(s):  
Differential Scanning Calorimetry ◽  
Soybean Oil ◽  
Thermophysical Properties ◽  
Ring Opening ◽  
Hard Segment ◽  
Waterborne Polyurethane ◽  
Hardness Testing ◽  
Scanning Calorimetry ◽  
Hard Segment Content ◽  
Polyurethane Dispersions

A series of polyols (GSOLs) with a range of hydroxyl numbers based on epoxidized soybean oil (ESO) were prepared by ring opening with glycol. These Polyols of hydroxyl (OH) numbers ranging from 111 to 162 mg KOH/g were obtained. The environmentally friendly soybean-oil-based waterborne polyurethane dispersions (SPU) with very promising properties have been successfully synthesized from a series of soybean-oil-based polyols (GSOLs) with different hydroxyl numbers by a polyaddition reaction with toluene 2,4-diisocyanate (2,4-TDI). The structure and thermophysical properties of the resulting SPU films have been studied by Fourier transform infrared spectroscopy, differential scanning calorimetry, thermogravimetric analysis, and hardness testing. The experimental results showed that the functionality of the GSOLs and the hard segment content play a key role in controlling the structure and the thermophysical properties of the SPU films.

Preparation and Characterization of Multiwalled Carbon Nanotubes-Reinforced pCBT by Ring-Opening Polymerization of Cyclic Butylene Terephthalate

2016 ◽  
Vol 848 ◽  
pp. 125-131
Author(s):  
Yin He Su ◽  
Jun Rong Yu
Keyword(s):  
Carbon Nanotubes ◽  
Multiwalled Carbon Nanotubes ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Scanning Calorimetry ◽  
Multiwalled Carbon ◽  
Butylene Terephthalate ◽  
Cyclic Butylene Terephthalate ◽  
The Matrix ◽  
Higher Temperature

Multiwalled carbon nanotubes (MWCNT)-reinforced polymerized cyclic butylene terephthalate (pCBT) nanocomposites were prepared by in situ ring opening polymerization of cyclic butylene terephthalate oligomers (CBT). The results of differential scanning calorimetry (DSC) indicated that the melting peak located at the low temperature (Tm1) increased and that at higher temperature (Tm2) decreased with the increasing of content of the MWCNT. During the cooling the MWCNT served as nucleation points from where crystallization can start. The more the MWCNT in the system the earlier the crystallization starts. The Morphological investigations performed by scanning electron microscopy (SEM) shown that the MWCNT were embedded in the matrix and held tightly by the matrix. The modulus and strength increased with MWCNT concentration in the nanocomposites, however, the elongation at break, absorbed energy at break and impact strength were decreased with the increasing of MWCNT content.

Kinetics and Thermodynamics of the Formation of Thin Film Titanium Diselicide

1995 ◽  
Vol 398 ◽  
Author(s):  
R.J. Kasica ◽  
E.J. Cotts ◽  
R.G. Ahrens
Keyword(s):  
Thin Film ◽  
Differential Scanning Calorimetry ◽  
Solid State ◽  
Isothermal Calorimetry ◽  
Sputter Deposition ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
Average Composition ◽  
Kinetics And Thermodynamics ◽  
X Ray

ABSTRACTMultilayered difiiision couples consisting of alternating layers of titanium (Ti) and amorphous silicon (a-Si) have been fabricated using sputter deposition with a range of modulation lengths corresponding to an average composition of Ti33 Si67. We have used differential scanning calorimetry to measure the enthalpy evolved during the solid state reaction a-Si + Ti → C49-TiSi2 and have characterized the phases formed using x-ray diffraction analysis. An average measured enthalpy of formation, ΔΗ was found to be ΔΗ = -58 + 9 kJ/g atom for thin film samples. Using scanning and isothermal calorimetry measurements, we have also characterized the kinetics involved during the initial intermixing stage.

SYNTHESIS OF POLY[(ε-CL)-co-(GA-alt-L-Asp)] COPOLYMER AND EFFECTS ON CELLS AFTER COUPLING WITH SMALL PEPTIDE

2015 ◽  
Vol 27 (06) ◽  
pp. 1550053
Author(s):  
Na Qiang ◽  
Fang Xie ◽  
Hao Liang ◽  
Xian-Feng Li ◽  
Shuo Tang ◽  
...  
Keyword(s):  
Ring Opening ◽  
Gel Permeation Chromatography ◽  
Ring Opening Polymerization ◽  
Carboxyl Groups ◽  
Structure And Properties ◽  
Small Peptide ◽  
Scanning Calorimetry ◽  
Beneficial Effects ◽  
Structural Regularity ◽  
Gel Permeation

A novel poly[([Formula: see text]-CL)-co-(GA-alt-L-Asp)] with improved hydrophilicity was prepared. The monomer 3(S)-[(benzyloxycarbony)methyl]-1,4-dioxane-2,5-dione (BMD) was prepared from aspartic acid. The polymer was obtained by ring-opening polymerization of [Formula: see text]-caprolactone ([Formula: see text]-CL) and BMD. Poly[([Formula: see text]-CL)-co-(GA-alt-L-Asp)] was synthesized by deprotection. The structure and properties of the polymer were characterized using 1H nuclear magnetic resonance, gel permeation chromatography, and differential scanning calorimetry. The melting point and melting enthalpy of the polymer decreased with the increase of BMD. The structural regularity of polycaprolactone was destroyed by the BMD. A laminin-derived peptide [i.e., Arg-Gly-Asp (RGD)] was covalently tethered to the carboxyl groups and the peptide-grafted films. Results indicated that the addition of RGD had beneficial effects for cell growth, as shown by scanning electron microscopy.

Synthesis of Ferroelectric Liquid Crystalline Polymers by Ring Opening Polymerization

1996 ◽  
Vol 425 ◽  
Author(s):  
C. S. Hsu ◽  
C. J. Lee
Keyword(s):  
Ring Opening ◽  
Liquid Crystalline ◽  
Liquid Crystalline Polymers ◽  
Ring Opening Polymerization ◽  
Side Chain ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Crystalline Polymers ◽  
Smectic A ◽  
Smectic C

AbstractThe synthesis of two series of side-chain liquid crystalline polyoxetanes and polyoxiranes containing 4-alkanyloxybiphenyl-4′ -yl (2S,3S)-2-chloro-3-methylvalerate side groups is presented. Differential scanning calorimetry, polarizing optical microscopy, and X-ray diffractometry reveal smectic mesomorphism for all obtained polymers. Most of the prepared polyoxetanes present smectic A and chiral smectic C phases. The polyoxetane containing tweleve methylene units in the spacer is the only one showing two enantiotropic smectic A and B phases. All of the obtained polyoxiranes display two enantiotropic smectic A and B phases. Although the polyoxetane and polyoxirane backbones are more flexible than the polymethacrylate backbone, side-chain crystallization do not occur in any of the synthesized polymers.

Preparation and Characterization of Dioxanone and Poly(dioxanone)

2013 ◽  
Vol 711 ◽  
pp. 22-25
Author(s):  
Kui Lin Deng ◽  
Wen Hui Jin ◽  
Fu Chen Zhang ◽  
Chun Xiu Li ◽  
Hui Juan Shen ◽  
...  
Keyword(s):  
Ring Opening ◽  
Raw Materials ◽  
Copper Chromite ◽  
Copper Nitrate ◽  
Ring Opening Polymerization ◽  
Scanning Calorimetry ◽  
H Nmr ◽  
Dsc Measurements ◽  
Ammonium Dichromate

In this paper, the ammonium dichromate and copper nitrate were used as raw materials to prepare the copper chromite, and nanocopper chromite as a catalyst was used to synthesize the monomer dioxanone in diethylene glycol dehydrogenation. Under the strict conditions of no water and no oxygen, the stannous octoate was selected to catalyze ring-opening polymerization of the dioxanone to prepare the polydioxanone. And dioxanone and its polymers were characterized with IR spectroscopy,1H NMR spectroscopy, thermogravimetric analysis (TG) and differential scanning calorimetry (DSC ) measurements.

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