scholarly journals Synthesis of epoxy resins derivatives of naphthalene-2,7-diol and their cross-linked products

2019 ◽  
Vol 138 (6) ◽  
pp. 4349-4358 ◽  
Author(s):  
K. Fila ◽  
M. Gargol ◽  
M. Goliszek ◽  
B. Podkościelna
Keyword(s):  
Fourier Transform ◽  
Epoxy Resins ◽  
Attenuated Total Reflectance ◽  
Cross Linking ◽  
Total Reflectance ◽  
Before And After ◽  
Ft Ir ◽  
The Cross ◽  
Derivatives Of ◽  
Epoxy Groups

Abstract The aim of this study was the synthesis of three different epoxy compounds based on naphthalene-2,7-diol (2,7-NAF.EP, 2,7-NAF.WEP, 2,7-NAF.P.EP) and then their cross-linking by triethylenetetramine (TETA). All epoxides were prepared by the reaction of naphthalene-2,7-diol with epichlorohydrin but under different conditions and with other catalysts. The structures of the obtained compounds before and after the cross-linking reactions were confirmed by the attenuated total reflectance Fourier transform infrared spectroscopy (ATR/FT-IR). The ATR/FT-IR spectra of cross-linked compounds show disappearance of the C–O–C bands (about 915 cm−1) derived from the epoxy groups. DSC and TG/DTG measurements indicated that the obtained materials possess good thermal resistance; they are stable up to about 250 °C. The hardness of the cross-linked products was determined using the Shore D method. The highest value of hardness was obtained for the 2,7-NAF.EP-POL. Additionally, the UV–Vis absorption spectra of the obtained polymers were registered and evaluated.

Observations of surface-mediated reduction of Pu(VI) to Pu(IV) on hematite nanoparticles by ATR FT-IR

2015 ◽  
Vol 103 (8) ◽  
Author(s):  
Hilary P. Emerson ◽  
Brian A. Powell
Keyword(s):  
Fourier Transform ◽  
Infrared Spectroscopy ◽  
Attenuated Total Reflectance ◽  
Mineral Surfaces ◽  
Hematite Nanoparticles ◽  
Total Reflectance ◽  
Ft Ir ◽  
First Time ◽  
Mediated Reduction

AbstractPrevious studies have shown that mineral surfaces may facilitate the reduction of plutonium though the mechanisms of the reduction are still unknown. The objective of this study is to use batch sorption and attenuated total reflectance Fourier transform infrared spectroscopy experiments to observe the surface-mediated reduction of plutonium on hematite nanoparticles. These techniques allow for in situ measurement of reduction of plutonium with time and may lead to a better understanding of the mechanisms of surface mediated reduction of plutonium. For the first time, ATR FT-IR peaks for Pu(VI) sorbed to hematite are measured at ∼ 916 cm

Role of Phenolic Tackifiers in Polyisoprene Rubber

1991 ◽  
Vol 64 (1) ◽  
pp. 65-73 ◽  
Author(s):  
F. L. Magnus ◽  
G. R. Hamed
Keyword(s):  
Phenolic Resin ◽  
Bond Formation ◽  
Surface Region ◽  
Attenuated Total Reflectance ◽  
Total Reflectance ◽  
Trans Isomerization ◽  
Before And After ◽  
Ft Ir

Abstract The effect of p-tert-octyl phenolic (PTOP) resin on the tack of an IR/N660 compound has been studied before and after aging. The phenolic resin has little effect on unaged tack. Upon aging at 23°C and 45% RH, autohesion of the IR/N660 significantly decreases. However, when the PTOP resin is added, tack is maintained during aging. FT-IR attenuated total reflectance analyses indicate that, upon aging, oxidation leads to cis → trans isomerization. The PTOP resin becomes enriched in the surface region and protects the IR from further oxidation and the accompanying cis → trans isomerization. Additionally, solubilized resin may behave as a plasticizer to enhance tack bond formation. A compound with phenolic monomer (PTOP resin precursor) forms a rapid bloom with aging and experiences rapid tack loss.

Fourier Transform Infrared Spectrometry/Attenuated Total Reflectance Study of the Reaction of Pentanal and Propanal with 2-(Hydroxymethyl)Piperidine

1992 ◽  
Vol 46 (2) ◽  
pp. 266-272 ◽  
Author(s):  
Eugene R. Kennedy ◽  
Kevin Ashley
Keyword(s):  
Fourier Transform ◽  
Fourier Transform Infrared ◽  
Solution Phase ◽  
Attenuated Total Reflectance ◽  
Infrared Spectrometry ◽  
Fourier Transform Infrared Spectrometry ◽  
Total Reflectance ◽  
Solid Interface ◽  
Ft Ir ◽  
Flow Through

The reactions of propanal and pentanal with 2-(hydroxymethyl)piperidine were investigated by Fourier transform infrared spectrometry/attenuated total reflectance in both the solution phase and at the gas/solid interface. The reactions were studied with the use of a flow-through cylindrical internal reflection (“circle”) cell. Reaction intermediates were tentatively identified by their characteristic infrared absorption frequencies. At the gas/solid interface the reaction is thought to yield a hemiaminal intermediate. In the solution phase a hemiaminal intermediate is believed to form initially, followed by loss of water to generate an enamine product. In both gas-phase and solution-phase studies, an oxazolidine product is prepared only after an ultrasound treatment. The FT-IR/ATR technique reveals detailed mechanistic information concerning reactions between aldehydes and ethanol amines.

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