Investigation of the Influence of Slag Basicity on Metal Droplet Dephosphorization

Author(s):  
Jayasree Biswas ◽  
Phillip B. Drain ◽  
Kezhuan Gu ◽  
Raymond J. Longbottom ◽  
Michael W. Chapman ◽  
...  
Keyword(s):  
Author(s):  
Manpreet Dash ◽  
Sangharsh Kumar ◽  
Partha Pratim Bandyopadhyay ◽  
Anandaroop Bhattacharya

The impact process of a molten metal droplet impinging on a solid substrate surface is encountered in several technological applications such as ink-jet printing, spray cooling, coating processes, spray deposition of metal alloys, thermal spray coatings, manufacturing processes and fabrication and in industrial applications concerning thermal spray processes. Deposition of a molten material or metal in form of a droplet on a substrate surface by propelling it towards it forms the core of the spraying process. During the impact process, the molten metal droplet spreads radially and simultaneously starts losing heat due to heat transfer to the substrate surface. The associated heat transfer influences impingement behavior. The physics of droplet impingement is not only related to the fluid dynamics, but also to the respective interfacial properties of solid and liquid. For most applications, maximum spreading diameter of the splat is considered to be an important factor for droplet impingement on solid surfaces. In the present study, we have developed a model for droplet impingement based on energy conservation principle to predict the maximum spreading radius and the radius as a function of time. Further, we have used the radius as a function of time in the heat transfer equations and to study the evolution of splat-temperature and predict the spreading factor and the spreading time and mathematically correlate them to the spraying parameters and material properties.


2021 ◽  
Vol 158 ◽  
pp. 108301
Author(s):  
Linyi Yang ◽  
Chenglong Wang ◽  
Hao Qin ◽  
Dalin Zhang ◽  
Wenxi Tian ◽  
...  

2017 ◽  
Vol 114 (6) ◽  
pp. 602 ◽  
Author(s):  
Changbo Guo ◽  
Haitao Ling ◽  
Lifeng Zhang ◽  
Wen Yang ◽  
Ying Ren ◽  
...  

1996 ◽  
Vol 118 (1) ◽  
pp. 164-172 ◽  
Author(s):  
C. H. Amon ◽  
K. S. Schmaltz ◽  
R. Merz ◽  
F. B. Prinz

A molten metal droplet landing and bonding to a solid substrate is investigated with combined analytical, numerical, and experimental techniques. This research supports a novel, thermal spray shape deposition process, referred to as microcasting, capable of rapidly manufacturing near netshape, steel objects. Metallurgical bonding between the impacting droplet and the previous deposition layer improves the strength and material property continuity between the layers, producing high-quality metal objects. A thorough understanding of the interface heat transfer process is needed to optimize the microcast object properties by minimizing the impacting droplet temperature necessary for superficial substrate remelting, while controlling substrate and deposit material cooling rates, remelt depths, and residual thermal stresses. A mixed Lagrangian–Eulerian numerical model is developed to calculate substrate remelting and temperature histories for investigating the required deposition temperatures and the effect of operating conditions on remelting. Experimental and analytical approaches are used to determine initial conditions for the numerical simulations, to verify the numerical accuracy, and to identify the resultant microstructures. Numerical results indicate that droplet to substrate conduction is the dominant heat transfer mode during remelting and solidification. Furthermore, a highly time-dependent heat transfer coefficient at the droplet/substrate interface necessitates a combined numerical model of the droplet and substrate for accurate predictions of the substrate remelting. The remelting depth and cooling rate numerical results are also verified by optical metallography, and compare well with both the analytical solution for the initial deposition period and the temperature measurements during droplet solidification.


2021 ◽  
Vol 410 ◽  
pp. 287-292
Author(s):  
Anatolij A. Babenko ◽  
Leonid A. Smirnov ◽  
Alena G. Upolovnikova

The equilibrium interfacial distribution of sulfur and boron was estimated using the HSC 6.1 Chemistry software package (Outokumpu) and the simplex-lattice planning method. Adequate mathematical models have been constructed in the form of III degree polynomial, which describe the effect of the composition of the studied oxide system on the equilibrium distribution of sulfur and boron between the slag and the metal. Generalization of the results of experimental studies and thermodynamic modeling made it possible to obtain new data on the influence of the basicity and content of B2O3 in the slag of the CaO-SiO2-B2O3-MgO-Al2O3 system on the interphase distribution of sulfur and boron. It was found that in the range of boron oxide concentration of 1.0-10%, an increase in slag basicity from 2 to 5 at 1600°C leads to an increase in the sulfur distribution coefficient from 1 to 20 and, as a consequence, a decrease in the sulfur content in the metal from 0.02 to 0.0014 %, i.e. an increase in slag basicity favorably affects the development of the metal desulfurization process. An increase in the B2O3 content from 2.0 to 10.0% in slags formed in the region of moderate basicity, not exceeding 2-3, is accompanied at 1600°C by a decrease in the boron interphase distribution coefficient from 450 to 150 and an increase in the boron concentration in the metal from 0.006 to 0.021 %, which indicates the progress of boron reduction from slag to metal. The shift of the formed slags to the area of ​​increased basicity up to 5.0 shows a high degree of boron reduction from slag to metal. The results of the laboratory experiment confirmed the results of thermodynamic modeling.


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