Abstract
Many workers have studied the changes in resistivity that occur on deforming rubbers loaded with carbon black. This paper describes three types of experimental investigation that do not seem to have received detailed study previously, and also a theory that explains the results qualitatively in terms of variations of contact resistances between carbon black particles. Firstly, the changes of resistance of vulcanized natural rubber, Butyl rubber, Neoprene, and Thiokol FA loaded with carbon black have been studied during cyclic deformations. Secondly, the initial increase of resistance during stretching testpieces of vulcanized natural rubber containing several loadings of different carbon blacks has been investigated. Finally, the changes of resistance with time that occur after stretching and releasing samples of electrically conducting rubber have been studied. The ingredients and preparation of the compounds used in experiments discussed in this paper are listed in the Appendix. The testpieces used in the following experiments were approximately 0.7 cm. wide, 0.1 cm. thick, and 7.0 cm. long. Electrical contact was established by means of brass strips bonded by molding into the ends of the samples, so that the direction of current flow was along the length of the pieces, and in the same direction as the extensions.
Simple Electrochemical Sensor Based on Carbon-black Paste Electrode Coupled with Derivative Square Wave Voltammetry for the Determination of Sulfites in Rice Wine
