scholarly journals Investigation of edge formation during the coating process of Li-ion battery electrodes

Author(s):  
Sandro Spiegel ◽  
Thilo Heckmann ◽  
Andreas Altvater ◽  
Ralf Diehm ◽  
Philip Scharfer ◽  
...  

AbstractIn this manuscript, a method to reduce superelevations of lateral edges in cross-web direction during slot die coating of shear-thinning slurries for Li-ion battery electrodes (LIB) was developed. Therefore, the impact of the inner slot die geometry on the edge elevations was investigated. These elevations of the coating could be almost eliminated by optimizing the flow profile at the outlet of the slot die by modification of the internal geometry. This adaption is an essential step in optimizing the coating quality of slot die coating for battery electrodes to significantly reduce coating edges and, hence, the resulting production reject during the coating step of the industrial roll-to-roll process. It was also shown that lateral edges of the coating can be influenced explicitly by process parameters such as volume flow and gap between slot die and substrate. This correlation has already been shown for other shear-thinning material systems in previous works, which is now confirmed for this material system. At the beginning, the influence of different internal geometries on the formation of the edge elevations was shown. Finally, for the shear-thinning electrode slurry used in this work, optimal dimensions of the previously determined inner geometry for the slot die outlet were found. The optimization was performed for a state-of-the-art electrode area capacity (approximately 2.2 mAh cm−2). The results enable a significant reduction of defects and reject in the coating step of large-scale production of LIB electrodes in the future, adding to a more sustainable battery production.

RSC Advances ◽  
2015 ◽  
Vol 5 (47) ◽  
pp. 37830-37836 ◽  
Author(s):  
Wei Wei ◽  
Linlin Guo ◽  
Xiaoyang Qiu ◽  
Peng Qu ◽  
Maotian Xu ◽  
...  

Although many routes have been developed that can efficiently improve the electrochemical performance of LiFePO4 cathodes, few of them meet the urgent industrial requirements of large-scale production, low cost and excellent performance.


2020 ◽  
Vol 8 (9) ◽  
pp. 2000259
Author(s):  
Ralf Diehm ◽  
Marcus Müller ◽  
David Burger ◽  
Jana Kumberg ◽  
Sandro Spiegel ◽  
...  

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 757
Author(s):  
Ohchan Kwon ◽  
Yunkyu Choi ◽  
Eunji Choi ◽  
Minsu Kim ◽  
Yun Chul Woo ◽  
...  

Graphene oxide (GO) has been a prized material for fabricating separation membranes due to its immense potential and unique chemistry. Despite the academic focus on GO, the adoption of GO membranes in industry remains elusive. One of the challenges at hand for commercializing GO membranes lies with large-scale production techniques. Fortunately, emerging studies have acknowledged this issue, where many have aimed to deliver insights into scalable approaches showing potential to be employed in the commercial domain. The current review highlights eight physical methods for GO membrane fabrication. Based on batch-unit or continuous fabrication, we have further classified the techniques into five small-scale (vacuum filtration, pressure-assisted filtration, spin coating, dip coating, drop-casting) and three large-scale (spray coating, bar/doctor blade coating, slot die coating) approaches. The continuous nature of the large-scale approach implies that the GO membranes prepared by this method are less restricted by the equipment’s dimensions but rather the availability of the material, whereas membranes yielded by small-scale methods are predominately limited by the size of the fabrication device. The current review aims to serve as an initial reference to provide a technical overview of preparing GO membranes. We further aim to shift the focus of the audience towards scalable processes and their prospect, which will facilitate the commercialization of GO membranes.


Author(s):  
Daniele Landi ◽  
Paolo Cicconi ◽  
Michele Germani

An important issue in the mechanical industry is the reduction of the time to market, in order to meet quickly the customer needs. This goal is very important for SMEs that produce small lots of customized products. In the context of greenhouse gas emissions reduction, vehicles powered by electric motors seem to be the most suitable alternative to the traditional internal combustion engine vehicles. The market of customized electric vehicles is a niche market suitable for SMEs. Nowadays, the energy storage system of an electric vehicle powertrain consists of several Li-ion cells arranged in a container called battery pack. Particularly, the battery unit is considered as the most critical component in electric vehicle, because it impacts on performance and life cycle cost. Currently, the design of a battery pack mostly depends on the related market size. A longer design time is expected in the case of a large scale production. While a small customized production requires more agility and velocity in the design process. The proposed research focuses on a design methodology to support the designer in the evaluation of the battery thermal behavior. This work has been applied in the context of a customized small production. As test case, an urban electric light commercial vehicle has been analyzed. The designed battery layout has been evaluated and simulated using virtual prototyping tools. A cooling configuration has been analyzed and then prototyped in a physical vehicle. The virtual thermal behavior of a Li-ion battery has been validated at the test bench. The real operational conditions have been analyzed reproducing several ECE-15 driving cycles and many acceleration runs at different load values. Thermocouples have measured the temperature values during the physical experiments, in order to validate the analytical thermal profile evaluated with the proposed design approach.


2014 ◽  
Vol 6 (20) ◽  
pp. 17376-17383 ◽  
Author(s):  
Hua-Rong Xia ◽  
Jia Li ◽  
Chen Peng ◽  
Wen-Tao Sun ◽  
Long-Wei Li ◽  
...  

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