Exploring high-strength glass-ceramic materials for upcycling of industrial wastes

2015 ◽  
Vol 21 (6) ◽  
pp. 1061-1067 ◽  
Author(s):  
Gu-Seul Back ◽  
Hyun Seo Park ◽  
Sung Mo Seo ◽  
Woo-Gwang Jung
2003 ◽  
Vol 68 (6) ◽  
pp. 505-510 ◽  
Author(s):  
Branko Matovic ◽  
Snezana Boskovic ◽  
Mihovil Logar

Local and conventional raw materials?massive basalt from the Vrelo locality on Kopaonik mountain?have been used as starting materials to test their suitability for the production of glass-ceramics. Crystallization phenomena of glasses of the fused basalt rocks were studied by X-ray phase analysis optical microscopy and other techniques. Various heat treatments were used and their influences, on controlling the microstructures and properties of the products were studied with the aim of developing high strength glass-ceramic materials. Diopside CaMg(SiO3)2 and hypersthene ((Mg,Fe)SiO3) were identifies as the crystalline phases. The final products contained considerable amounts of a glassy phase. The crystalline size was in range of 8?480 ?m with plate or needle shape. Microhardness, crashing strength and wears resistence of the glass-ceramics ranged from 6.5?7.5, from 2000?6300 kg/cm2 and from 0.1?0.2 g/cm, respectively.


2020 ◽  
Vol 14 (4) ◽  
pp. 583-589
Author(s):  
Оksana Savvova ◽  
◽  
Hennadiy Voronov ◽  
Оlena Babich ◽  
Oleksii Fesenko ◽  
...  

Relevance of the development of high-strength glass-ceramic coatings obtained by resource-saving technology for protective elements has been established. Structure formation mechanism in magnesium aluminosilicate glasses during heat treatment has been analyzed. Selection of the system was substantiated, model glasses and glass-ceramic materials on its base have been developed. Patterns of structure regularity and formation of the phase composition of glass-ceramic materials during their ceramization have been investigated. It was established that the presence of crystalline phase of mullite after melting leads to formation of the primary crystals and allows the formation of the fine crystalline structure under conditions of the low-temperature heat treatment at the nucleation stage. Developed high-strength glass ceramic materials can be used as a base in creating protective elements for special-purpose vehicles by energy-saving technology.


2015 ◽  
Vol 51 (3) ◽  
pp. 202-205 ◽  
Author(s):  
I. G. Atabaev ◽  
Sh. A. Faiziev ◽  
M. Paizullakhanov ◽  
Zh. Z. Shermatov ◽  
O. Razhamatov

2018 ◽  
Vol 118 ◽  
pp. 111-118
Author(s):  
О. V. Savvova ◽  
O. I. Fesenko ◽  
V. D. Timofeеv ◽  
Ya. V. Poviderna

Based on the analysis of existing mullite-cordierite sitalls, the need to create high-strength materials of this type for individual and local protection against high-speed loads has been determined. They should be characterized by lower cost, due to low-temperature short-term heat treatment using domestic raw materials. An important aspect of ensuring the effective protective effect of an armor-element, in addition to its armor resistance and survivability, is the ability to withstand the effects of open flame and combustible mixtures, which is determined by the thermal properties of the sitalls. The aim of this work is to study the thermal properties, namely thermal expansion coefficient and fire resistance, high strength mullite-cordierite glass-ceramics that they are developed by us earlier. The temperature coefficient of linear expansion was determined using a quartz vertical dilatometer QVD-5A (ASTM C 372-94 (2007)), fire resistance according to GOST 33000—2014. According to X-ray diffraction and differential thermal analyzes, the experimental samples were divided into two groups according to the formation mechanism of structure and phase composition of glass materials during heat treatment. For each of the materials groups, the influence of the chemical and phase compositions on the thermal coefficient of linear expansion of the original mullite-cordierite glass materials and glass-ceramic materials (sitalls) thermally treated using two-stage heat treatment was determined. The study of the fire resistance of the developed glass-ceramic materials made it possible to establish that they withstand the thermal load in a certain mode for 360 minutes. It has been established that providing high thermal- and fire resistance (RE 360 (h)) is a determining factor in the production of hardened glass crystalline materials that are able to resist to thermal destroying at sharp temperature change.


2016 ◽  
Vol 8 (12) ◽  
pp. 2295-2298
Author(s):  
Dongyoon Shin ◽  
Duk-Hee Lee ◽  
Mijung Yoon ◽  
Hyun Seo Park ◽  
Sung Mo Seo ◽  
...  

2017 ◽  
Vol 49 (3) ◽  
pp. 479-486 ◽  
Author(s):  
O. V. Savvova ◽  
O. V. Babich ◽  
G. K. Voronov ◽  
S. O. Ryabinin

1994 ◽  
Vol 10 (1-2) ◽  
pp. 171-176 ◽  
Author(s):  
M. Pelino ◽  
C. Cantalini ◽  
P.P. Boattini ◽  
C. Abbruzzese ◽  
J.Ma. Rincon ◽  
...  

1994 ◽  
Vol 29 (8) ◽  
pp. 2087-2094 ◽  
Author(s):  
M. Pelino ◽  
C. Cantalini ◽  
F. Veglio' ◽  
P. P. Plescia

Author(s):  
O.V. Savvova ◽  
S.A. Ryabinin ◽  
E.A. Svitlichniy ◽  
G.K. Voronov ◽  
A.I. Fesenko

Advanced methods for obtaining high-strength glass-ceramic materials based on lithium aluminum silicate glass for glass and ceramic technologies are identified. Were analyzed  forming methods: pressing, thermoplastic molding and slip casting with the definition the advantages and disadvantages of in each of them. The choice of the base LAS system is substantiated and model lithium-aluminum-silicate glasses and glass-ceramic materials based on β-spodumene are synthesized by the methods of pressing, slip casting and thermoplastic molding. The features of the formation of glass-ceramic materials using various technologies are investigated. Technological parameters were established for pressing: molding powder with a fraction size from 63 to 125 μm − 70 vol. %, from 25 to 63 microns − 15 vol. %, less 25 microns − 15 vol. %, xanthan gum solution in an amount of 10 wt. %; for slip casting: slip specific weight − γ = 1852 kg/m3, pH = 9.90; for the thermoplastic formation: paraffin − 15 wt. %, beeswax − 5 wt. %, oleic acid − 1 wt. %. It has been established that the determining influence on the mechanical properties of the developed glass-ceramic materials has the character of their micro- and macrostructures. It has been established that, for the studied glass-ceramic materials, an increase in porosity and pore size significantly affects the magnitude of their compressive strength. Glass-ceramic materials obtained by wet pressing and slip technology can be recommended as the most technologically advanced in creating composite armor elements and promising in the development of high-strength glass-ceramic materials for the local protection of special equipment and technology. Composite structural materials obtained by thermoplastic processing can be used to create high-strength parts for precision mechanisms and instruments, which are subject to stringent requirements for mechanical strength.


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