A novel process, of melt infiltration combined with diffusion annealing technique, was
developed to prepare Ti-Al intermetallics at temperature lower than ingot melting point. In this
process, a porous Ti preform was firstly fabricated and the Al melt was reheated to temperature
slightly higher than Al melting point to infiltrate the porous Ti preform by capillary force
spontaneously. After long-time high-temperature diffusion annealing, Ti-Al intermetallic compound
can be finally synthesized from the bulk Tip+melt Al via diffusion. As example, Ti-46Al
intermetallics has been fabricated, and the microstructures and the phases of the as-synthesized
intermetallics were characterized by XRD and SEM. The compressive behavior of the as-synthesized
Ti-Al at elevated temperatures has been studied and the reaction mechanism involved in the process
finally analyzed.