Effect of octadecylamine modified graphene on thermal stability, mechanical properties and gas barrier properties of brominated butyl rubber

2017 ◽  
Vol 25 (3) ◽  
pp. 270-275 ◽  
Author(s):  
Xinya Yang ◽  
Yong Zhang ◽  
Yan Xu ◽  
Steven Gao ◽  
Sharon Guo
Polymer ◽  
2006 ◽  
Vol 47 (9) ◽  
pp. 3083-3093 ◽  
Author(s):  
S. Takahashi ◽  
H.A. Goldberg ◽  
C.A. Feeney ◽  
D.P. Karim ◽  
M. Farrell ◽  
...  

2021 ◽  
Author(s):  
Alain Guinault ◽  
Tiphaine Messin ◽  
Gilbert Anderer ◽  
Stefan Krawielitzki ◽  
Cyrille Sollogoub ◽  
...  

Food packaging films must be reinvented in order to answer the new demanding ecological requirements. Biobased and/or biodegradable polymers appear as an interesting alternative to reduce petroleum dependence and carbon dioxide emissions. Poly(ethylene furanoate) (PEF) appears today as a new promising biopolymer thanks to its good gas barrier and mechanical properties, despite its high price that could limit its industrial applications. Its combination with other polymers is thus of great interest and for the first time, film coextrusion process is used to create PLA-PEF and PET-PEF multi-micro/nano layered films. A new PEF grade developed by AVA Biochem in the H2020 Mypack program, has been used and firstly analysed in terms of melt processability, mechanical, thermal and gas barrier properties. Our major results confirmed the good gas barrier as well as mechanical properties of amorphous PEF. Post-extrusion PEF bulk thermal crystallization led to very brittle material making gas barrier measurements impossible. Micro/nanolayered PLA-PEF and PET-PEF films with different PEF layer thicknesses have been processed and post-extrusion annealing treatment was carried out. The relationship between crystallinity, mechanical and gas barrier properties will be investigated.


RSC Advances ◽  
2016 ◽  
Vol 6 (1) ◽  
pp. 716-729 ◽  
Author(s):  
Quantao Li ◽  
Wenqiu Chen ◽  
Wei Yan ◽  
Quanyuan Zhang ◽  
Changfeng Yi ◽  
...  

Two kinds of (GE-MDI/HBPEI) nanocomposites with highly enhanced thermal, mechanical and gas barrier properties, were prepared via in situ solution polymerization, as well as subsequent synchronous thermal imidization and reduction.


2008 ◽  
Vol 68 (3-4) ◽  
pp. 933-943 ◽  
Author(s):  
A. Vassiliou ◽  
D. Bikiaris ◽  
K. Chrissafis ◽  
K.M. Paraskevopoulos ◽  
S.Y. Stavrev ◽  
...  

2014 ◽  
Vol 87 (4) ◽  
pp. 579-592 ◽  
Author(s):  
Arun Kumar ◽  
Satyam Modi ◽  
Artee Panwar ◽  
Daniel Schmidt ◽  
Carol M. F. Barry ◽  
...  

ABSTRACT Incorporation of nanoclays in vulcanized rubber can enhance the barrier and mechanical properties, with the aid of intercalation, exfoliation, or both. Achieving a high degree of dispersion such as intercalation and exfoliation is critical for obtaining optimal properties. In this work, a stepwise approach was developed to disperse the natural montmorillonite (MMT) clay modified with a quaternary ammonium salt in brominated butyl rubber (BIIR). The solvent intercalation method followed by mechanical shear was used to effectively intercalate/exfoliate the MMT bundles. Special consideration was given to effectively remove the solvent from the solvent intercalated master batch. The nanocomposites fabricated using this technique showed a high degree of intercalation and exfoliation along with improved barrier, dynamic mechanical, and mechanical properties. This improvement in properties offers an opportunity for this material to be used in high-end applications requiring improved mechanical as well as barrier properties; an example is a thinner tire inner liner with reduced hysteresis, lower running temperatures, and reduced fuel consumption.


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