Deposition of Dopamine and Polyethyleneimine on Polymeric Membranes: Improvement of Performance of Ultrafiltration Process

2020 ◽  
Vol 28 (12) ◽  
pp. 1091-1097
Author(s):  
Ingrid R. Marques ◽  
Guilherme Zin ◽  
Lidia T. Prando ◽  
Cristiana C. Bretanha ◽  
Mariane C. Proner ◽  
...  
2017 ◽  
Vol 54 (4) ◽  
pp. 726-730
Author(s):  
George Alexandru Popa ◽  
Daniela Florentina Enache (Popa) ◽  
Szidonia Katalin Tanczos ◽  
Adrian Ciocanea

The objective of the study is the low-pressure membrane process for treating aqueous solutions containing synthetic food dye (E104 - quinoline yellow). Dye concentration used was 10% (equivalent to 100g/m3). The pressures used in the ultrafiltration process were 0.1, 0.2 and 0.3 MPa. Experiments were performed in dead - end instalations in which the effectiveness of the polysulfone - alkylbenzyldimethylammonium chloride (PSU-ABDMA) and polysulfone - N-dodecylpyridinium chloride (PSU - NDPCl) were tested. The efficiency of these membranes has been proved by calculating the permeate flow and the retention. Analyzing the experimental data, it was found that for the polysulfone-alkylbenzyldimethylammonium chloride composite membrane the degree of retention is completely different, with high values being obtained for low pressures and low values for high pressures used.


2018 ◽  
Vol 55 (4) ◽  
pp. 680-685
Author(s):  
Laureniu Tataru ◽  
Valentin Nedeff ◽  
Narcis Barsan ◽  
Emilian Mosnegutu ◽  
Mirela Panainte Lehadus ◽  
...  

This paper proposes to investigate in detail the behavior of polymeric membranes ultrafiltration process uses in the retention of humic acid from aqueous systems. Nowadays, the aqueous systems (contaminated water and/or wastewater) resulting from various domestic and industrial activities contain many contaminants, some of them increasingly dangerous to the environment. Laboratory testing of membranes in the ultrafiltration process as well as their experimentation with different chemical compounds is essential because it is important to know how they can be eliminated before they cause a negative impact. Testing of polymeric membranes consists in carrying out the process of ultrafiltration of aqueous systems containing humic acid over a set time, following the variation in time of the volume of permeate obtained as well as the influence of process parameters. Following the investigation of the ultrafiltration process of the water through the polymeric membrane, it was found that the formation of the humic acid layer on the surface of the membrane that favors fouling is delayed, after many hours of operation, due to both the internal fiber structure which offers advantages to this type of membranes as well as high efficiency of humic acid retention. Experimental results showed that the humic acid retention rate increased by up to 37% as a result of the double decrease of the conductivity value in the permeate samples from about 600 mS/cm to 373 mS/cm and the temperature being continuously increasing, from 22.5 at 25oC over 5 h influenced the entire ultrafiltration process. The full process approach as well as the expression and interpretation of the results will be detailed in this paper.


2019 ◽  
Vol 56 (1) ◽  
pp. 97-102 ◽  
Author(s):  
Laurentiu Tataru ◽  
Valentin Nedeff ◽  
Narcis Barsan ◽  
Andrei Victor Sandu ◽  
Emilian Mosnegutu ◽  
...  

In the field of purification and treatment of waste water resulting from various domestic and industrial activities, classical methods of retention of pollutants almost can no longer eliminate their large quantities, and this signifies a problem related to the environment. Filtration membrane technology has a larger footprint in the removal of these pollutants, and their success is due to virtually the quality of the resulting water. This paper highlights the development of a wastewater ultrafiltration process, containing bentonite, an inorganic compound found in wastewater from industries such as the steel industry, food industry, and so on. This study aims to find the relation between all parameters present in the ultrafiltration process, respectively how these parameters can influence each other. The study is necessary because bentonite, from a common substance, can be a dangerous pollutant, especially if it comes into contact with other compounds that in chemical reactions can harm the environment, and this raises questions to researchers who are experimenting with water purification technologies at a state-of-the-art level. At the same time, the study aims at determining the percentage of bentonite retaining on the membrane filtration surface, and in the final analysis of how bentonite can block the pores of the membrane or deposit on its surface. Throughout the entire ultrafiltration experiment it will be monitorized parameters related to organic membrane with hollow fibers and the results of physico-chemical indicators obtained at the final of the process. The results of the study showed that bentonite can be retained more than 20%. Accumulation of bentonite on the surface of the membrane decreased slightly the volume of permeate at the end of the experiment, resulting in an insignificant decrease in the volume of the liquid in the membrane. The results on bentonite retention efficiency and dependence parameters in the ultrafiltration process will be detailed in the present paper.


Author(s):  
R.T. Chen ◽  
M.G. Jamieson ◽  
R. Callahan

“Row lamellar” structures have previously been observed when highly crystalline polymers are melt-extruded and recrystallized under high stress. With annealing to perfect the stacked lamellar superstructure and subsequent stretching in the machine (extrusion) direction, slit-like micropores form between the stacked lamellae. This process has been adopted to produce polymeric membranes on a commercial scale with controlled microporous structures. In order to produce the desired pore morphology, row lamellar structures must be established in the membrane precursors, i.e., as-extruded and annealed polymer films or hollow fibers. Due to the lack of pronounced surface topography, the lamellar structures have typically been investigated by replica-TEM, an indirect and time consuming procedure. Recently, with the availability of high resolution imaging techniques such as scanning tunneling microscopy (STM) and field emission scanning electron microscopy (FESEM), the microporous structures on the membrane surface as well as lamellar structures in the precursors can be directly examined.The materials investigated are Celgard® polyethylene (PE) flat sheet membranes and their film precursors, both as-extruded and annealed, made at different extrusion rates (E.R.).


Author(s):  
Lorna K. Mayo ◽  
Kenneth C. Moore ◽  
Mark A. Arnold

An implantable artificial endocrine pancreas consisting of a glucose sensor and a closed-loop insulin delivery system could potentially replace the need for glucose self-monitoring and regulation among insulin dependent diabetics. Achieving such a break through largely depends on the development of an appropriate, biocompatible membrane for the sensor. Biocompatibility is crucial since changes in the glucose sensors membrane resulting from attack by orinter action with living tissues can interfere with sensor reliability and accuracy. If such interactions can be understood, however, compensations can be made for their effects. Current polymer technology offers several possible membranes that meet the unique chemical dynamics required of a glucose sensor. Two of the most promising polymer membranes are polytetrafluoroethylene (PTFE) and silicone (Si). Low-voltage scanning electron microscopy, which is an excellent technique for characterizing a variety of polymeric and non-conducting materials, 27 was applied to the examination of experimental sensor membranes.


Polymer News ◽  
2004 ◽  
Vol 29 (8) ◽  
pp. 253-257
Author(s):  
Tejraj Aminabhavi ◽  
Udaya Toti ◽  
Mahaveer Kurkuri ◽  
Nadagouda Mallikarjuna ◽  
Lakshmi Shetti
Keyword(s):  

2001 ◽  
Author(s):  
J. Zartman ◽  
V. Khare ◽  
A. Greenberg ◽  
M. Pekny ◽  
P. Todd ◽  
...  

2020 ◽  
Author(s):  
Ruobin Dai ◽  
Hongyi Han ◽  
Tianlin Wang ◽  
Jiayi Li ◽  
Chuyang Y. Tang ◽  
...  

Commercial polymeric membranes are generally recognized to have low sustainability as membranes need to be replaced and abandoned after reaching the end of their life. At present, only techniques for downcycling end-of-life high-pressure membranes are available. For the first time, this study paves the way for upcycling fouled/end-of-life low-pressure membranes to fabricate new high-pressure membranes for water purification, forming a closed eco-loop of membrane recycling with significantly improved sustainability.


2013 ◽  
Vol 12 (8) ◽  
pp. 1583-1591 ◽  
Author(s):  
Eugenia Teodora Iacob Tudose Ioan Mamaliga ◽  
Ciprian Constantin Negoescu ◽  
Nicoleta Bunduc

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