Enhanced Thermal Stability, Mechanical Properties and Structural Integrity of MWCNT Filled Bamboo/Kenaf Hybrid Polymer Nanocomposites

Recently, there has been an inclination towards natural fibre reinforced polymer composites owing to their merits such as environmental friendliness, light weight and excellent strength. In the present study, six laminates were fabricated consisting of natural fibres such as Kenaf fibre (Hibiscus cannabinus L.) and Bamboo fibre, together with multi-walled carbon nanotubes (MWCNTs) as reinforcing fillers in the epoxy matrix. Mechanical testing revealed that hybridization of natural fibres was capable of yielding composites with enhanced tensile properties. Additionally, impact testing showed a maximum improvement of ≈80.6% with the inclusion of MWCNTs as nanofiller in the composites with very high energy absorption characteristics, which were attributed to the high specific energy absorption of carbon nanotubes. The viscoelastic behaviour of hybridised composites reinforced with MWCNTs also showed promising results with a significant improvement in the glass transition temperature (Tg) and 41% improvement in storage modulus. It is worth noting that treatment of the fibres in NaOH solution prior to composite fabrication was effective in improving the interfacial bonding with the epoxy matrix, which, in turn, resulted in improved mechanical properties.

High intensity proton beam impact at 440 GeV/c on Mo and Cu coated CfC/graphite and SiC/SiC absorbers for beam intercepting devices

Beam Intercepting Devices (BIDs) are essential protection elements for the operation of the Large Hadron Collider (LHC) complex. The LHC internal beam dump (LHC Target Dump Injection or LHC TDI) is the main protection BID of the LHC injection system; its main function is to protect LHC equipment in the event of a malfunction of the injection kicker magnets during beam transfer from the SPS to the LHC. Several issues with the TDI were encountered during LHC operation, most of them due to outgassing from its core components induced by electron cloud effects, which led to limitations of the injector intensity and hence had an impact on LHC availability. The absorbing cores of the TDIs, and of beam intercepting devices in general, need to deal with high thermo-mechanical loads induced by the high intensity particle beams. In addition, devices such as the TDI — where the absorbing materials are installed close to the beam, are important contributors to the accelerator impedance budget. To reduce impedance, the absorbing materials that make up the core must be typically coated with high electrical conductivity metals. Beam impact testing of the coated absorbers is a crucial element of development work to ensure their correct operation. In the work covered by this paper, the behaviour of several metal-coated absorber materials was investigated when exposed to high intensity and high energy proton beams in the HiRadMat facility at CERN. Different coating configurations based on copper and molybdenum, and absorbing materials such as isostatic graphite, Carbon Fibre Composite (CfC) and Silicon Carbide reinforced with Silicon Carbide fibres (SiC-SiC), were tested in the facility to assess the TDI's performance and to extract information for other BIDs using these materials. In addition to beam impact tests and an extensive Post Irradiation Examination (PIE) campaign to assess the performance of the coatings and the structural integrity of the substrates, extensive numerical simulations were carried out.

Impact modification of hybrid polypropylene composites with poly(vinyl alcohol) fibers

Polypropylene (PP) hybrid composites were prepared by the combination of three reinforcing (carbon, glass, and wood) and a synthetic (PVA) fiber. Tensile and impact testing, acoustic emission measurements, and scanning electron microscopy (SEM) were used for the characterization of the composites as well as to follow deformation and failure processes. The results obtained prove that the novel concept of using synthetic fibers for impact modification can be applied successfully also with PVA fibers. The extent of improvement in impact strength depends on fiber type and content, but also on interfacial adhesion which strongly influences the local deformation processes occurring around the fibers during fracture. Both the reinforcing and the synthetic fibers take part in these processes and contribute to energy consumption. Debonding and the subsequent plastic deformation of the matrix consumes energy the most efficiently, but the fracture of the PVA fibers also requires energy; thus, PVA fibers improve impact resistance both at poor and good adhesion. This approach allows the design of materials for structural applications; the combination of a stiffness of 4–6 GPa and an impact resistance of 20–25 kJ/m2 exceeds the properties of most PP composites available on the market.

3D printed geometrically tessellated sheets with origami-inspired patterns

This study demonstrates that the impact energy absorption capabilities of flexible sheets can be significantly enhanced by implementing tessellated designs into their structure. Configurations of three tessellated geometries were tested; they included a triangular-based, a rectangular-based, and a novel square-based pattern. Due to their geometrical complexity, multiple configurations of these tessellations were printed from a rubber-like material using an inkjet printer with two different thicknesses (2 and 4 mm), and their ability to absorb impact energy was compared to an unpatterned inkjet-printed sheet. In addition, the effect of multi-sheets stacking was also tested. Due to the tailored structure, the impact testing showed that the single-layer sheets were more effective at absorbing impact loads, and experience less deformation, than their two-layer counterparts. The 4 mm thick tessellated patterns were most effective at absorbing impact loads; all three thick patterns measured about 40% lower impact forces transferred to the base of the samples compared to the unpatterned counterparts.

Property Correlations of Polypropylene based Composites Filled with Mimusop elengi Seed Shell Powder

The saturation point of Mimusop elengi seed shell powder (MESSP) and the effect of MESSP addition on the mechanical, thermal, water absorption and morphological properties of polypropylene (PP) composites were studied. Tensile fracture, physio-mechanical properties and thermal behavior of composites were characterized using tensile and impact testing, thermogravimetric analysis, scanning electron micrograph, and differential scanning calorimetry. Processability of composites were feasible up to 20 wt. % MESSP by which agglomeration of MESSP and poor dispersion of MESSP in PP was observed above 20 wt% MESSP loading. Increasing MESSP loading showed tremendous improvement in tensile modulus and impact strength, whereas tensile strength and elongation at break were reduced. Water absorption and thermal decomposition of composites remain comparable with addition of MESSP up to 20 wt. %. Reduction of tensile strength was attributed by weak adhesion between MESSP and PP. However, morphological analysis revealed the presence of physical interaction via PP chain interlocking on MESSP surface.