Fibers covered with 3D interconnected network of Au nanostructures and their application in SERS detection

Gold Bulletin ◽  
2022 ◽  
Author(s):  
Cuiping Wang ◽  
Huan Zhang ◽  
Chunrong Wang
2021 ◽  
pp. 129741
Author(s):  
Yingying Sun ◽  
Wan Li ◽  
Liqing Zhao ◽  
Fengyong Li ◽  
Yunfei Xie ◽  
...  

2021 ◽  
pp. 000370282110329
Author(s):  
Ling Wang ◽  
Mario O. Vendrell-Dones ◽  
Chiara Deriu ◽  
Sevde Doğruer ◽  
Peter de B. Harrington ◽  
...  

Recently there has been upsurge in reports that illicit seizures of cocaine and heroin have been adulterated with fentanyl. Surface-enhanced Raman spectroscopy (SERS) provides a useful alternative to current screening procedures that permits detection of trace levels of fentanyl in mixtures. Samples are solubilized and allowed to interact with aggregated colloidal nanostars to produce a rapid and sensitive assay. In this study, we present the quantitative determination of fentanyl in heroin and cocaine using SERS, using a point-and-shoot handheld Raman system. Our protocol is optimized to detect pure fentanyl down to 0.20 ± 0.06 ng/mL and can also distinguish pure cocaine and heroin at ng/mL levels. Multiplex analysis of mixtures is enabled by combining SERS detection with principal component analysis and super partial least squares regression discriminate analysis (SPLS-DA), which allow for the determination of fentanyl as low as 0.05% in simulated seized heroin and 0.10% in simulated seized cocaine samples.


2020 ◽  
Vol 9 (1-2) ◽  
pp. 89-100 ◽  
Author(s):  
Xinyu Hu ◽  
Rui Pan ◽  
Mingyong Cai ◽  
Weijian Liu ◽  
Xiao Luo ◽  
...  

AbstractEvaporation concentration of target analytes dissolved in a water droplet based on superhydrophobic surfaces could be able to break the limits for sensitive trace substance detection techniques (e.g. SERS) and it is promising in the fields such as food safety, eco-pollution, and bioscience. In the present study, polytetrafluoroethylene (PTFE) surfaces were processed by femtosecond laser and the corresponding processing parameter combinations were optimised to obtain surfaces with excellent superhydrophobicity. The optimal parameter combination is: laser power: 6.4 W; scanning spacing: 40 μm; scanning number: 1; and scanning path: 90 degree. For trapping and localising droplets, a tiny square area in the middle of the surface remained unprocessed for each sample. The evaporation and concentration processes of droplets on the optimised surfaces were performed and analyzed, respectively. It is shown that the droplets with targeted solute can successfully collect all solute into the designed trapping areas during evaporation process on our laser fabricated superhydrophobic surface, resulting in detection domains with high solute concentration for SERS characterisation. It is shown that the detected peak intensity of rhodamine 6G with a concentration of 10−6m in SERS characterisation can be obviously enhanced by one or two orders of magnitude on the laser fabricated surfaces compared with that of the unprocessed blank samples.


2021 ◽  
Vol 2 (1) ◽  
Author(s):  
Lawrence C. Carter ◽  
Ben J. Williamson ◽  
Simon R. Tapster ◽  
Catia Costa ◽  
Geoffrey W. Grime ◽  
...  

AbstractPorphyry-type deposits are the world’s main source of copper and molybdenum and provide a large proportion of gold and other metals. However, the mechanism by which mineralising fluids are extracted from source magmas and transported upwards into the ore-forming environment is not clearly understood. Here we use field, micro-textural and geochemical techniques to investigate field relationships and samples from a circa 8 km deep cross-section through the archetypal Yerington porphyry district, Nevada. We identify an interconnected network of relatively low-temperature hydrothermal quartz that is connected to mineralised miarolitic cavities within aplite dykes. We propose that porphyry-deposit-forming fluids migrated from evolved, more water-rich internal regions of the underlying Luhr Hill granite via these aplite dykes which contained a permeable magmatic crystal mush of feldspar and quartz. The textures we describe provide petrographic evidence for the transport of fluids through crystal mush dykes. We suggest that this process should be considered in future models for the formation of porphyry- and similar-type deposits.


Small ◽  
2021 ◽  
pp. 2100755
Author(s):  
Sara Gullace ◽  
Verónica Montes‐García ◽  
Victor Martín ◽  
David Larios ◽  
Valentina Girelli Consolaro ◽  
...  

RSC Advances ◽  
2021 ◽  
Vol 11 (16) ◽  
pp. 9518-9527
Author(s):  
Iván A. Ramos ◽  
L. M. León Hilario ◽  
María L. Pedano ◽  
Andres A. Reynoso

Designs with gold covering far from the gap area applied on nanorod-dimer antennas can enable hybrid electrical and SERS detection. Simulations show promising and robust increasement of the enhancement factor with respect to the uncovered dimer.


2021 ◽  
Vol 544 ◽  
pp. 148908
Author(s):  
Jihua Xu ◽  
Yuan Si ◽  
Zhen Li ◽  
Shouzhen Jiang ◽  
Xianwu Xiu ◽  
...  

2020 ◽  
Vol 8 (4) ◽  
pp. 429-439
Author(s):  
Ying Tao ◽  
Rong Li ◽  
Ai-Bin Huang ◽  
Yi-Ning Ma ◽  
Shi-Dong Ji ◽  
...  

AbstractAmong the transition metal oxide catalysts, manganese oxides have great potential for formaldehyde (HCHO) oxidation at ambient temperature because of their high activity, nontoxicity, low cost, and polybasic morphologies. In this work, a MnO2-based catalyst (M-MnO2) with an interconnected network structure was successfully synthesized by a one-step hydrothermal method. The M-MnO2 catalyst was composed of the main catalytic agent, δ-MnO2 nanosheets, dispersed in a nonactive framework material of γ-MnOOH nanowires. The catalytic activity of M-MnO2 for HCHO oxidation at room temperature was much higher than that of the pure δ-MnO2 nanosheets. This is attributed to the special interconnected network structure. The special interconnected network structure has high dispersion and specific surface area, which can provide more surface active oxygen species and higher surface hydroxyl groups to realize rapid decomposition of HCHO.


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