scholarly journals Perspectives and challenges for lead-free energy-storage multilayer ceramic capacitors

2021 ◽  
Vol 10 (6) ◽  
pp. 1153-1193
Author(s):  
Peiyao Zhao ◽  
Ziming Cai ◽  
Longwen Wu ◽  
Chaoqiong Zhu ◽  
Longtu Li ◽  
...  
Keyword(s):  
Free Energy ◽  
High Temperature ◽  
Energy Storage ◽  
Energy Density ◽  
State Of The Art ◽  
High Energy ◽  
High Energy Density ◽  
Lead Free ◽  
Multilayer Ceramic Capacitors ◽  
Multilayer Ceramic

AbstractThe growing demand for high-power-density electric and electronic systems has encouraged the development of energy-storage capacitors with attributes such as high energy density, high capacitance density, high voltage and frequency, low weight, high-temperature operability, and environmental friendliness. Compared with their electrolytic and film counterparts, energy-storage multilayer ceramic capacitors (MLCCs) stand out for their extremely low equivalent series resistance and equivalent series inductance, high current handling capability, and high-temperature stability. These characteristics are important for applications including fast-switching third-generation wide-bandgap semiconductors in electric vehicles, 5G base stations, clean energy generation, and smart grids. There have been numerous reports on state-of-the-art MLCC energy-storage solutions. However, lead-free capacitors generally have a low-energy density, and high-energy density capacitors frequently contain lead, which is a key issue that hinders their broad application. In this review, we present perspectives and challenges for lead-free energy-storage MLCCs. Initially, the energy-storage mechanism and device characterization are introduced; then, dielectric ceramics for energy-storage applications with aspects of composition and structural optimization are summarized. Progress on state-of-the-art energy-storage MLCCs is discussed after elaboration of the fabrication process and structural design of the electrode. Emerging applications of energy-storage MLCCs are then discussed in terms of advanced pulsed power sources and high-density power converters from a theoretical and technological point of view. Finally, the challenges and future prospects for industrialization of lab-scale lead-free energy-storage MLCCs are discussed.

scholarly journals Lead-free (Ba,Sr)TiO3 – BiFeO3 based multilayer ceramic capacitors with high energy density

2020 ◽  
Vol 40 (4) ◽  
pp. 1779-1783 ◽  
Author(s):  
Ge Wang ◽  
Zhilun Lu ◽  
Jinglei Li ◽  
Hongfen Ji ◽  
Huijing Yang ◽  
...  
Keyword(s):  
Energy Density ◽  
High Energy ◽  
High Energy Density ◽  
Lead Free ◽  
Multilayer Ceramic Capacitors ◽  
Ceramic Capacitors ◽  
Multilayer Ceramic

Significantly enhanced energy storage performance of flexible composites using sodium bismuth titanate based lead-free fillers

2020 ◽  
Vol 8 (42) ◽  
pp. 14910-14918
Author(s):  
Pingan Yang ◽  
Lili Li ◽  
Hongbin Yuan ◽  
Fei Wen ◽  
Peng Zheng ◽  
...  
Keyword(s):  
Energy Storage ◽  
Energy Density ◽  
Bismuth Titanate ◽  
High Energy ◽  
High Energy Density ◽  
Lead Free ◽  
Sodium Bismuth Titanate ◽  
Flexible Composites ◽  
Storage Performance

A new lead-free antiferroelectric ceramic NBT–SBT was introduced into PVDF polymer to fabricate composites films, achieving record-high energy density of 15.3 J cm−3 at 500 MV m−1 and meeting the requirement of miniaturization and lightweight device.

scholarly journals Strategies to Improve the Energy Storage Properties of Perovskite Lead-Free Relaxor Ferroelectrics: A Review

Materials ◽  
2020 ◽  
Vol 13 (24) ◽  
pp. 5742
Author(s):  
Vignaswaran Veerapandiyan ◽  
Federica Benes ◽  
Theresa Gindel ◽  
Marco Deluca
Keyword(s):  
Energy Storage ◽  
Energy Density ◽  
Electrical Energy ◽  
High Energy ◽  
Relaxor Ferroelectrics ◽  
High Energy Density ◽  
Lead Free ◽  
Chemical Additives ◽  
Energy Storage Properties ◽  
Novel Processing

Electrical energy storage systems (EESSs) with high energy density and power density are essential for the effective miniaturization of future electronic devices. Among different EESSs available in the market, dielectric capacitors relying on swift electronic and ionic polarization-based mechanisms to store and deliver energy already demonstrate high power densities. However, different intrinsic and extrinsic contributions to energy dissipations prevent ceramic-based dielectric capacitors from reaching high recoverable energy density levels. Interestingly, relaxor ferroelectric-based dielectric capacitors, because of their low remnant polarization, show relatively high energy density and thus display great potential for applications requiring high energy density properties. In this study, some of the main strategies to improve the energy density properties of perovskite lead-free relaxor systems are reviewed, including (i) chemical modification at different crystallographic sites, (ii) chemical additives that do not target lattice sites, and (iii) novel processing approaches dedicated to bulk ceramics, thick and thin films, respectively. Recent advancements are summarized concerning the search for relaxor materials with superior energy density properties and the appropriate choice of both composition and processing routes to match various applications’ needs. Finally, future trends in computationally-aided materials design are presented.

Lead-free BaTiO3–Bi(Zn2/3Nb1/3)O3 weakly coupled relaxor ferroelectric materials for energy storage

RSC Advances ◽  
2016 ◽  
Vol 6 (17) ◽  
pp. 14273-14282 ◽  
Author(s):  
Longwen Wu ◽  
Xiaohui Wang ◽  
Longtu Li
Keyword(s):  
Energy Efficiency ◽  
Energy Storage ◽  
Energy Density ◽  
High Energy ◽  
Ferroelectric Materials ◽  
Relaxor Ferroelectric ◽  
High Energy Density ◽  
Lead Free ◽  
Weakly Coupled ◽  
High Energy Efficiency

High energy density BaTiO3–Bi(Zn2/3Nb1/3)O3 materials with concurrently high energy efficiency.

Lead-Free Ceramics with High Energy Density and Reduced Losses for High Temperature Applications

2017 ◽  
Vol 19 (6) ◽  
pp. 1700019 ◽  
Author(s):  
Tatiana Correia ◽  
Mark Stewart ◽  
Angela Ellmore ◽  
Knuth Albertsen
Keyword(s):  
High Temperature ◽  
Energy Density ◽  
High Energy ◽  
High Energy Density ◽  
Lead Free ◽  
Lead Free Ceramics ◽  
Temperature Applications

Multilayer ceramic capacitors based on relaxor BaTiO3-Bi(Zn1/2Ti1/2)O3 for temperature stable and high energy density capacitor applications

2015 ◽  
Vol 106 (25) ◽  
pp. 252901 ◽  
Author(s):  
Nitish Kumar ◽  
Aleksey Ionin ◽  
Troy Ansell ◽  
Seongtae Kwon ◽  
Wesley Hackenberger ◽  
...  
Keyword(s):  
Energy Density ◽  
High Energy ◽  
High Energy Density ◽  
Multilayer Ceramic Capacitors ◽  
Ceramic Capacitors ◽  
Multilayer Ceramic

Achieved High Energy Density and Excellent Thermal Stability in (1-x)(Bi0.5Na0.5)0.94Ba0.06TiO3-xBi(Mg0.5Ti0.5)O3 Relaxor Ferroelectric Thin Films

2021 ◽  
Author(s):  
Hao Yan ◽  
Baijie Song ◽  
Kun Zhu ◽  
Liuxue Xu ◽  
Bo Shen ◽  
...  
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
Energy Storage ◽  
Energy Density ◽  
High Energy ◽  
High Energy Density ◽  
Lead Free ◽  
Relaxor Behavior ◽  
Moderate Amount ◽  
Excellent Thermal Stability

Abstract In this work, lead-free (1-x)(Bi0.5Na0.5)0.94Ba0.06TiO3-xBi(Mg0.5Ti0.5)O3 (abbreviated as BNBT-xBMT, x = 0.3, 0.4, 0.5 and 0.6) thin films were prepared on Pt/Ti/SiO2/Si substrates using sol-gel method. The microstructures, dielectric and energy storage properties were investigated. The results showed that the addition of BMT disrupted the long-range ferroelectric order and enhanced the relaxor behavior of BNBT-xBMT thin films. In addition, the leakage current density of thin films was also reduced by the doping of moderate amount of BMT. A high recoverable energy density of 34.36 J/cm3 with an efficiency of 56.63% was achieved in the BNBT-0.5BMT thin film under the electric field of 2149 kV/cm. Furthermore, BNBT-0.5BMT thin film exhibited superior stability in the temperature range of 30°C − 145°C and frequency range of 500 Hz − 5 kHz, as well as long-term fatigue durability after 1 × 105 cycles. These results suggest that BNBT-0.5BMT thin film may be a promising material for lead-free dielectric energy storage applications.

High-energy storage performance in BaTiO3-based lead-free multilayer ceramic capacitors

2020 ◽  
pp. 1-10
Author(s):  
Huijing Yang ◽  
Weichao Bao ◽  
Zhilun Lu ◽  
Linhao Li ◽  
Hongfen Ji ◽  
...  
Keyword(s):  
Energy Storage ◽  
High Energy ◽  
Lead Free ◽  
Multilayer Ceramic Capacitors ◽  
Storage Performance ◽  
Ceramic Capacitors ◽  
Multilayer Ceramic ◽  
High Energy Storage

Abstract

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