Leaching behavior of phosphorous compounds from sewage sludge ash based on quantitative X-ray diffraction analysis

2020 ◽  
Vol 2 (2) ◽  
pp. 113-125
Author(s):  
Pinjing He ◽  
Xiaotong Zhang ◽  
Fan Lü ◽  
Liming Shao ◽  
Hua Zhang
Keyword(s):  
Sewage Sludge ◽  
Diffraction Analysis ◽  
X Ray Diffraction ◽  
Leaching Behavior ◽  
Sewage Sludge Ash ◽  
X Ray ◽  
Sludge Ash ◽  
Phosphorous Compounds

Nanocrystalline and stacking-disordered β-cristobalite AlPO4: the now deciphered main constituent of a municipal sewage sludge ash from a full-scale incineration facility

2015 ◽  
Vol 30 (S1) ◽  
pp. S31-S35 ◽  
Author(s):  
B. Peplinski ◽  
C. Adam ◽  
B. Adamczyk ◽  
R. Müller ◽  
M. Michaelis ◽  
...  
Keyword(s):  
Sewage Sludge ◽  
Fluidized Bed ◽  
Large Scale ◽  
Sodium Hydroxide Solution ◽  
Direct Proof ◽  
Municipal Sewage ◽  
Municipal Sewage Sludge ◽  
Sewage Sludge Ash ◽  
X Ray ◽  
Sludge Ash

For the first time evidence is provided that a nanocrystalline and stacking-disordered, chemically stabilized β-cristobalite form of AlPO4 occurs in a sewage sludge ash (SSA). This proof is based on a combined X-ray powder diffraction and X-ray fluorescence investigation of an SSA produced at a large-scale fluidized bed incineration facility serving a catching area with a population of 2 million. The structural and chemical characterization was carried out on ‘as received’ SSA samples as well as on solid residues remaining after leaching this SSA in sodium hydroxide solution. Thus, it was ascertained that the observed nanocrystalline and stacking-disordered cristobalite-like component belongs to the aluminum phosphate component of this SSA, rather than to its silicon dioxide component. In addition, a direct proof is presented that the chemically stabilized β-cristobalite form of AlPO4 does crystallize from X-ray amorphous precursors under conditions that mimic the huge heating rate and short retention time (just seconds at T ≈ 850°C), typical for fluidized bed incinerators.

scholarly journals Evaluation of the long-term compressive strength development of the sewage sludge ash/metakaolin-based geopolymer

2021 ◽  
Vol 71 (343) ◽  
pp. e254
Author(s):  
D. Istuque ◽  
L. Soriano ◽  
M.V. Borrachero ◽  
J. Payá ◽  
J.L. Akasaki ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Sewage Sludge ◽  
Strength Development ◽  
X Ray Diffraction ◽  
Sewage Sludge Ash ◽  
Dense Microstructure ◽  
Compressive Strength Development ◽  
Physicochemical Characterisation ◽  
Sludge Ash

This paper aimed to evaluate the long-term compressive strength development of the sewage sludge ash/metakaolin (SSA/MK)-based geopolymer. SSA/MK-based geopolymeric mortars and pastes were produced at 25ºC with different SSA contents (0 - 30 wt.%). Compressive strength tests were run within the 3-720 curing days range. A physicochemical characterisation (X-ray diffraction and scanning electron microscopy) was performed in geopolymeric pastes. All the geopolymeric mortars presented a compressive strength gain with curing time. The mortars with all the SSA evaluated contents (10, 20, 30 wt.%) developed a compressive strength over 40 MPa after 720 curing days at 25ºC. The maximum compressive strength of the mortars with SSA was approximately 61 MPa (10 wt.% of SSA), similarly to the reference mortar (100% MK-based geopolymer). The microstructure analyses showed that the SSA/MK-based geopolymer presented a dense microstructure with N-A-S-H gel formation.

scholarly journals Properties of concrete containing microwaved sewage sludge ash

2021 ◽  
Vol 15 (4) ◽  
pp. 8469-8479
Author(s):  
M.A. Azed ◽  
D.S. Ing
Keyword(s):  
Mechanical Properties ◽  
Sewage Sludge ◽  
Modulus Of Elasticity ◽  
Strength Test ◽  
Sewage Sludge Ash ◽  
X Ray ◽  
Sludge Waste ◽  
Water Curing ◽  
Sludge Ash

Urban population of Malaysia is stated as 72.8% of its total population, and growing every year. Due to this growing number of population, the sewage sludge waste produce every year has also gradually increased. Malaysia itself produces 3.2 million m3 of sewage sludge annually. Normally all of this waste is disposed by landfill. Furthermore, usual production of cement and sewage sludge ash consumes a lot of energy by using incineration process with a very high temperature. Thus, microwave heating method was an alternatives use in this research to reduce the consumption of energy and time used to heat the sewage sludge ash. This research was conducted to investigate the optimum performances of different percentage (0%, 5%, 10%, 15% and 20%) by weight of cement of the Microwaved Sewage Sludge Ash (MSSA) concrete with different curing regime, which was air and water curing. The characteristic of MSSA was tested by X-Ray Fluorescence (XRF), X-Ray Diffraction (XRD) and Scanning Electron Microscopy (SEM). The mechanical properties of MSSA concrete was examined by Compressive Strength test, Flexural Strength test and Modulus of Elasticity test after 180 days of curing. The MSSA samples were also tested with water absorption test to evaluate the quality of concrete in term of porosity and permeability. Water curing sample with 5% of MSSA (W5) had the best in results compared to other specimens. The mechanical properties of W5 content in concrete shows the most optimum samples due to the densification of pozzolanic reaction and filler effect of MSSA. The curing effect with better result was water curing, as it got highest value of strength in compressive test, flexural test and modulus of elasticity test. As conclusion, based on the results, it is shown the positive impact on using the MSSA as additional material to the cement mixture to improve the quality of the concrete. Thus, this will reduce the disposal of sewage sludge waste on dumping site and improves the quality performances of the concrete.

Ten-Vertex Polyhedral Monocarbaborane Chemistry. The Novel High-Yield Formation of the Ten-Vertex closo Compound [6-(PMe2Ph)-closo-1-CB9H9] from the Thermolysis of [8,8-(PMe2Ph)2-nido-8,7-PtCB9H11]

1993 ◽  
Vol 58 (12) ◽  
pp. 2924-2935 ◽  
Author(s):  
Jane H. Jones ◽  
Bohumil Štíbr ◽  
John D. Kennedy ◽  
Mark Thornton-Pett
Keyword(s):  
Nmr Spectroscopy ◽  
Diffraction Analysis ◽  
High Yield ◽  
Monoclinic Space Group ◽  
The Novel ◽  
X Ray Diffraction ◽  
Metal Centre ◽  
X Ray ◽  
Yield Formation ◽  
Boiling Toluene

Thermolysis of [8,8-(PMe2Ph)2-nido-8,7-PtCB9H11] in boiling toluene solution results in an elimination of the platinum centre and cluster closure to give the ten-vertex closo species [6-(PMe2Ph)-closo-1-CB9H9] in 85% yield as a colourles air stable solid. The product is characterized by NMR spectroscopy and single-crystal X-ray diffraction analysis. Crystals (from hexane-dichloromethane) are monoclinic, space group P21/c, with a = 903.20(9), b = 1 481.86(11), c = 2 320.0(2) pm, β = 97.860(7)° and Z = 8, and the structure has been refined to R(Rw) = 0.045(0.051) for 3 281 observed reflections with Fo > 2.0σ(Fo). The clean high-yield elimination of a metal centre from a polyhedral metallaborane or metallaheteroborane species is very rare.

Bis(μ-carboxylato)dienerhodium(I) Complexes - Synthesis, Characterization and Catalytic Activity

2008 ◽  
Vol 73 (8-9) ◽  
pp. 1205-1221 ◽  
Author(s):  
Jiří Zedník ◽  
Jan Sedláček ◽  
Jan Svoboda ◽  
Jiří Vohlídal ◽  
Dmitrij Bondarev ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Diffraction Analysis ◽  
Spectroscopic Methods ◽  
X Ray Diffraction ◽  
X Ray

Dinuclear rhodium(I) η2:η2-cycloocta-1,5-diene (series a) and η2:η2-norborna-2,5-diene (series b) complexes with μ-RCOO- ligands, where R is linear C21H43 (complexes 1a, 1b), CH2CMe3 (2a, 2b), 1-adamantyl (3a, 3b) and benzyl (4a, 4b), have been prepared and characterized by spectroscopic methods. Structures of complexes 2b, 3a and 4a were determined by X-ray diffraction analysis. Complexes prepared show low to moderate catalytic activity in polymerization of phenylacetylene in THF giving high-cis-transoid polymers, but they show only oligomerization activity in dichloromethane.

Sign in / Sign up

Export Citation Format

Share Document