Theoretical and solid state aspects of electrochemistry (with special contributions on optical methods of investigation of electrochemical interfaces)

1982 ◽  
Vol 131 ◽  
pp. 411
1998 ◽  
Vol 70 (15) ◽  
pp. 518A-527A ◽  
Author(s):  
YuYe Tong ◽  
Eric Oldfield ◽  
Andrzej Wieckowski

2020 ◽  
Vol 15 (1) ◽  
Author(s):  
Sepehr Lajevardi Esfahani ◽  
Shohre Rouhani ◽  
Zahra Ranjbar

Abstract It proved that the most destructive effects of the toxic Al3+ ion on the human nervous system and disease that are involved with this system, such as Alzheimer's. The development of solid-state electrodes is still in its infancy during the sensor-based detection methods for Al3+. Hence, in this study, a novel flexible ITO/PET-based electrochemical solid-state sensor was designed and constructed. Modification of the surface of electrode bedding was done by layer-by-layer (LbL) assembly of Mg–Al LDH. nanoplatelets along with alizarin red S (ARS) in an interconnected matrix film. In the molecular design of sensing base of the electrode, the electroactive organic units (ARS molecules) present in the ITO/PET-layered (ARS/LDHs)n matrix are involved in electrochemical reactions when exposed to the target molecule (Al3+ ion), so the electrochemical changes of the new formed Al-chelated system are detectable. This type of sensor is used for sensitive and selective detection of Al3+. The minimum sheet resistance, morphology and high electrocatalytic activity of the modified matrix film are obtained in the fifth cycle of LbL assembly technique. In this electrochemical sensor, both electrochemical and optical methods were detected with high sensitivity and selectivity of Al3+, so that in a cyclic voltammetry electrochemical method, the lower detection limit of 10.1 nM with a linear range of [0.2–120 μM] was obtained compared to the fluorescence-based optical method.


2020 ◽  
Vol 10 (15) ◽  
pp. 5111
Author(s):  
Zbigniew Bielecki ◽  
Tadeusz Stacewicz ◽  
Janusz Smulko ◽  
Jacek Wojtas

High precision and fast measurement of gas concentrations is important for both understanding and monitoring various phenomena, from industrial and environmental to medical and scientific applications. This article deals with the recent progress in ammonia detection using in-situ solid-state and optical methods. Due to the continuous progress in material engineering and optoelectronic technologies, these methods are among the most perceptive because of their advantages in a specific application. We present the basics of each technique, their performance limits, and the possibility of further development. The practical implementations of representative examples are described in detail. Finally, we present a performance comparison of selected practical application, accumulating data reported over the preceding decade, and conclude from this comparison.


Joule ◽  
2018 ◽  
Vol 2 (11) ◽  
pp. 2189-2193 ◽  
Author(s):  
Veronica Augustyn ◽  
Matthew T. McDowell ◽  
Aleksandra Vojvodic

Author(s):  
T. J. Magee ◽  
J. Peng ◽  
J. Bean

Cadmium telluride has become increasingly important in a number of technological applications, particularly in the area of laser-optical components and solid state devices, Microstructural characterizations of the material have in the past been somewhat limited because of the lack of suitable sample preparation and thinning techniques. Utilizing a modified jet thinning apparatus and a potassium dichromate-sulfuric acid thinning solution, a procedure has now been developed for obtaining thin contamination-free samples for TEM examination.


Author(s):  
Kenneth M. Richter ◽  
John A. Schilling

The structural unit of solid state collagen complexes has been reported by Porter and Vanamee via EM and by Cowan, North and Randall via x-ray diffraction to be an ellipsoidal unit of 210-270 A. length by 50-100 A. diameter. It subsequently was independently demonstrated by us in dog tendon, dermis, and induced complexes. Its detailed morphologic, dimensional and molecular weight (MW) aspects have now been determined. It is pear-shaped in long profile with m diameters of 57 and 108 A. and m length of 263 A. (Fig. 1, tendon, KMnO4 fixation, Na-tungstate; Fig. 2a, schematic of unit in long, C, and x-sectional profiles of its thin, xB, and bulbous, xA portions; Fig. 2b, tendon essentially unmodified by ether and 0.4 N NaOH treatment, Na-tungstate). The unit consists of a uniquely coild cable, c, of ṁ 22.9 A. diameter and length of 2580-3316 A. The cable consists of three 2nd-strands, s, each of m 10.6 A.


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