Hazards associated with the use of electrochemically prepared substrates in the qualitative analysis of aqueous solutions by surface-enhanced Raman spectroscopy

1993 ◽  
Vol 49 (5-6) ◽  
pp. 837-843 ◽  
Author(s):  
L. Markwort ◽  
P.J. Hendra
2015 ◽  
Vol 17 (33) ◽  
pp. 21364-21372 ◽  
Author(s):  
Rudolf Holze

The adsorbate formed by adsorption of thiophenol on a polycrystalline gold electrode and brought into contact with aqueous solutions of 1 M HClO4and 0.1 M KClO4has been studied using cyclic voltammetry and surface-enhanced Raman spectroscopy.


Author(s):  
Sampson Saj Andoh ◽  
Tarmo Nuutinen ◽  
Cheetham Mingle ◽  
Matthieu Roussey

Abstract Background Palm oil is one of the most useful vegetable available. Sudan IV dye is used as hue enhancer in palm oil despite the ban as food colorant due to its carcinogenicity and mutagenicity by the International Agency for Research on Cancer (IARC). Methods Surface enhanced Raman spectroscopy (SERS) coupled with chemometric methods was applied to detect the presence of Sudan IV in some edible palm oil samples. Results We studied the samples within the 1200–1800 cm− 1 Raman frequency range. In predicting adulteration, we used 1388 cm− 1 Raman peak that is associated with Sudan IV as our marker. We were able to confirm adulteration in four of the five palm oil samples provided by the Food and Drug Authority of Ghana. Conclusions With these methods, we confirmed the results from Food and Drug Authorities of Ghana by proving that there were indeed Sudan IV adulteration in some palm oil samples.


RSC Advances ◽  
2016 ◽  
Vol 6 (15) ◽  
pp. 12131-12142 ◽  
Author(s):  
R. A. Harris ◽  
M. Mlambo ◽  
P. S. Mdluli

The surface enhanced Raman spectroscopy enhancement factors (SERS EFs) for different AuNP–surfactant systems are measured and the observed trend is theoretically and qualitatively investigated.


2017 ◽  
Author(s):  
Caitlin S. DeJong ◽  
David I. Wang ◽  
Aleksandr Polyakov ◽  
Anita Rogacs ◽  
Steven J. Simske ◽  
...  

Through the direct detection of bacterial volatile organic compounds (VOCs), via surface enhanced Raman spectroscopy (SERS), we report here a reconfigurable assay for the identification and monitoring of bacteria. We demonstrate differentiation between highly clinically relevant organisms: <i>Escherichia coli</i>, <i>Enterobacter cloacae</i>, and <i>Serratia marcescens</i>. This is the first differentiation of bacteria via SERS of bacterial VOC signatures. The assay also detected as few as 10 CFU/ml of <i>E. coli</i> in under 12 hrs, and detected <i>E. coli</i> from whole human blood and human urine in 16 hrs at clinically relevant concentrations of 10<sup>3</sup> CFU/ml and 10<sup>4</sup> CFU/ml, respectively. In addition, the recent emergence of portable Raman spectrometers uniquely allows SERS to bring VOC detection to point-of-care settings for diagnosing bacterial infections.


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