Сравнительное исследование электрохромных свойств слоев полианилин-поликислота, нанесенных методами спрей-распыления и полива с добавлением углеродных нанотрубок

The influence of coating method (spray-coating or drop-casting onto horizontal substrate) on the electrochromic characteristics of the layers of water-soluble polyaniline-polyacid complex was investigated. It was shown that in case of addition of single-wall nanotubes the polyaniline-polyacid layers prepared by scalable spray-coating technology demonstrate high coloration speed an electrochromic efficiency.

Unsteady hybrid-nanofluid flow comprising ferrousoxide and CNTs through porous horizontal channel with dilating/squeezing walls

The key objective of the present research is to examine the hybrid magnetohydrodynamics (MHD) nanofluid (Carbon-nanotubes and ferrous oxide–water) CNT–Fe3O4/H2 flow into a horizontal parallel channel with thermal radiation through squeezing and dilating porous walls. The parting motion is triggered by the porous walls of the channel. The fluid flow is time-dependent and laminar. The channel is asymmetric and the upper and lower walls are distinct in temperature and are porous. With the combination of nanoparticles of Fe3O4 and single and multi-wall carbon nanotubes, the hybrid nanofluid principle is exploited. By using the similarity transformation, the set of partial differential equations (PDEs) of this mathematical model, governed by momentum and energy equations, is reduced to corresponding ordinary differential equations (ODEs). A very simple numerical approach called the Runge–Kutta system of order four along with the shooting technique is used to achieve the solutions for regulating ODEs. MATLAB computing software is used to create temperature and velocity profile graphs for various emerging parameters. At the end of the manuscript, the main conclusions are summarized. Through different graphs, it is observed that hybrid-nanofluid has more prominent thermal enhancement than simple nanofluid. Further, the single-wall nanotubes have dominated impact on temperature than the multi-wall carbon nanotubes. From the calculations, it is also noted that Fe2O3–MWCNT–water has an average of 4.84% more rate of heat transfer than the Fe2O3–SWCNT–water. On the other hand, 8.27% more heat flow observed in Fe2O3–SWCNT–water than the simple nanofluid. Such study is very important in coolant circulation, inter-body fluid transportation, aerospace engineering, and industrial cleaning procedures, etc.

ZnO nucleation into trititanate nanotubes by ALD equipment techniques, a new way to functionalize layered metal oxides

In this contribution, we explore the potential of atomic layer deposition (ALD) techniques for developing new semiconductor metal oxide composites. Specifically, we investigate the functionalization of multi-wall trititanate nanotubes, H2Ti3O7 NTs (sample T1) with zinc oxide employing two different ALD approaches: vapor phase metalation (VPM) using diethylzinc (Zn(C2H5)2, DEZ) as a unique ALD precursor, and multiple pulsed vapor phase infiltration (MPI) using DEZ and water as precursors. We obtained two different types of tubular H2Ti3O7 species containing ZnO in their structures. Multi-wall trititanate nanotubes with ZnO intercalated inside the tube wall sheets were the main products from the VPM infiltration (sample T2). On the other hand, MPI (sample T3) principally leads to single-wall nanotubes with a ZnO hierarchical bi-modal functionalization, thin film coating, and surface decorated with ZnO particles. The products were mainly characterized by electron microscopy, energy dispersive X-ray, powder X-ray diffraction, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy. An initial evaluation of the optical characteristics of the products demonstrated that they behaved as semiconductors. The IR study revealed the role of water, endogenous and/or exogenous, in determining the structure and properties of the products. The results confirm that ALD is a versatile tool, promising for developing tailor-made semiconductor materials.

Structural and chemical mechanisms governing stability of inorganic Janus nanotubes

One-dimensional inorganic nanotubes hold promise for technological applications due to their distinct physical/chemical properties, but so far advancements have been hampered by difficulties in producing single-wall nanotubes with a well-defined radius. In this work we investigate, based on Density Functional Theory (DFT), the formation mechanism of 135 different inorganic nanotubes formed by the intrinsic self-rolling driving force found in asymmetric 2D Janus sheets. We show that for isovalent Janus sheets, the lattice mismatch between inner and outer atomic layers is the driving force behind the nanotube formation, while in the non-isovalent case it is governed by the difference in chemical bond strength of the inner and outer layer leading to steric effects. From our pool of candidate structures we have identified more than 100 tubes with a preferred radius below 35 Å, which we hypothesize can display distinctive properties compared to their parent 2D monolayers. Simple descriptors have been identified to accelerate the discovery of small-radius tubes and a Bayesian regression approach has been implemented to assess the uncertainty in our predictions on the radius.

Molecular insights on the dynamic stability of peptide nucleic acid functionalized carbon and boron nitride nanotubes

The rational design of self-assembled nanobio-molecular hybrids of peptide nucleic acids with single-wall nanotubes rely on understanding how biomolecules recognize and mediate intermolecular interactions with the nanomaterial's surface.

A Review of Inkjet Printed Graphene and Carbon Nanotubes Based Gas Sensors

Graphene and carbon nanotube (CNT)-based gas/vapor sensors have gained much traction for numerous applications over the last decade due to their excellent sensing performance at ambient conditions. Inkjet printing various forms of graphene (reduced graphene oxide or modified graphene) and CNT (single-wall nanotubes (SWNTs) or multiwall nanotubes (MWNTs)) nanomaterials allows fabrication onto flexible substrates which enable gas sensing applications in flexible electronics. This review focuses on their recent developments and provides an overview of the state-of-the-art in inkjet printing of graphene and CNT based sensors targeting gases, such as NO2, Cl2, CO2, NH3, and organic vapors. Moreover, this review presents the current enhancements and challenges of printing CNT and graphene-based gas/vapor sensors, the role of defects, and advanced printing techniques using these nanomaterials, while highlighting challenges in reliability and reproducibility. The future potential and outlook of this rapidly growing research are analyzed as well.

Channeling of Protons through Radial Deformed Double Wall Carbon Nanotubes

In this study we presented a theoretical investigation of the channeling of high energy protons with the radial deformed (10, 0)@(5, 0) double-wall carbon nanotubes (DWNTs). Proton energy is varied from 0.1 to 10 GeV. The channeling potential within the deformed DWNTs is presented. A Monte Carlo (MC) simulation is used to obtain spatial and angular distributions of channeled protons with radially deformed DWNTs. We treated problem relativistically. This is the first time that we presented spatial and angular distributions of channeled protons with radially deformed DWNTs. Our results show that the spatial and angular distributions depend strongly of nanotube lengths, proton energy, and especially of level of radial deformation of nanotube. Multi-wall nanotubes (MWNTs) can be technically realised with better channeling performance then single-wall nanotubes (SWNTs) and that is why we believe that these results may be useful for production and guiding of nanosized ion beams.