Fractionation of biological markers in crude oils during migration and the effects on correlation and maturation parameters

Author(s):  
JIANG ZHUSHENG ◽  
R.P. PHILP ◽  
C.A. LEWIS
World Science ◽  
2020 ◽  
Vol 1 (5(57)) ◽  
pp. 35-43
Author(s):  
Natela Khetsuriani ◽  
Vladimer Tsitsishvili ◽  
Elza Topuria ◽  
Madlena Chkhaidze ◽  
Irina Mchedlishvili

The results of investigation of molecular composition of biological markers of Eastern Georgia crude oils by methods of GLC, MS, GC/MS, genetic and geochemical aspects of their chemical composition, the main geochemical criteria for making various genetic correlations are presented. It was established that though these crude oils belong to different chemical types they all belong to a single genetic type. High concentrations of isoprenoid alkanes, ratio iC19/iC20 > 1, were revealed. In fractions higher than 420°С amongst the main biomarkers — steranes and triterpanes (C27–C33) – prevail hopanes of the 17αH-hopan series (C30H52); steranes (C27–C29) are represented by α-sterans and iso-sterans. Based on the main geochemical criteria the degree of catagenesis of oils and the probability of biodegradation of some of them was determined. In some crude oils polymethylsubstituted decalines, the relict type hydrocarbons (C14-C16) have been identified.


1982 ◽  
Vol 22 (1) ◽  
pp. 188 ◽  
Author(s):  
R. P. Philp ◽  
T. D. Gilbert ◽  
J. Friedrich

Correlation of crude oils with either their suspected source rocks or other crude oils thought to be derived from similar sources is important for basin studies and their suspected source rocks or other crude oils thought to be derived from similar sources is important for basin studies and and source rock extracts using computerized gas chromatography — mass spectrometry (C-GC-MS). Biological markers are compounds that retain the structure of molecules occurring in living organisms during diagenesis and conversion of the original organic material to petroleum hydrocarbons. In general, the distribution of biological markers is identical for oils from similar sources and for their respective source rocks. Differences in sources or maturity of the oils lead to differences, sometimes very subtle, in the distribution of the biological markers.Results from C-GC-MS analyses performed on a series of oils from the Gippsland, Carnarvon and Surat Basins show how two classes of biological markers, namely steranes and triterpanes, can be used for correlation purposes. Oils from the Gippsland Basin can be divided into two groups differing in source and maturity. Similarly, the oils examined from the Dampier Sub-basin fall into two groups. It is proposed that they have at least one common source, with one group being distinguished by the presence of additional source material. Additional data are presented to show that the Barrow Jurassic and Windalia oils are derived from the same or similar sources and differ only as a result of the biodegradation of the Windalia oil. Results for the limited number of oils examined from the Surat Basin suggest the presence of at least two sources for the oils of this basin.


2018 ◽  
Vol 41 ◽  
Author(s):  
Daniel Crimston ◽  
Matthew J. Hornsey

AbstractAs a general theory of extreme self-sacrifice, Whitehouse's article misses one relevant dimension: people's willingness to fight and die in support of entities not bound by biological markers or ancestral kinship (allyship). We discuss research on moral expansiveness, which highlights individuals’ capacity to self-sacrifice for targets that lie outside traditional in-group markers, including racial out-groups, animals, and the natural environment.


Sign in / Sign up

Export Citation Format

Share Document