High-temperature oxidation properties of ODS MA754 alloy

Author(s):  
K. Pryzybylski
2019 ◽  
Vol 71 (5) ◽  
pp. 706-711 ◽  
Author(s):  
Bingxue Cheng ◽  
Haitao Duan ◽  
Yongliang Jin ◽  
Lei Wei ◽  
Jia Dan ◽  
...  

Purpose This paper aims to investigate the thermal oxidation characteristics of the unsaturated bonds (C=C) of trimethylolpropane trioleate (TMPTO) and to reveal the high temperature oxidation decay mechanism of unsaturated esters and the nature of the anti-oxidation properties of the additives. Design/methodology/approach Using a DXR laser microscopic Raman spectrometer and Linkam FTIR600 temperature control platform, the isothermal oxidation experiments of TMPTO with or without 1.0 wt. % of different antioxidants were performed. Findings The results indicated that the Raman peaks of =C-H, C=C and -CH2- weaken gradually with prolonged oxidation time, and the corresponding Raman intensities drop rapidly at higher temperatures. The aromatic amine antioxidant can decrease the attenuation of peak intensity, as it significantly reduces the rate constant of C=C thermal oxidation. The hindered phenolic antioxidant has a protective effect during the early stages of oxidation (induction period), but it may accelerate the oxidation of C=C afterwards. Originality/value Research on the structure changes of synthetic esters during oxidation by Raman spectroscopy will be of great importance in promoting the use of Raman spectroscopy to analyze the oxidation of lubricants.


2015 ◽  
Vol 60 (2) ◽  
pp. 1169-1173
Author(s):  
Kee-Ahn Lee ◽  
Jae-Sung Oh ◽  
Young-Min Kong ◽  
Byoung-Kee Kim

Abstract Fe-Cr-Al based Powder porous metals were manufactured using a new electro-spray process, and the microstructures and high-temperature oxidation properties were examined. The porous materials were obtained at different sintering temperatures (1350°C, 1400°C, 1450°C, and 1500°)C and with different pore sizes (500 μm, 450 μm, and 200 μm). High-temperature oxidation experiments (TGA, Thermal Gravimetry Analysis) were conducted for 24 hours at 1000°C in a 79% N2+ 21% O2, 100 mL/min. atmosphere. The Fe-Cr-Al powder porous metals manufactured through the electro-spray process showed more-excellent oxidation resistance as sintering temperature and pore size increased. In addition, the fact that the densities and surface areas of the abovementioned powder porous metals had the largest effects on the metal’s oxidation properties could be identified.


2011 ◽  
Vol 189-193 ◽  
pp. 441-446
Author(s):  
Xiao Xia Tan ◽  
Zong De Liu

NiAl and Ni3Al intermetallic compound claddings are prepared by argon arc cladding technology on the 16Mn steel substrate. These claddings were oxidized for 100 hours at 850 and the oxide quality of each sample was recorded every 10 hours. The results show that the NiAl and Ni3Al claddings have homogeneous structure and few defects, and form excellent metallurgical bonding with the matrix. The oxidation kinetics results show that, the oxidation weight gain rate of NiAl was more stable than Ni3Al and tended to zero earlier. Oxide layer spallation of Ni3Al cladding was more serious than that of NiAl cladding. Thus, NiAl argon arc cladding has the more excellent high temperature oxidation properties than Ni3Al argon arc cladding.


2004 ◽  
Vol 2004 (0) ◽  
pp. 213-214
Author(s):  
Masayuki ARAI ◽  
Uichi IWATA ◽  
Tatsuo SUIDZU ◽  
Kazumi TANI

2016 ◽  
Vol 370 ◽  
pp. 357-363 ◽  
Author(s):  
Xiaowen Yu ◽  
Shijun Shen ◽  
Bin Jiang ◽  
Zhongtao Jiang ◽  
Hong Yang ◽  
...  

1990 ◽  
Vol 213 ◽  
Author(s):  
B.A. Pint ◽  
A. Jain ◽  
L.W. Hobbs

ABSTRACTNiAl was ion implanted with yttrium (2×1016 cm−2) in order to study its effect on the very high temperature (1000–1500°C) oxidation properties. At 1000°C, implanted Y stabilizes the faster growing θ-Al2O3 phase, thus slightly increasing the oxidation rate. At 1200°C, where predominantly α-Al2 O3 is formed with and without Y, there is a factor of 4 reduction in the oxidation rate. However at higher than 1200°C, there is little effect by Y on the oxidation rate. Cyclic testing showed that the Y implant had an imperfect and short-lived improvement on adherence relative to other Y-containing alloys. Variations in aluminum content from 23.5 to 36.0wt%(40–55at%) had little effect on the oxidation properties. Initial experiments at 1500°C with a novel Rh marker indicate that alumina grows at least partially by outward cation diffusion both with and without Y.


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