Applications of cellulose materials and their composites

2022 ◽  
pp. 267-284
Author(s):  
Muhammad Khusairy Bin Bakri ◽  
Md Rezaur Rahman
Keyword(s):  
2018 ◽  
Vol 196 ◽  
pp. 04005
Author(s):  
Irina Stepina ◽  
Irina Kotlyarova

The difficulty of wood protection from biocorrosion and fire is due to the fact that modifiers in use are washed out from the surface of the substrate under the influence of environmental factors. This results in a rapid loss of the protective effect and other practically important wood characteristics caused by the modification. To solve this problem is the aim of our work. Here, monoethanolaminoborate is used as a modifier, where electron-donating nitrogen atom provides a coordination number equal to four to a boron atom, which determines the hydrolytic stability of the compounds formed. Alpha-cellulose ground mechanically to a particle size of 1 mm at most was used as a model compound for the modification. X-ray photoelectron spectra were recorded on the XSAM-800 spectrometer (Kratos, UK). Prolonged extraction of the modified samples preceded the registration of the photoelectron spectra to exclude the fixation of the modifier molecules unreacted with cellulose. As a result of the experiment, boron and nitrogen atoms were found in the modified substrate, which indicated the hydrolytic stability of the bonds formed between the modifier molecules and the substrate. Therefore monoethanolaminoborate can be considered as a non-extractable modifier for wood-cellulose materials.


Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1241
Author(s):  
Michael Ioelovich

In this study, physicochemical and chemical methods of cellulose modification were used to increase the hydrophobicity of this natural semicrystalline biopolymer. It has been shown that acid hydrolysis of the initial cellulose increases its crystallinity, which improves hydrophobicity, but only to a small extent. A more significant hydrophobization effect was observed after chemical modification by esterification, when polar hydroxyl groups of cellulose were replaced by non-polar substituents. The esterification process was accompanied by the disruption of the crystalline structure of cellulose and its transformation into the mesomorphous structure of cellulose esters. It was found that the replacement of cellulose hydroxyls with ester groups leads to a significant increase in the hydrophobicity of the resulting polymer. Moreover, the increase of the number of non-polar groups in the ester substituent contributes to rise in hydrophobicity of cellulose derivative. Depending on the type of ester group, the hydrophobicity increased in the following order: acetate < propionate < butyrate. Therefore, tributyrate cellulose (TBC) demonstrated the most hydrophobicity among all studied samples. In addition, the mixed ester, triacetobutyrate cellulose (TAB), also showed a sufficiently high hydrophobicity. The promising performance properties of hydrophobic cellulose esters, TBC and TAB, were also demonstrated.


2016 ◽  
Vol 11 (10) ◽  
pp. 1343-1351 ◽  
Author(s):  
Samuel J. Butler ◽  
Leif Bülow ◽  
Johan Bonde
Keyword(s):  

Cellulose ◽  
2021 ◽  
Author(s):  
C. Fernández-Diego ◽  
I. A. Carrascal ◽  
A. Ortiz ◽  
I. Fernández ◽  
D. Ferreño ◽  
...  

AbstractOil-immersed transformers use paper and oil as insulation system which degrades slowly during the operation of these machines. Cellulose materials are used generally as insulation solid in power transformers. The degree of polymerization (DP), defined as number of repeating β-glucose residues in the cellulose molecule, is a critical property of cellulosic insulation material used in transformers, since it provides information about paper ageing and its mechanical strength. The fast-developing electric power industry demanding superior performance of electrical insulation materials has led to the development of new materials, as well as different drying techniques performed during transformer manufacturing and service when required. Both developments have caused some practical difficulties in the DP measurement. Moreover, the increasing interest in synthetic dielectric materials replacing cellulose materials requires measuring alternative properties to the DP to quantify the degradation of insulation solids over time. In this sense, this paper proposes the possibility of analyzing paper degradation through fracture toughness. This approach is different from the study of mechanical properties such as tensile strength or strain because it provides a tool for solving most practical problems in engineering mechanics, such as safety and life expectancy estimation of cracked structures and components which cannot to be considered through the traditional assessment of the mechanical resistance of the material. An accelerated thermal ageing of Kraft paper in mineral oil was carried out at 130 °C during different periods of time, to obtain information on the kinetics of the ageing degradation of the paper. Double-edged notched specimens were tested in tension to study their fracture toughness. The evolution of the load–displacement curves obtained for different ageing times at the ageing temperature of 130 °C was utilized to the determination of the stress intensity factor. Furthermore, different kinetic models based on this stress intensity factor were applied to relate its evolution over time as a function of the temperature. Finally, the correlation between the DP and stress intensity factor, which depends on the fiber angle, was also defined. Graphic abstract


Author(s):  
Marius C. Barbu ◽  
Roman Reh ◽  
Ayfer Dönmez Çavdar

It would seem that with appropriate treatment almost any agricultural residue may be used as a suitable raw material for the wood-based panels like particle- and fiberboard production. The literature on wood-ligno-cellulose plant composite boards highlights steady interest for the design of new structures and technologies towards products for special applications with higher physical-mechanical properties at relatively low prices. Experimental studies have revealed particular aspects related to the structural composition of ligno-cellulose materials, such as the ratio between the different composing elements, their compatibility, and the types and characteristics of the used resins. Various technologies have been developed for designing and processing composite materials by pressing, extrusion, airflow forming, dry, half-dry, and wet processes, including thermal, chemical, thermo-chemical, thermo-chemo-mechanical treatments, etc. Researchers have undertaken to determine the manufacturing parameters and the physical-mechanical properties of the composite boards and to compare them with the standard PB, MDF, HB, SB made from single-raw material (wood). A great emphasis is placed on the processability of the ligno-cellulose composite boards by classical methods, by modified manufacturing processes, on the types of tools and processing equipment, the automation of the manufacturing technologies, the specific labor conditions, etc. The combinations of wood and plant fibers are successful, since there is obvious compatibility between the macro- and microscopic structures, their chemical composition, and the relatively low manufacturing costs and high performances, as compared to synthetic fiber-based composite materials.


Soft Matter ◽  
2019 ◽  
Vol 15 (39) ◽  
pp. 7901-7908 ◽  
Author(s):  
Nela Buchtová ◽  
Christophe Pradille ◽  
Jean-Luc Bouvard ◽  
Tatiana Budtova

Compressive modulus of highly porous and lightweight cellulose materials prepared via dissolution–coagulation and different drying routes.


Sign in / Sign up

Export Citation Format

Share Document