Contaminant concentration reduction

2007 ◽  
pp. 25-33
2001 ◽  
Vol 44 (5) ◽  
pp. 53-60 ◽  
Author(s):  
C.A. Martín ◽  
O.M. Alfano ◽  
A.E. Cassano

Sometimes, provision of water for domiciliary consumption faces the problem of natural contamination originated by the presence of organic substances such as humic or fulvic acids. Very often, after conventional sanitary treatments this water exhibits a persistent yellowish coloration that affects its use. Moreover, these substances may act as precursors of tri-halomethanes formation during pre-desinfection with chlorine. This paper presents, with a simplified mechanistic approach, the intrinsic reaction kinetics of natural water decolorization employing UV radiation and hydrogen peroxide. The main variables for the model are: contaminant concentration expressed as TOC, hydrogen peroxide concentration and the photon absorption rate.


Author(s):  
Hamed Mahdipanah ◽  
Askari Tashakori ◽  
Samad Emamgholizadeh ◽  
Eisa Maroufpoor

Abstract Dispersivity is a measurable parameter in soil porous media that is used for studying the transport of contaminants to groundwater. The value of this parameter depends on various factors, including the kind of porous media (homogeneous or heterogeneous), flow velocity, initial contaminant concentration, travel distance, and sampling method. A physical model with dimensions of 0.10 m in width, 0.80 m in height, and 1.10 m in length was constructed to investigate the effects of these parameters on the dispersivity value. The stratified soil consisted of three 20-cm-thick layers containing fine-grained, medium-grained, and coarse-grained soil. Sodium chloride solutions with electrical conductivity values of 10, 14, and 19 dS/m were used as the contaminants. Flow was forced through the layered heterogeneous soils at three discharge velocities of 17.58, 22.02, and 26.18 × 10−5 m/s. The point and mixed sampling methods were used. The results indicated that the soil dispersivity values in the layered heterogeneous soils and homogeneous soil were influenced by contaminant concentration, flow velocity, and travel distance. Moreover, the dispersivity values obtained by point sampling were lower than those obtained using the mixed sampling method, and the mean dispersivity value in the layered heterogeneous soils was lower than that of the homogeneous soil.


2007 ◽  
Vol 12 (3) ◽  
pp. 329-343 ◽  
Author(s):  
A. J. Chamkha

A one-dimensional advective-dispersive contaminant transport model with scale-dependent dispersion coefficient in the presence of a nonlinear chemical reaction of arbitrary order is considered. Two types of variations of the dispersion coefficient with the downstream distance are considered. The first type assumes that the dispersivity increases as a polynomial function with distance while the other assumes an exponentiallyincreasing function. Since the general problem is nonlinear and possesses no analytical solutions, a numerical solution based on an efficient implicit iterative tri-diagonal finitedifference method is obtained. Comparisons with previously published analytical and numerical solutions for special cases of the main transport equation are performed and found to be in excellent agreement. A parametric study of all physical parameters is conducted and the results are presented graphically to illustrate interesting features of the solutions. It is found that the chemical reaction order and rate coefficient have significant effects on the contaminant concentration profiles. Furthermore, the scale-dependent polynomial type dispersion coefficient is predicted to obtain significant changes in the contaminant concentration at all dimensionless time stages compared with the constant dispersion case. However, relatively smaller changes in the concentration level are predicted for the exponentially-increasing dispersion coefficient.


1998 ◽  
Vol 40 (4) ◽  
pp. 417-428
Author(s):  
Nobuyuki EGUSA ◽  
Tatemasa HIRATA ◽  
Kiyoshi FUKUURA ◽  
Takashi MATSUSHITA

2021 ◽  
Author(s):  
Arezou Dodangeh ◽  
Mohammad Mahdi Rajabi ◽  
Marwan Fahs

<p>In coastal aquifers, we face the problem of salt water intrusion, which creates a complex flow field. Many of these coastal aquifers are also exposed to contaminants from various sources. In addition, in many cases there is no information about the characteristics of the aquifer. Simultaneous identification of the contaminant source and coastal aquifer characteristics can be a challenging issue. Much work has been done to identify the contaminant source, but in the complex velocity field of coastal aquifer, no one has resolved this issue yet. We want to address that in a three-dimensional artificial coastal aquifer.</p><p>To achieve this goal, we have developed a method in which the contaminant source can be identified and the characteristics of the aquifer can be estimated by using information obtained from observation wells. First, by assuming the input parameters required to simulate the contaminant transfer to the aquifer, this three-dimensional coastal aquifer that is affected by various phenomena such as seawater intrusion, tides, shore slope, rain, discharge and injection wells, is simulated and the time series of the output parameters including head, salinity and contaminant concentration are estimated. In the next step, with the aim of performing inverse modeling, random values ​​are added to the time series of outputs obtained at specific points (points belonging to observation wells) in order to rebuilt the initial conditions of the problem to achieve the desired unknowns (contaminant source and aquifer characteristics). The unknowns estimated in this study are the contaminant source location (x, y, z), the initial contaminant concentration, the horizontal and vertical hydraulic conductivity of the aquifer. SEAWAT model in GMS software environment has been used to solve the equations of flow and contaminant transfer and simulate a three-dimensional coastal aquifer. Next, for reverse modeling, one of the Bayesian Filters subset (ensemble Kalman filter) has been used in the Python programming language environment. Also, to reduce the code run time, the neural network model is designed and trained for the SEAWAT model.</p><p>This method is able to meet the main purpose of the study, namely estimating the value ​​of unknown input parameters, including the contaminant source location, the initial contaminant concentration, the horizontal and vertical hydraulic conductivity of the aquifer. In addition, that makes it possible to achieve a three-dimensional numerical model of the coastal aquifer that can be used as a benchmark to examine more accurately the impact of different phenomena simultaneously. In conclusion, we have developed an algorithm which can be used in the world's coastal aquifers to identify the contaminant source and estimate its characteristics.</p><p> </p><p>Key words: coastal aquifer, seawater intrusion, contaminants, groundwater, flow field, parameter estimation, ensemble kalman filter</p>


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