Dissolution kinetics of Devonian carbonates at circum-neutral pH, 50bar pCO2, 105°C, and 0.4M: The importance of complex brine chemistry on reaction rates

2014 ◽  
Vol 41 ◽  
pp. 128-134 ◽  
Author(s):  
Peter Crockford ◽  
Kevin Telmer ◽  
Melvin Best
Keyword(s):  
Dissolution Kinetics ◽  
Reaction Rates ◽  
Neutral Ph ◽  
Brine Chemistry ◽  
Kinetics Of

Effect of Microstructure on the Dissolution Kinetics of Copper Thin Films in Dilute Aqueous Solutions of Cupric Chloride

1993 ◽  
Vol 323 ◽  
Author(s):  
L. Harper Walsh ◽  
N. B. Feilchenfeld ◽  
J. A. Schwarz
Keyword(s):  
Grain Size ◽  
Grain Orientation ◽  
Dissolution Kinetics ◽  
Surface Region ◽  
Practical Method ◽  
Reaction Rates ◽  
Near Surface ◽  
Dilute Aqueous Solutions ◽  
Microelectronics Industry ◽  
Kinetics Of

ABSTRACTMicrostructural differences in copper deposited by four techniques commonly used in the microelectronics industry were previously reported. [1] The reaction rates were predicted using either grain size or grain orientation as the dominant microstructure characteristic. A practical method to monitor copper speciation was developed.[2] This technique was used to measure the reaction rates for the different copper films under two different etching conditions. The results are explained using grain size, grain orientation and near surface region composition.

Kinetics of esterification of monoisopropylphenols with phosphoryl trichloride

1989 ◽  
Vol 54 (5) ◽  
pp. 1311-1317
Author(s):  
Miroslav Magura ◽  
Ján Vojtko ◽  
Ján Ilavský
Keyword(s):  
Liquid Phase ◽  
Rate Constants ◽  
Reaction Rates ◽  
Activation Energies ◽  
The Individual ◽  
Kinetics Of

The kinetics of liquid-phase isothermal esterification of POCl3 with 2-isopropylphenol and 4-isopropylphenol have been studied within the temperature intervals of 110 to 130 and 90 to 110 °C, respectively. The rate constants and activation energies of the individual steps of this three-step reaction have been calculated from the values measured. The reaction rates of the two isomers markedly differ: at 110 °C 4-isopropylphenol reacts faster by the factors of about 7 and 20 for k1 and k3, respectively. This finding can be utilized in preparation of mixed triaryl phosphates, since the alkylation mixture after reaction of phenol with propene contains an excess of 2-isopropylphenol over 4-isopropylphenol.

Kinetics of Ion-Pair Effect of Aquation of Bromopentaammine Cobalt(III) Complex in Different Dicarboxylate Media

2011 ◽  
Vol 324 ◽  
pp. 166-169 ◽  
Author(s):  
Farah Zeitouni ◽  
Gehan El-Subruiti ◽  
Ghassan Younes ◽  
Mohammad Amira
Keyword(s):  
Free Energy ◽  
Solvent Effect ◽  
Compensation Effect ◽  
Ion Pairing ◽  
Reaction Rates ◽  
Ion Pair ◽  
Free Energy Of Activation ◽  
Different Types ◽  
Different Temperatures ◽  
Kinetics Of

The rate of aquation of bromopentaammine cobalt(III) ion in the presence of different types of dicarboxylate solutions containing tert-butanol (40% V/V) have been measured spectrophotometrically at different temperatures (30-600°C) in the light of the effects of ion-pairing on reaction rates and mechanism. The thermodynamic and extrathermodynamic parameters of activation have been calculated and discussed in terms of solvent effect on the ion-pair aquation reaction. The free energy of activation ∆Gip* is more or less linearly varied among the studied dicarboxylate ion-pairing ligands indicating the presence of compensation effect between ∆Hip* and ∆Sip*. Comparing the kip values with respect of different buffers at 40% of ter-butanol is introduced.

Short time dissolution kinetics of refractory elements Fe, Al, and Ti in Asian outflow-impacted marine aerosols and implications

2013 ◽  
Vol 79 ◽  
pp. 93-100 ◽  
Author(s):  
Shih-Chieh Hsu ◽  
Fei-Jan Lin ◽  
Tsun-Hsien Liu ◽  
Shuen-Hsin Lin ◽  
Shuh-Ji Kao ◽  
...  
Keyword(s):  
Dissolution Kinetics ◽  
Marine Aerosols ◽  
Refractory Elements ◽  
Short Time ◽  
Kinetics Of
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