Al2O3 supported Ru catalysts prepared by thermolysis of Ru3(CO)12 for catalytic wet air oxidation

2011 ◽  
Vol 257 (17) ◽  
pp. 7727-7731 ◽  
Author(s):  
Chaoying Yu ◽  
Peiqing Zhao ◽  
Gexin Chen ◽  
Bin Hu
RSC Advances ◽  
2016 ◽  
Vol 6 (77) ◽  
pp. 73810-73816 ◽  
Author(s):  
Fagui Lu ◽  
Chaoying Yu ◽  
Xu Meng ◽  
Jinqi Zhang ◽  
Gexin Chen ◽  
...  

The nature of the Ru precursors affected the performance of Ru catalysts with those prepared from chloride-free Ru precursors being more active than those prepared from chlorine-containing Ru precursors.


Energies ◽  
2019 ◽  
Vol 12 (20) ◽  
pp. 3974
Author(s):  
Thu ◽  
Besson

The production of brandy from wine and bioethanol from sugarcane in distilleries generates vinasses, which are effluents that are rich in organic matter. Since they have a high pollution load characterized by high chemical and biological oxygen demands and a dark color, the depollution of these effluents is inevitable. Pt and Ru catalysts supported on titania and zirconia were explored in the catalytic wet air oxidation (CWAO) processing of cognac and sugarcane wastewaters, in batch mode and in a trickle-bed reactor, at a temperature condition of 190 °C and a pressure condition of 70 bar air. The addition of a catalyst promoted total organic carbon (TOC) abatement and the oxidation of ammonium ions formed from organic nitrogen in the effluents to dinitrogen or nitrates. The best results in terms of selectivity to N2 were obtained by using Pt catalysts; a selectivity of 92% to N2 and a TOC removal of 90% were observed in continuous oxidation of the sugarcane vinasse.


RSC Advances ◽  
2016 ◽  
Vol 6 (115) ◽  
pp. 114383-114395 ◽  
Author(s):  
Dilip Kumar Mondal ◽  
Chandona Mondal ◽  
Shyamal Roy

Catalytic wet air oxidation (CWAO) of phenol was carried out in a fixed bed reactor over a noble metal (Ru) supported on silica MCM-41 material.


1997 ◽  
Vol 35 (4) ◽  
pp. 311-319 ◽  
Author(s):  
L. Lei ◽  
X. Hu ◽  
H. P. Chu ◽  
G. Chen ◽  
P. L. Yue

The treatment of dyeing and printing wastewater from the textile industry by oxidation was studied. The reaction was carried out in a two-litre high pressure reactor. In order to promote the oxidation of organic pollutants present in the wastewater, experiments were conducted using various catalysts including metal salts, metal oxides, and porous alumina supported metals. All catalysts tested were able to enhance the conversion of organic compounds in wastewater, shorten the reaction time, and lower the reaction temperature. The alumina supported catalyst has an advantage over other catalysts in that it can be easily separated from the treated wastewater by filtration and recycled. The conditions in preparing the catalyst supported by porous alumina were experimentally optimised.


Author(s):  
Mohamed Achraf Bouabdellah ◽  
Itidel Belkadhi ◽  
Lassaad Ben Hammouda ◽  
Gwendoline Lafaye ◽  
Francisco Medina Cabello ◽  
...  

2021 ◽  
Vol 23 (4) ◽  
pp. 1847-1860
Author(s):  
Christopher S. McCallum ◽  
Wanling Wang ◽  
W. John Doran ◽  
W. Graham Forsythe ◽  
Mark D. Garrett ◽  
...  

A life cycle thinking analysis (LCT) conducted on the production of vanillin via bamboo wet air oxidation compared to vanillin production from crude oil or kraft lignin.


Author(s):  
Valérie Boucher ◽  
Margot Beaudon ◽  
Pedro Ramirez ◽  
Pascal Lemoine ◽  
Kalyssa Volk ◽  
...  

Removal of pharmaceuticals from wastewater using chemical processes is a promising solution to mitigate pollution in drinking and surface waters. Non-catalytic wet air oxidation (WAO) is a highly efficient advanced...


1995 ◽  
Vol 24 (1-2) ◽  
pp. 73-78 ◽  
Author(s):  
F. Luck ◽  
M. Djafer ◽  
M.M. Bourbigot

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